The accepted doping ion in Ti^(4+)-site of PbZr_(y)Ti_(1–y)O_(3)(PZT)-based piezoelectric ceramics is a well-known method to increase mechanical quality factor(Q_(m)),since the acceptor coupled by oxygen vacancy beco...The accepted doping ion in Ti^(4+)-site of PbZr_(y)Ti_(1–y)O_(3)(PZT)-based piezoelectric ceramics is a well-known method to increase mechanical quality factor(Q_(m)),since the acceptor coupled by oxygen vacancy becomes defect dipole,which prevents the domain rotation.In this field,a serious problem is that generally,Qm decreases as the temperature(T)increases,since the oxygen vacancies are decoupled from the defect dipoles.In this work,Q_(m) of Pb_(0.95)Sr_(0.05)(Zr_(0.53)Ti_(0.47))O_(3)(PSZT)ceramics doped by 0.40%Fe_(2)O_(3)(in mole)abnormally increases as T increases,of which the Qm and piezoelectric coefficient(d_(33))at room temperature and Curie temperature(TC)are 507,292 pC/N,and 345℃,respectively.The maximum Qm of 824 was achieved in the range of 120–160℃,which is 62.52%higher than that at room temperature,while the dynamic piezoelectric constant(d_(31))was just slightly decreased by 3.85%.X-ray diffraction(XRD)and piezoresponse force microscopy results show that the interplanar spacing and the fine domains form as temperature increases,and the thermally stimulated depolarization current shows that the defect dipoles are stable even the temperature up to 240℃.It can be deduced that the aggregation of oxygen vacancies near the fine domains and defect dipole can be stable up to 240℃,which pins domain rotation,resulting in the enhanced Q_(m) with the increasing temperature.These results give a potential path to design high Q_(m) at high temperature.展开更多
A theoretical model was suggested which describes the generation of the misfit dislocation dipole in the system of the viscoelastic matrix containing a circular stiff nanoscale inhomogeneity.The critical condition of ...A theoretical model was suggested which describes the generation of the misfit dislocation dipole in the system of the viscoelastic matrix containing a circular stiff nanoscale inhomogeneity.The critical condition of misfit dislocation dipole and the solution of equilibrium position were given.The influence of the ratio of shear modulus,the misfit strain and viscosity on the equilibrium of the dislocation and critical parameter of inhomogeneity was investigated.The result shows that the equilibrium position de increases with the increase of the ratio of original shear modulus and the effect decreases with the increase of viscosity of matrix.Along with the increase of viscosity of matrix,de first increases and then decreases and possesses maximum value when t=0.3τ and tends to a stable value when t≥1.0τ.Along with the increase of viscosity of matrix,Rc first decreases and then increases and possesses minimum value when t=0.3τ and tends to a stable value when t≥1.0τ.展开更多
In the case of three-layered(air-seawater-seabed)model,the analytical expressions of the static electric and static magnetic field produced by the static electric dipole located in seawater were derived by using the m...In the case of three-layered(air-seawater-seabed)model,the analytical expressions of the static electric and static magnetic field produced by the static electric dipole located in seawater were derived by using the mirror image theory.Combined with the distribution of the underwater electric potential measured in laboratory,an electric dipole model for physical scale of ship was established and the distribution characteristics of an actual ship' s corrosion related magnetic field were obtained.Based on established models,theoretical analysis and calculation were made to catch out the distribution characteristics of static magnetic field related with corrosion and anticorrosion,which can not be measured directly in seawater.The results show that the static magnetic field related with corrosion and anticorrosion is a kind of noteworthy obstacle signal for degaussed ships.展开更多
In this paper,we propose an RLC equivalent circuit model theory which can accurately predict the spectral response and resonance characteristics of metamaterial absorption structures,extend its design,and characterize...In this paper,we propose an RLC equivalent circuit model theory which can accurately predict the spectral response and resonance characteristics of metamaterial absorption structures,extend its design,and characterize the parameters of the model in detail.By employing this model,we conducted computations to characterize the response wavelength and bandwidth of variously sized metamaterial absorbers.A comparative analysis with Finite Difference Time Domain(FDTD)simulations demonstrated a remarkable level of consistency in the results.The designed absorbers were fabricated using micro-nano fabrication processes,and were experimentally tested to demonstrate absorption rates exceeding 90%at a wavelength of 9.28μm.The predicted results are then compared with test results.The comparison reveals good consistency in two aspects of the resonance responses,thereby confirming the rationality and accuracy of this model.展开更多
Magnetic field gradient tensor measurement is an important technique to obtain position information of magnetic objects. When using magnetic field sensors to measure magnetic field gradient as the coefficients of tens...Magnetic field gradient tensor measurement is an important technique to obtain position information of magnetic objects. When using magnetic field sensors to measure magnetic field gradient as the coefficients of tensor, field differentiation is generally approximated by field difference. As a result, magnetic objects positioning by magnetic field gradient tensor measurement always involves an inherent error caused by sensor sizes, leading to a reduction in detectable distance and detectable angle. In this paper, the inherent positioning error caused by magnetic field gradient tensor measurement is calculated and corrected by iterations based on the systematic position error distribution patterns. The results show that, the detectable distance range and the angle range of an ac magnetic object(2.44 Am^2@1 kHz) can be increased from(0.45 m, 0.75 m),(0?, 25?) to(0.30 m, 0.80 m),(0?,80?), respectively.展开更多
A modeling tool for simulating three-dimensional land frequency-domain controlled-source electromagnetic surveys,based on a finite-element discretization of the Helmholtz equation for the electric fields,has been deve...A modeling tool for simulating three-dimensional land frequency-domain controlled-source electromagnetic surveys,based on a finite-element discretization of the Helmholtz equation for the electric fields,has been developed.The main difference between our modeling method and those previous works is edge finite-element approach applied to solving the three-dimensional land frequency-domain electromagnetic responses generated by horizontal electric dipole source.Firstly,the edge finite-element equation is formulated through the Galerkin method based on Helmholtz equation of the electric fields.Secondly,in order to check the validity of the modeling code,the numerical results are compared with the analytical solutions for a homogeneous half-space model.Finally,other three models are simulated with three-dimensional electromagnetic responses.The results indicate that the method can be applied for solving three-dimensional electromagnetic responses.The algorithm has been demonstrated,which can be effective to modeling the complex geo-electrical structures.This efficient algorithm will help to study the distribution laws of3-D land frequency-domain controlled-source electromagnetic responses and to setup basis for research of three-dimensional inversion.展开更多
A discrete dislocation plasticity analysis of dispersion strengthening in oxide dispersion strengthened(ODS) steels was described. Parametric dislocation dynamics(PDD) simulation of the interaction between an edge dis...A discrete dislocation plasticity analysis of dispersion strengthening in oxide dispersion strengthened(ODS) steels was described. Parametric dislocation dynamics(PDD) simulation of the interaction between an edge dislocation and randomly distributed spherical dispersoids(Y2O3) in bcc iron was performed for measuring the influence of the dispersoid distribution on the critical resolved shear stress(CRSS). The dispersoid distribution was made using a method mimicking the Ostwald growth mechanism. Then, an edge dislocation was introduced, and was moved under a constant shear stress condition. The CRSS was extracted from the result of dislocation velocity under constant shear stress using the mobility(linear) relationship between the shear stress and the dislocation velocity. The results suggest that the dispersoid distribution gives a significant influence to the CRSS, and the influence of dislocation dipole, which forms just before finishing up the Orowan looping mechanism, is substantial in determining the CRSS, especially for the interaction with small dispersoids. Therefore, the well-known Orowan equation for determining the CRSS cannot give an accurate estimation, because the influence of the dislocation dipole in the process of the Orowan looping mechanism is not accounted for in the equation.展开更多
Interfaces play critical roles in electronic devices and provide great diversity of film morphology and device performance.We retrospect the substrate mediated vacuum film growth of benchmark high mobility material 2,...Interfaces play critical roles in electronic devices and provide great diversity of film morphology and device performance.We retrospect the substrate mediated vacuum film growth of benchmark high mobility material 2,7-dioctyl[1]benzothieno[3,2-b]benzothiophene(C8-BTBT)and the interface electronic structures.The film growth of C8-BTBT molecules is diversified depending on the substrate-molecule and molecule-molecule interactions.On atomic smooth substrates C8-BTBT film grows in layer-by-layer mode while on coarse substrate it grows in islands mode.The initial molecular layer at dielectric,semiconductor and conductive substrates displays slight different lattice structure.The initial molecule orientation depends on the substrate and will gradually change to standing up configuration as in bulk phase.C8-BTBT behaves as electron donor when contacting with dielectric and stable conductive materials.This usually induces a dipole layer pointing to C8-BTBT and an upward bend bending in C8-BTBT side toward the interface.Although it is air stable,C8-BTBT is chemically reactive with some transition metals and compounds.The orientation change from lying down to standing up in the film usually leads to decrease of ionization potential.The article provides insights to the interface physical and chemical processes and suggestions for optimal design and fabrication of C8-BTBT based devices.展开更多
Left-hand materials have drawn increasing attention from many disciplines and found widespread application, especially in microwave engineering. A sandwiched metamaterial consisting of multi-nested square-split-ring r...Left-hand materials have drawn increasing attention from many disciplines and found widespread application, especially in microwave engineering. A sandwiched metamaterial consisting of multi-nested square-split-ring resonators on the top side and a set of wires on the back side is proposed. Scattering parameters are retrieved by high-frequency structure simulator(HFSS) software based on the finite element method. Effects of square-split-ring number on the left-hand characteristics containing negative values of permittivity, permeability, and refractive index have been intensively investigated. Simulated results show that obvious resonant left-hand characteristics could be observed within 8-18 GHz, and the resonant frequency counts are inclined to be in direct proportion to the square-split-ring number over 8-18 GHz. Besides, the proposed sandwiched metamaterial with three square-split-ring resonators and three wires presents the widest frequency band of left-hand characteristics in a range of 8-18 GHz. Further, electromagnetic field distributions demonstrated that the induced magnetic dipole dominates the resonant absorption. The multi-peak resonance characteristics of square-split-ring resonant structure are considered to be a promising candidate for selective-frequency absorption or modulation toward microwave frequency band.展开更多
Infrared spectrum and NMR chemical shifts of Si (CH3)2O double free radical were calculatedemploying density functional theory(DFT) with the basis sets 6 - 311 + G(2d, p). Excited states, dipole momentand energy of Si...Infrared spectrum and NMR chemical shifts of Si (CH3)2O double free radical were calculatedemploying density functional theory(DFT) with the basis sets 6 - 311 + G(2d, p). Excited states, dipole momentand energy of Si(CH3 )2O double free radical were also calculated using time dependent density function theory(TD-DFT) with the same basis sets. It is found that the external electric field along the X,Y and Z axis affectdifferently on the excited states and other properties of Si(CH3)2O double free radical.展开更多
Because the conventional ultra wideband(UWB) radar imaging algorithm cannot meet the demand in the capability of multiple targets detection,a novel UWB radar imaging algorithm based on the near field radiation theor...Because the conventional ultra wideband(UWB) radar imaging algorithm cannot meet the demand in the capability of multiple targets detection,a novel UWB radar imaging algorithm based on the near field radiation theory of dipole is presented.On the foundation of researching the principle of a time domain imaging algorithm,the back projection(BP) algorithm is derived and analyzed.Firstly,the far field sampling data are transferred to the near field sampling data by using the near field radiation theory of dipole.Then the BP algorithm is applied to target detection.The capability of the new algorithm to detect the multi-target is verified by using the finite-difference time-domain method,and the threedimensional images of targets are obtained.The coupling effect between targets for imaging is analyzed.The simulation results show that the new UWB radar imaging algorithm based on the near field radiation theory of dipole could weaken the coupling effect for imaging,and as a result the quality of imaging is improved.展开更多
A novel metasurface antenna consisting of 5×5 rectangular patch elements is presented.Thestructure with and without the central element are both analyzed by the Characteristic Mode Theory(CMT).The developed mutua...A novel metasurface antenna consisting of 5×5 rectangular patch elements is presented.Thestructure with and without the central element are both analyzed by the Characteristic Mode Theory(CMT).The developed mutually orthogonal principal modes of the optimized periodic patch structure areexcited by a center-feed dipole.A differential feeding network is employed to realize impedance matching.Prototype with profile height of 0.07λ_(0)(λ_(0)is the wavelength in free space at the lowest operatingfrequency)is fabricated and assembled to verify the simulation results.The measured results show that thereflectance coefficient of proposed matesurface antenna is less than-10 dB in the whole operating bandrange from 4.2 GHz to 5.5 GHz,a relative bandwidth of 26.8%is achieved,and the maximummeasured realized gain is more than 9 dBi with a maximum radiation efficiency of 90%.The designprovides a guideline on the application of characteristic modes(CMs)to radiation problems.展开更多
基金National Natural Science Foundation of China(U2241242)National Key R&D Program of China(2023YFB3812000,2021YFA0716502)。
文摘The accepted doping ion in Ti^(4+)-site of PbZr_(y)Ti_(1–y)O_(3)(PZT)-based piezoelectric ceramics is a well-known method to increase mechanical quality factor(Q_(m)),since the acceptor coupled by oxygen vacancy becomes defect dipole,which prevents the domain rotation.In this field,a serious problem is that generally,Qm decreases as the temperature(T)increases,since the oxygen vacancies are decoupled from the defect dipoles.In this work,Q_(m) of Pb_(0.95)Sr_(0.05)(Zr_(0.53)Ti_(0.47))O_(3)(PSZT)ceramics doped by 0.40%Fe_(2)O_(3)(in mole)abnormally increases as T increases,of which the Qm and piezoelectric coefficient(d_(33))at room temperature and Curie temperature(TC)are 507,292 pC/N,and 345℃,respectively.The maximum Qm of 824 was achieved in the range of 120–160℃,which is 62.52%higher than that at room temperature,while the dynamic piezoelectric constant(d_(31))was just slightly decreased by 3.85%.X-ray diffraction(XRD)and piezoresponse force microscopy results show that the interplanar spacing and the fine domains form as temperature increases,and the thermally stimulated depolarization current shows that the defect dipoles are stable even the temperature up to 240℃.It can be deduced that the aggregation of oxygen vacancies near the fine domains and defect dipole can be stable up to 240℃,which pins domain rotation,resulting in the enhanced Q_(m) with the increasing temperature.These results give a potential path to design high Q_(m) at high temperature.
基金Project(10472030) supported by the National Natural Science Foundation of China
文摘A theoretical model was suggested which describes the generation of the misfit dislocation dipole in the system of the viscoelastic matrix containing a circular stiff nanoscale inhomogeneity.The critical condition of misfit dislocation dipole and the solution of equilibrium position were given.The influence of the ratio of shear modulus,the misfit strain and viscosity on the equilibrium of the dislocation and critical parameter of inhomogeneity was investigated.The result shows that the equilibrium position de increases with the increase of the ratio of original shear modulus and the effect decreases with the increase of viscosity of matrix.Along with the increase of viscosity of matrix,de first increases and then decreases and possesses maximum value when t=0.3τ and tends to a stable value when t≥1.0τ.Along with the increase of viscosity of matrix,Rc first decreases and then increases and possesses minimum value when t=0.3τ and tends to a stable value when t≥1.0τ.
基金Sponsored by National Defense Pre-research Foundation(51444070105JB11)
文摘In the case of three-layered(air-seawater-seabed)model,the analytical expressions of the static electric and static magnetic field produced by the static electric dipole located in seawater were derived by using the mirror image theory.Combined with the distribution of the underwater electric potential measured in laboratory,an electric dipole model for physical scale of ship was established and the distribution characteristics of an actual ship' s corrosion related magnetic field were obtained.Based on established models,theoretical analysis and calculation were made to catch out the distribution characteristics of static magnetic field related with corrosion and anticorrosion,which can not be measured directly in seawater.The results show that the static magnetic field related with corrosion and anticorrosion is a kind of noteworthy obstacle signal for degaussed ships.
基金Supported by the National Natural Science Foundation of China(62174092)the Open Fund of State Key Laboratory of Infrared Physics(SITP-NLIST-ZD-2023-04)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0580000)。
文摘In this paper,we propose an RLC equivalent circuit model theory which can accurately predict the spectral response and resonance characteristics of metamaterial absorption structures,extend its design,and characterize the parameters of the model in detail.By employing this model,we conducted computations to characterize the response wavelength and bandwidth of variously sized metamaterial absorbers.A comparative analysis with Finite Difference Time Domain(FDTD)simulations demonstrated a remarkable level of consistency in the results.The designed absorbers were fabricated using micro-nano fabrication processes,and were experimentally tested to demonstrate absorption rates exceeding 90%at a wavelength of 9.28μm.The predicted results are then compared with test results.The comparison reveals good consistency in two aspects of the resonance responses,thereby confirming the rationality and accuracy of this model.
基金supported by the National Natural Science Foundation of China(61473023)
文摘Magnetic field gradient tensor measurement is an important technique to obtain position information of magnetic objects. When using magnetic field sensors to measure magnetic field gradient as the coefficients of tensor, field differentiation is generally approximated by field difference. As a result, magnetic objects positioning by magnetic field gradient tensor measurement always involves an inherent error caused by sensor sizes, leading to a reduction in detectable distance and detectable angle. In this paper, the inherent positioning error caused by magnetic field gradient tensor measurement is calculated and corrected by iterations based on the systematic position error distribution patterns. The results show that, the detectable distance range and the angle range of an ac magnetic object(2.44 Am^2@1 kHz) can be increased from(0.45 m, 0.75 m),(0?, 25?) to(0.30 m, 0.80 m),(0?,80?), respectively.
基金Projects(41674080,41674079)supported by the National Natural Science Foundation of China
文摘A modeling tool for simulating three-dimensional land frequency-domain controlled-source electromagnetic surveys,based on a finite-element discretization of the Helmholtz equation for the electric fields,has been developed.The main difference between our modeling method and those previous works is edge finite-element approach applied to solving the three-dimensional land frequency-domain electromagnetic responses generated by horizontal electric dipole source.Firstly,the edge finite-element equation is formulated through the Galerkin method based on Helmholtz equation of the electric fields.Secondly,in order to check the validity of the modeling code,the numerical results are compared with the analytical solutions for a homogeneous half-space model.Finally,other three models are simulated with three-dimensional electromagnetic responses.The results indicate that the method can be applied for solving three-dimensional electromagnetic responses.The algorithm has been demonstrated,which can be effective to modeling the complex geo-electrical structures.This efficient algorithm will help to study the distribution laws of3-D land frequency-domain controlled-source electromagnetic responses and to setup basis for research of three-dimensional inversion.
文摘A discrete dislocation plasticity analysis of dispersion strengthening in oxide dispersion strengthened(ODS) steels was described. Parametric dislocation dynamics(PDD) simulation of the interaction between an edge dislocation and randomly distributed spherical dispersoids(Y2O3) in bcc iron was performed for measuring the influence of the dispersoid distribution on the critical resolved shear stress(CRSS). The dispersoid distribution was made using a method mimicking the Ostwald growth mechanism. Then, an edge dislocation was introduced, and was moved under a constant shear stress condition. The CRSS was extracted from the result of dislocation velocity under constant shear stress using the mobility(linear) relationship between the shear stress and the dislocation velocity. The results suggest that the dispersoid distribution gives a significant influence to the CRSS, and the influence of dislocation dipole, which forms just before finishing up the Orowan looping mechanism, is substantial in determining the CRSS, especially for the interaction with small dispersoids. Therefore, the well-known Orowan equation for determining the CRSS cannot give an accurate estimation, because the influence of the dislocation dipole in the process of the Orowan looping mechanism is not accounted for in the equation.
基金Project(2017YFA0206602)supported in part by the National Key Research and Development Program of China。
文摘Interfaces play critical roles in electronic devices and provide great diversity of film morphology and device performance.We retrospect the substrate mediated vacuum film growth of benchmark high mobility material 2,7-dioctyl[1]benzothieno[3,2-b]benzothiophene(C8-BTBT)and the interface electronic structures.The film growth of C8-BTBT molecules is diversified depending on the substrate-molecule and molecule-molecule interactions.On atomic smooth substrates C8-BTBT film grows in layer-by-layer mode while on coarse substrate it grows in islands mode.The initial molecular layer at dielectric,semiconductor and conductive substrates displays slight different lattice structure.The initial molecule orientation depends on the substrate and will gradually change to standing up configuration as in bulk phase.C8-BTBT behaves as electron donor when contacting with dielectric and stable conductive materials.This usually induces a dipole layer pointing to C8-BTBT and an upward bend bending in C8-BTBT side toward the interface.Although it is air stable,C8-BTBT is chemically reactive with some transition metals and compounds.The orientation change from lying down to standing up in the film usually leads to decrease of ionization potential.The article provides insights to the interface physical and chemical processes and suggestions for optimal design and fabrication of C8-BTBT based devices.
基金Project(2017YFA0204600)supported by the National Key Research and Development Program of ChinaProject(51802352)supported by the National Natural Science Foundation of ChinaProject(2019JJ50768)supported by the Natural Science Foundation of Hunan Province of China。
文摘Left-hand materials have drawn increasing attention from many disciplines and found widespread application, especially in microwave engineering. A sandwiched metamaterial consisting of multi-nested square-split-ring resonators on the top side and a set of wires on the back side is proposed. Scattering parameters are retrieved by high-frequency structure simulator(HFSS) software based on the finite element method. Effects of square-split-ring number on the left-hand characteristics containing negative values of permittivity, permeability, and refractive index have been intensively investigated. Simulated results show that obvious resonant left-hand characteristics could be observed within 8-18 GHz, and the resonant frequency counts are inclined to be in direct proportion to the square-split-ring number over 8-18 GHz. Besides, the proposed sandwiched metamaterial with three square-split-ring resonators and three wires presents the widest frequency band of left-hand characteristics in a range of 8-18 GHz. Further, electromagnetic field distributions demonstrated that the induced magnetic dipole dominates the resonant absorption. The multi-peak resonance characteristics of square-split-ring resonant structure are considered to be a promising candidate for selective-frequency absorption or modulation toward microwave frequency band.
文摘Infrared spectrum and NMR chemical shifts of Si (CH3)2O double free radical were calculatedemploying density functional theory(DFT) with the basis sets 6 - 311 + G(2d, p). Excited states, dipole momentand energy of Si(CH3 )2O double free radical were also calculated using time dependent density function theory(TD-DFT) with the same basis sets. It is found that the external electric field along the X,Y and Z axis affectdifferently on the excited states and other properties of Si(CH3)2O double free radical.
基金supported by the Key Laboratory of Millimeter Waves of China (K200907)
文摘Because the conventional ultra wideband(UWB) radar imaging algorithm cannot meet the demand in the capability of multiple targets detection,a novel UWB radar imaging algorithm based on the near field radiation theory of dipole is presented.On the foundation of researching the principle of a time domain imaging algorithm,the back projection(BP) algorithm is derived and analyzed.Firstly,the far field sampling data are transferred to the near field sampling data by using the near field radiation theory of dipole.Then the BP algorithm is applied to target detection.The capability of the new algorithm to detect the multi-target is verified by using the finite-difference time-domain method,and the threedimensional images of targets are obtained.The coupling effect between targets for imaging is analyzed.The simulation results show that the new UWB radar imaging algorithm based on the near field radiation theory of dipole could weaken the coupling effect for imaging,and as a result the quality of imaging is improved.
文摘A novel metasurface antenna consisting of 5×5 rectangular patch elements is presented.Thestructure with and without the central element are both analyzed by the Characteristic Mode Theory(CMT).The developed mutually orthogonal principal modes of the optimized periodic patch structure areexcited by a center-feed dipole.A differential feeding network is employed to realize impedance matching.Prototype with profile height of 0.07λ_(0)(λ_(0)is the wavelength in free space at the lowest operatingfrequency)is fabricated and assembled to verify the simulation results.The measured results show that thereflectance coefficient of proposed matesurface antenna is less than-10 dB in the whole operating bandrange from 4.2 GHz to 5.5 GHz,a relative bandwidth of 26.8%is achieved,and the maximummeasured realized gain is more than 9 dBi with a maximum radiation efficiency of 90%.The designprovides a guideline on the application of characteristic modes(CMs)to radiation problems.