Based on the deep understanding of the requirements of cutting conditions on ceramic tools, a design model for functionally gradient ceramic tool materials with symmetrical composition distribution was presented in th...Based on the deep understanding of the requirements of cutting conditions on ceramic tools, a design model for functionally gradient ceramic tool materials with symmetrical composition distribution was presented in this paper, according to which an Al 2O 3-TiC functionally gradient ceramic tool material FG-1 was synthesized by powder-laminating and uniaxially hot-pressing technique. The thermal shock resistance of the Al 2O 3-TiC functionally gradient ceramics FG-1 was evaluated by water quenching and subsequent three-point bending tests of flexural strength diminution. Comparisons were made with results from parallel experiments conducted using a homogeneous Al 2O 3-TiC ceramics. Functionally gradient ceramics exhibited higher retained strength under all thermal shock temperature differences compared to homogeneous ceramics, indicating the higher thermal shock resistance. The experimental results were supported by the calculation of transient thermal stress field. The cutting performance of the Al 2O 3-TiC functionally gradient ceramic tool FG-1 was also investigated in rough turning the cylindrical surface of exhaust valve of diesel engine in comparison with that of a common Al 2O 3-TiC ceramic tool LT55. The results indicated that the tool life of FG-1 increased by 50 percent over that of LT55. Tool life of LT55 was mainly controlled by thermal shock cracking which was accompanied by mechanical shock. While tool life of FG-1 was mainly controlled by mechanical fatigue crack extension rather than thermal shock cracking, revealing the less thermal shock susceptibility of functionally gradient ceramics than that of common ceramics.展开更多
There were only two kinds of superhard tool material at the past, i.e. diamond and cubic boron nitride (CBN). Manmade diamond and CBN are manufactured by the middle of 20th century. Various manufacturing methods and m...There were only two kinds of superhard tool material at the past, i.e. diamond and cubic boron nitride (CBN). Manmade diamond and CBN are manufactured by the middle of 20th century. Various manufacturing methods and manmade superhard materials were developed later. They were widely used in different industry and science areas. Recently, a new kind of superhard tool material, C 3N 4 coating film, had been developed. American physical scientists, A. M. Liu and M. L. Cohen, designed a new kind of inorganic compound C 3N 4 with the theory of molecule engineering. According to calculation, it can reach or even exceed the hardness of diamond, so material scientists and technique circles draw their attention to it. A high speed steel twist drill coated with C 3N 4 film is applied to the drilling hole process on steel workpiece in cutting tests, the tool life is increased greatly. When the C 3N 4 film is coated on the cemented carbide inserts, the cutting performance is improved, but is not good enough. The data of mechanical performance and cutting tests about this kind of new tool material is given in this paper, it shows that C 3N 4 has a promising future. The anti-wear ability of cutting tool increases sharply after C 3N 4 being coated on HSS tool. Coated HSS drill also has some benefit after being reground. The tool life prolongs after C 3N 4 being coated on cemented carbide inserts, but is not so long as that of C 3N 4 coated HSS tool. When machining PRCM with C 3N 4 thin-film coated cemented carbide tool, the cutting performance is poor and it is much better when machining PRCM with PCBN, PCD compound plates and CVD thick-film coated cutting tool. Some relative aspects need to be deeply discussed and researched, e.g. the existing coating techniques is not good enough and should be improved in the future, the film thickness should be optimized and try to find out the most effective value, the binding force and mutual effect between coated film and substrate need to be studied furtherly, etc.展开更多
Compared with the sintered polycrystalline diamond, the deposited thin film diamond has the great advantage on the fabrication of cutting tools with complex geometries such as drills. Because of their low costs for fa...Compared with the sintered polycrystalline diamond, the deposited thin film diamond has the great advantage on the fabrication of cutting tools with complex geometries such as drills. Because of their low costs for fabrication equipment and high performance on high speed machining non-ferrous metals and alloys, metal-compound materials, and hard brittle non-metals, diamond-coated drills find great potentialities in the commercial application. However, the poor adhesion of the diamond film on the substrate becomes the main technical barriers for the successful development and commercialization of diamond-coated tools. In this paper, diamond thin films were deposited on WC-Co based drills by the electron aided hot filament chemical vapor deposition (EACVD). A new multiple chemical pre-treatment technology including microwave oxidation, reaction in alkaline solution and cleaning by ultrasonic treatment in acid solution was developed and affects on the diamond adhesion strength, nucleation and surface morphology were investigated. At the same time, a special setup to fabricate diamond-coated drills was also developed and then the novel CVD process based on the varied parameters controlling model was presented, therefore the uniform quality and homogenized thickness of diamond coating could be available. From practical utilization viewpoint, the cutting performance of the diamond-coated drill was studied by drilling SiC particle reinforced aluminum matrix composite. The satisfied wear resistance and decrease of torque and thrust led to the long life of this kind of drill. This paper exhibited the meaningful work for the development of cutting tools with complex geometries and further extended the application of diamond material.展开更多
文摘Based on the deep understanding of the requirements of cutting conditions on ceramic tools, a design model for functionally gradient ceramic tool materials with symmetrical composition distribution was presented in this paper, according to which an Al 2O 3-TiC functionally gradient ceramic tool material FG-1 was synthesized by powder-laminating and uniaxially hot-pressing technique. The thermal shock resistance of the Al 2O 3-TiC functionally gradient ceramics FG-1 was evaluated by water quenching and subsequent three-point bending tests of flexural strength diminution. Comparisons were made with results from parallel experiments conducted using a homogeneous Al 2O 3-TiC ceramics. Functionally gradient ceramics exhibited higher retained strength under all thermal shock temperature differences compared to homogeneous ceramics, indicating the higher thermal shock resistance. The experimental results were supported by the calculation of transient thermal stress field. The cutting performance of the Al 2O 3-TiC functionally gradient ceramic tool FG-1 was also investigated in rough turning the cylindrical surface of exhaust valve of diesel engine in comparison with that of a common Al 2O 3-TiC ceramic tool LT55. The results indicated that the tool life of FG-1 increased by 50 percent over that of LT55. Tool life of LT55 was mainly controlled by thermal shock cracking which was accompanied by mechanical shock. While tool life of FG-1 was mainly controlled by mechanical fatigue crack extension rather than thermal shock cracking, revealing the less thermal shock susceptibility of functionally gradient ceramics than that of common ceramics.
文摘There were only two kinds of superhard tool material at the past, i.e. diamond and cubic boron nitride (CBN). Manmade diamond and CBN are manufactured by the middle of 20th century. Various manufacturing methods and manmade superhard materials were developed later. They were widely used in different industry and science areas. Recently, a new kind of superhard tool material, C 3N 4 coating film, had been developed. American physical scientists, A. M. Liu and M. L. Cohen, designed a new kind of inorganic compound C 3N 4 with the theory of molecule engineering. According to calculation, it can reach or even exceed the hardness of diamond, so material scientists and technique circles draw their attention to it. A high speed steel twist drill coated with C 3N 4 film is applied to the drilling hole process on steel workpiece in cutting tests, the tool life is increased greatly. When the C 3N 4 film is coated on the cemented carbide inserts, the cutting performance is improved, but is not good enough. The data of mechanical performance and cutting tests about this kind of new tool material is given in this paper, it shows that C 3N 4 has a promising future. The anti-wear ability of cutting tool increases sharply after C 3N 4 being coated on HSS tool. Coated HSS drill also has some benefit after being reground. The tool life prolongs after C 3N 4 being coated on cemented carbide inserts, but is not so long as that of C 3N 4 coated HSS tool. When machining PRCM with C 3N 4 thin-film coated cemented carbide tool, the cutting performance is poor and it is much better when machining PRCM with PCBN, PCD compound plates and CVD thick-film coated cutting tool. Some relative aspects need to be deeply discussed and researched, e.g. the existing coating techniques is not good enough and should be improved in the future, the film thickness should be optimized and try to find out the most effective value, the binding force and mutual effect between coated film and substrate need to be studied furtherly, etc.
文摘Compared with the sintered polycrystalline diamond, the deposited thin film diamond has the great advantage on the fabrication of cutting tools with complex geometries such as drills. Because of their low costs for fabrication equipment and high performance on high speed machining non-ferrous metals and alloys, metal-compound materials, and hard brittle non-metals, diamond-coated drills find great potentialities in the commercial application. However, the poor adhesion of the diamond film on the substrate becomes the main technical barriers for the successful development and commercialization of diamond-coated tools. In this paper, diamond thin films were deposited on WC-Co based drills by the electron aided hot filament chemical vapor deposition (EACVD). A new multiple chemical pre-treatment technology including microwave oxidation, reaction in alkaline solution and cleaning by ultrasonic treatment in acid solution was developed and affects on the diamond adhesion strength, nucleation and surface morphology were investigated. At the same time, a special setup to fabricate diamond-coated drills was also developed and then the novel CVD process based on the varied parameters controlling model was presented, therefore the uniform quality and homogenized thickness of diamond coating could be available. From practical utilization viewpoint, the cutting performance of the diamond-coated drill was studied by drilling SiC particle reinforced aluminum matrix composite. The satisfied wear resistance and decrease of torque and thrust led to the long life of this kind of drill. This paper exhibited the meaningful work for the development of cutting tools with complex geometries and further extended the application of diamond material.
