Solution-processed chalcopyrite solar cells are widely regarded as a promising alternative method in reducing the cost compared with vacuum-based techniques.It is noted that the absorber layer usually needs to be prep...Solution-processed chalcopyrite solar cells are widely regarded as a promising alternative method in reducing the cost compared with vacuum-based techniques.It is noted that the absorber layer usually needs to be prepared under a high insert pressure(~1.6 atm)to suppress element loss or under a mild pressure but additional surface etching is needed for fabricating high efficient solar cell.Herein,a copper gradient structured precursor is proposed to prepare CuIn(S,Se)_(2)(CISSe)film under a mild pressure(1.1 atm).The designed gradient Cu not only promotes crystal grain growth and tailors the defects,but also avoids the surface etching of the formed CISSe film for the fabrication of high efficient solar cells.Further,Cu gradient design decreases the conduction band offset of heterojunction,boosting the carriers transport across the p-n heterojunction.Accordingly,a 13,35%efficient CISSe solar cell,comparable to the high efficient CISSe solar cell prepared by this method under high pressure or with film surface etching,is fabricated.This work provides a facile pathway to fabricate high efficient solution-processed chalcopyrite solar cell,avoiding high selenization pressure and film etching,and shows huge potential for solutionprocessed copper-based solar cells.展开更多
采用QM-1SP4-CL行星式球磨机将Mo、Cu粉简单混合和机械合金化后进行压片,在1250℃液相烧结1.5h后获得致密的Mo-30Cu合金;添加1.5%硬脂酸作造孔剂的Mo、Cu混合粉压片在1050℃固相烧结1.5h后获得孔隙率为33.186%的Mo-30Cu合金。利用激光...采用QM-1SP4-CL行星式球磨机将Mo、Cu粉简单混合和机械合金化后进行压片,在1250℃液相烧结1.5h后获得致密的Mo-30Cu合金;添加1.5%硬脂酸作造孔剂的Mo、Cu混合粉压片在1050℃固相烧结1.5h后获得孔隙率为33.186%的Mo-30Cu合金。利用激光热导仪测定所制备的Mo-30Cu合金的热导率。采用Maxwell模型、Hasselman and Johnson模型、单元结构模型和多相系统的传导性计算Mo-30Cu合金的理论热导率值。通过Mo-30Cu合金的热导率实测值与理论值的比较,得出适用于不同工艺状态的Mo-30Cu合金的热导率模型。展开更多
The hydrogenation of carbon dioxide over Cu-Mo/HZSM-5 composite catalysts prepared by an impregnation method has been studied. The reduction property and adsorption ability of the catalyst towards hydrogen and carbon ...The hydrogenation of carbon dioxide over Cu-Mo/HZSM-5 composite catalysts prepared by an impregnation method has been studied. The reduction property and adsorption ability of the catalyst towards hydrogen and carbon dioxide have been investigated by TPR and TPD-MS techniques. The results indicated that the addition of Mo increased the activity and dimethyl ether selectivity of Cu/HZSM-5 catalyst, the most active and selective for dimethyl ether was the catalyst with n (Cu)/n (Mo) = 5:1. The addition of Mo caused the TPR peaks of Cu/HZSM-5 to move to higher temperatures. CO2-TPD results revealed the raise of the adsorbability of the catalyst toward CO2.展开更多
基金supported by the National Natural Science Foundation of China(U1902218).
文摘Solution-processed chalcopyrite solar cells are widely regarded as a promising alternative method in reducing the cost compared with vacuum-based techniques.It is noted that the absorber layer usually needs to be prepared under a high insert pressure(~1.6 atm)to suppress element loss or under a mild pressure but additional surface etching is needed for fabricating high efficient solar cell.Herein,a copper gradient structured precursor is proposed to prepare CuIn(S,Se)_(2)(CISSe)film under a mild pressure(1.1 atm).The designed gradient Cu not only promotes crystal grain growth and tailors the defects,but also avoids the surface etching of the formed CISSe film for the fabrication of high efficient solar cells.Further,Cu gradient design decreases the conduction band offset of heterojunction,boosting the carriers transport across the p-n heterojunction.Accordingly,a 13,35%efficient CISSe solar cell,comparable to the high efficient CISSe solar cell prepared by this method under high pressure or with film surface etching,is fabricated.This work provides a facile pathway to fabricate high efficient solution-processed chalcopyrite solar cell,avoiding high selenization pressure and film etching,and shows huge potential for solutionprocessed copper-based solar cells.
文摘采用QM-1SP4-CL行星式球磨机将Mo、Cu粉简单混合和机械合金化后进行压片,在1250℃液相烧结1.5h后获得致密的Mo-30Cu合金;添加1.5%硬脂酸作造孔剂的Mo、Cu混合粉压片在1050℃固相烧结1.5h后获得孔隙率为33.186%的Mo-30Cu合金。利用激光热导仪测定所制备的Mo-30Cu合金的热导率。采用Maxwell模型、Hasselman and Johnson模型、单元结构模型和多相系统的传导性计算Mo-30Cu合金的理论热导率值。通过Mo-30Cu合金的热导率实测值与理论值的比较,得出适用于不同工艺状态的Mo-30Cu合金的热导率模型。
文摘The hydrogenation of carbon dioxide over Cu-Mo/HZSM-5 composite catalysts prepared by an impregnation method has been studied. The reduction property and adsorption ability of the catalyst towards hydrogen and carbon dioxide have been investigated by TPR and TPD-MS techniques. The results indicated that the addition of Mo increased the activity and dimethyl ether selectivity of Cu/HZSM-5 catalyst, the most active and selective for dimethyl ether was the catalyst with n (Cu)/n (Mo) = 5:1. The addition of Mo caused the TPR peaks of Cu/HZSM-5 to move to higher temperatures. CO2-TPD results revealed the raise of the adsorbability of the catalyst toward CO2.
