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Analysis and characterization of microstructures of a TiO_2/bamboo charcoal composite and modified poplar veneer
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作者 CHENG Da-li JIANG Shen-xue ZHANG Qi-sheng 《Forestry Studies in China》 CAS 2012年第3期240-245,共6页
A type of TiO/bamboo charcoal composite made by a dip-dry method was loaded onto wood veneer with a vacuum- pressure method in order to prepare modified poplar veneer. The pore structure parameters and surface morphol... A type of TiO/bamboo charcoal composite made by a dip-dry method was loaded onto wood veneer with a vacuum- pressure method in order to prepare modified poplar veneer. The pore structure parameters and surface morphology of the TiO2/ bamboo charcoal composite were determined and analyzed by means of a porosimetry analyzer and SEM. The results show that the surface morphology of the composite does not change after being loaded with nano TiO2. However, its specific surface area (359.814 m^2·g^-1), pore volume (0.317 cm^3.g^-1) and average pore diameter (3.526 nm) increased; particularly the cumulative volume of pores was increased by 65.83%. In addition, the distribution range of the pores was wider than that of the bamboo charcoal. Combining the SEM of unmodified and modified poplar veneer, the results of X-ray photoelectron spectroscopy revealed that actually some TiOz compounds, i.e., 4.08%, are imbedded in the modified poplar veneer. 展开更多
关键词 bamboo charcoal titanium dioxide TiO2/bamboo charcoal composite SEM XPS
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Coppicing ability of dry miombo woodland species harvested for traditional charcoal production in Zambia:a win–win strategy for sustaining rural livelihoods and recovering a woodland ecosystem 被引量:1
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作者 Stephen Syampungani Mulualem Tigabu +2 位作者 Nalukui Matakala Ferdinand Handavu Per Christer Oden 《Journal of Forestry Research》 SCIE CAS CSCD 2017年第3期549-556,共8页
The miombo woodland is one of the most extensive woodlands in Africa, supporting livelihoods based on biomass fuel for millions of rural people. However, there are growing concerns about the sustainability of harvesti... The miombo woodland is one of the most extensive woodlands in Africa, supporting livelihoods based on biomass fuel for millions of rural people. However, there are growing concerns about the sustainability of harvesting for biomass fuel (mainly charcoal). Thus, the aim of this study was to examine whether regeneration by coppice is a viable option for sustainably managing miombo woodlands for biomass fuel production. We tested the hypotheses that (1) species, stump diameter, stump height and time since cutting significantly affect the number of sprouts per cut stump (coppice density) and mean sprout height (shoot vigour) and (2) higher coppice density reduces shoot vigour due to competition among coppice shoots in a given stump. In an inventory in areas that were harvested for charcoal production by the local people, 369 stumps of 11 species were recorded with mean coppice stumps ranged from 6 to 84. The mean coppice density ranged from 5 to 8 shoots per stump while the mean height of coppice shoots ranged from 46 to 118 cm with marked interspecific variations. Stump size was signifi- cantly and positively correlated with coppice density for some of the species, but not with shoot vigour for the majority of the species. However, shoot vigour was significantly positively correlated to time since cutting of trees for nearly half of the species. Coppice density had a significant negative correlation with shoot vigour for two species, and a positive correlation for one species. In conclusion, the results provide evidence about the importance of coppice management as a win-win strategy for sustaining charcoal-based rural livelihoods and recovering the miombo woodland ecosystem. 展开更多
关键词 African woodlands charcoal production Forest management Regeneration Resprouting ability
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Effects of bamboo charcoal-based bio-fertilizer on wine bamboo sap yield and nutrient composition 被引量:1
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作者 Weicheng Li Haiyan Sheng 《Journal of Forestry Research》 SCIE CAS CSCD 2018年第4期1072-1081,共10页
To explore fertilization methods for wine bamboo cultivation in southwestern semi-arid areas of China, this study analyzed annual changes in sap yield and nutrient composition from May 2013 to March 2015 by using bamb... To explore fertilization methods for wine bamboo cultivation in southwestern semi-arid areas of China, this study analyzed annual changes in sap yield and nutrient composition from May 2013 to March 2015 by using bamboo charcoal-based bio-fertilizer (ZT) and organic fertilizer treatments (CK). The study also provided basic data for functional beverage preparation and for application of ZT. The results of the two experimental cycles revealed that under the ZT treatment, sap was available for collection from May, the beginning of the rainy season, to November, the beginning of the dry season. The period of abundance was July to October with the highest yield of sap of 3.18 L stalk-1 in September, 2014, still lower than the moso bamboo sap, which was likely due to the scale of sap production of monopodial bamboos being different from that of sympodial bamboos. In January, trace amounts of sap were still detected, suggesting that the effect of the treatment was significant. Moreover,in the dry season, soil water content and soil temperatures at 10-15 cm depths indicated that the fertilizer had the ability to maintain soil temperatures and moisture. In both fertilizer treatments, the correlation between the collected sap and environmental parameters was significant. In the ZT treatment for the entire 2 years, the effectual environ- mental factors were soil water at 10-15 cm, air tempera- tures, and wind speeds. The same determining factors were observed for the rainy season. In the CK treatments, the effectual environmental factors for the entire year and the rainy season were soil water at 0-5 cm and air moisture. The bamboo charcoal-based bio-fertilizer elevated the potassium, calcium, iron, manganese, copper, and total phosphorus content, simultaneously increasing the sap yield, protein and reducing sugar contents, and with a relative increase in sap pH. The wine bamboo sap con- tained 18 amino acids. Glutamic acid, alanine and proline were the most abundant. Compared to the controls, the treatment showed higher levels of all amino acids. Thus, the ZT treatment could be more beneficial to the development of root systems because the function of heat preservation and moisture retention prolong the sap collection period, increase sap yields, and elevate mineral element, conventional nutrients, and amino acid contents with evident fertilization effects and broader application prospects. 展开更多
关键词 Amino acids Bamboo charcoal-based fertilizer BIO-FERTILIZER Mineral elements Sympodial bamboo Wine bamboo sap
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Thermal testing methods in determination ofcharacterization of charcoals
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作者 刘守新 张世润 +1 位作者 礼波宁 朱文红 《Journal of Forestry Research》 CAS CSCD 2000年第1期60-62,共3页
Thermal analysis testing methods were used in determination of the characterization of charcoals. Thermogravimetry (TG) method was adopted to determine the composition of charcoals, which include moisture, volatiles, ... Thermal analysis testing methods were used in determination of the characterization of charcoals. Thermogravimetry (TG) method was adopted to determine the composition of charcoals, which include moisture, volatiles, fixed carbon and ash contents. The result showed that this method could detect the subtle change of charcoal composition, even the variation of different parts of material. Differential Thermal analysis (DTA) and related methods were also used to investigate reactivity of charcoals. The ignition temperature decrease with increasing carbon content was detected by these methods. 展开更多
关键词 Thermal analysis charcoal Ignition temperature THERMOGRAVIMETRY Differential thermal analysis
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Study on Applications of Nanotechnology in Bamboo Charcoal Fibre
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作者 Jiang Cheng Peng1, Cheng Jian Bing2, Lu Jian Ming2 (1.Huazhong science and technology university, 2.zhejiang university) 《China Textile》 2009年第4期44-48,50+52-56+58,共12页
Nanotechnology (NT) deals with materials from 1 to 100 nm in length. Internationaly, NT is defined as the understanding, manipulation, and control of matter at the length mentioned above, thus, the physical, chemical,... Nanotechnology (NT) deals with materials from 1 to 100 nm in length. Internationaly, NT is defined as the understanding, manipulation, and control of matter at the length mentioned above, thus, the physical, chemical, and biological properties of the materials (individual atoms, molecules, and bulk matter) can be engineered, synthesized, and altered to develop the next generation of improved materials, devices, structures, and systems. NT at the molecular level can be used to develop desired textile with special feature, such as high strength, unique surface structure, soft feeling, durability, water resistance, incombustibility, antimicrobial property, and so on. Indeed, NT has created numerous opportunities and challenges in the need of research, by the advancing of the technology in textile industry of China and the importing of bamboo charcoal fibers of nanotechnology from foreign countries. This paper focuses on summarizing recent applications of NT, its characters and functional test for bamboo charcoal fibers. 展开更多
关键词 NANO Study on Applications of Nanotechnology in Bamboo charcoal Fibre NT
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Charcoal kiln sites, associated landscape attributes and historic forest conditions:DTM-based investigations in Hesse(Germany)
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作者 Marcus Schmidt Andreas M?lder +2 位作者 Egbert Sch?nfelder Falko Engel Werner Fortmann-Valtink 《Forest Ecosystems》 SCIE CSCD 2016年第3期174-189,共16页
Background: An examination of the distribution of ancient charcoal kiln sites in the forest landscape seems to be worthwhile, since general trends in the selection of suitable kiln site locations in the past might be... Background: An examination of the distribution of ancient charcoal kiln sites in the forest landscape seems to be worthwhile, since general trends in the selection of suitable kiln site locations in the past might become obvious. In this way forest landscape elements with a more intense usage by charcoal burning can be identified. By doing this, we can expect to gain information on the former condition and tree species composition of woodland. Investigations on the spatial distribution of charcoal kiln sites in relation to landscape attributes are sparse, however, probably due to the high on-site mapping effort. The outstanding suitability of LiDAR-derived digital terrain models (DTMs) for the detection of charcoal kiln sites has been recently proved. Hence, DTM-based surveys of charcoal kiln sites represent a promising attempt to fill this research gap. Methods: Based on DTM-based surveys, we analyzed the spatial distribution of charcoal kiln sites in two forest landscapes in the German federal state of Hesse: Reinhardswald and Kellerwald-Edersee National Park. In doing so, we considered the landscape attibutes "tree species composition", "water supply status", "nutrient supply status", "soil complex classes", "altitude", "exposition", and "inclination". Results: We found that charcoal kiln sites were established preferably on hillside locations that provided optimal growing and regeneration conditions for European beech (Fagus sylvatico) due to their acidic brown soils and sufficient water supply. These results are in line with instructions for the selection of appropriate kiln site locations, found in literature from the 18th to the 19th century. Conclusions: We conclude that there were well-stocked, beech-dominated deciduous forest stands in northern Hesse before 1800, particularly at poorly accessible hillside locations. These large stocks of beech wood were utilized by the governments of the different Hessian territories through the establishment of ironworks and hammer mills. Our argumentation is well in line with findings which underline that not all Hessian forests were overexploited in the 18th century. Frequently repeated complaints about "wood shortage" seemed to be more a political instrument than reality, not only in Hesse, but all over Europe. Consequently, a differentiated assessment of woodland conditions in proto-industrial times is strictly advised, even if contemporary sources draw a dark picture of the historic situation. 展开更多
关键词 Airborne laser scanning charcoal production Cultural remains Digital terrain model Fagus sylvatica Forest history Historical ecology Landscape history Industrial history METALLURGY
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Effects of different charcoal treatments on the growth of Japanese larch seedlings inoculated with ectomycorrhizal fungi
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作者 Laiye Qu Mingjie Guo +3 位作者 Kobayashi Makoto Yoko Watanabe Gang Wu Takayoshi Koike 《Journal of Forestry Research》 2025年第1期371-378,共8页
To understand the roles of charcoal and ectomycorrhizal fungi(ECMF)on tree growth,which relates to the rehabilitation of forest ecosystems after forest fires,two experiments were set up in this study,the first was to ... To understand the roles of charcoal and ectomycorrhizal fungi(ECMF)on tree growth,which relates to the rehabilitation of forest ecosystems after forest fires,two experiments were set up in this study,the first was to determine the correct amount of charcoal for Japanese larch(Larix kaempferi Sarg.)seedling growth by applying oak charcoal to basic soil medium at ratios of 1:1,1:2,1:4 and 1:8 by volume.The second experiment investigated the combined effects of four types of charcoal:derived from oak wood,husks of buckwheat,rice and activated charcoal of larch wood,and two types of ECMF:Pt(Pisolithus tinctorius Pers.)and Ec(Pt+Rhizopogon spp.+Laccaria spp.+Scleroderma spp.)on the growth of Japanese larch seedlings.Our results show that growth was significantly stressed by large amounts charcoal applications.There were significant variations among the four types of charcoal on growth.We concluded that the addition of charcoal was the critical factor that influenced larch growth and ECMF formation.Rice charcoal and Ec stimulates the growth and nitrogen uptake of Japanese larch seedlings,thus the most suitable fungus and charcoal for practices is Ec-rice charcoal(1:8 charcoal to basic soil). 展开更多
关键词 charcoal Ectomycorrhizal fungi Growth characteristics Larix kaempferi Silviculture
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稻壳炭-石灰复合土的力学性能及微观机理研究
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作者 扈惠敏 郭雷 王博 《重庆交通大学学报(自然科学版)》 北大核心 2025年第3期57-64,共8页
采用生物质气化的副产品稻壳炭和石灰对路基土进行复合改性,测试稻壳炭-石灰复合土的无侧限抗压强度及动态回弹模量,采用傅里叶红外光谱、XRD及SEM分析其强度特性机理。结果表明:加入稻壳炭可以显著提高土的无侧限抗压强度,不同稻壳炭... 采用生物质气化的副产品稻壳炭和石灰对路基土进行复合改性,测试稻壳炭-石灰复合土的无侧限抗压强度及动态回弹模量,采用傅里叶红外光谱、XRD及SEM分析其强度特性机理。结果表明:加入稻壳炭可以显著提高土的无侧限抗压强度,不同稻壳炭、石灰掺量的复合土强度差异明显,稻壳炭、石灰复掺优于稻壳炭单掺,根据强度及节能降碳效果,推荐稻壳炭+石灰的掺量为2%+2%(2L+2R);复合土具有早强性,其后期强度提升缓慢,获得了抗压强度随龄期变化的预测公式;稻壳炭可以增强复合土的韧性,复合土的破坏形态随掺量的增加逐渐由脆性向塑性转变;复合土的动态回弹模量与围压、循环应力、龄期呈正相关,加入稻壳炭,复合土的动态回弹模量增大,建立的多状态动态回弹模量预估模型具有较高的精度;稻壳炭中活性SiO_(2)与石灰的火山灰反应是复合土强度迅速提升的主要原因,不同龄期的强度差异源自于C—S—H生成的数量和存在形式。 展开更多
关键词 道路工程 稻壳炭-石灰复合土 抗压强度 动态回弹模量 微观机理
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大容量注射剂中活性炭应用调研分析
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作者 周冲 赵敏 +4 位作者 董爱梅 张平 侯瑾 刘军田 武海军 《食品与药品》 2025年第1期I0009-I0012,共4页
目的通过了解活性炭在国内大容量注射剂中的应用现状、控制策略和变更意向等,为相关单位开展工艺变更研究工作提供参考,为后续监管工作提供支持。方法以问卷形式向国内大容量注射剂生产企业进行调研,调研内容包括现有大容量注射剂批准... 目的通过了解活性炭在国内大容量注射剂中的应用现状、控制策略和变更意向等,为相关单位开展工艺变更研究工作提供参考,为后续监管工作提供支持。方法以问卷形式向国内大容量注射剂生产企业进行调研,调研内容包括现有大容量注射剂批准文号数量、使用活性炭的批准文号数量、后续变更意愿,及现有工艺下对采用活性炭品种的工艺控制策略等。结果纳入调研有20家生产企业,共1081个大容量注射剂批准文号,大部分在2015年之前获批,工艺中使用活性炭的产品占该阶段总数的90.24%。虽然调研中大部分企业认为现有技术条件下所持有的大容量注射剂品种不具有使用活性炭的必要性,但完成变更的品种较少,仅占总数的12.36%。现阶段企业主要通过提高控制标准等方式控制产品质量。结论调研结果表明,因工艺中去除活性炭的变更涉及成本、政策等方面,在目前政策没有强制性要求去掉活性炭的条件下,大部分企业扔持观望态度。本次调研为后续相关政策的制定提供了参考。 展开更多
关键词 大容量注射剂 活性炭 变更 控制策略
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稻壳炭强化城市污泥蚯蚓堆肥过程中重金属变化特征 被引量:2
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作者 王兴明 徐岚 +4 位作者 范廷玉 储昭霞 董众兵 董鹏 邓瑞来 《农业环境科学学报》 CAS CSCD 北大核心 2024年第7期1648-1656,共9页
为探讨稻壳炭强化蚯蚓堆肥对污泥性质和重金属的影响,本研究以城市污泥为研究对象,添加不同比例稻壳炭对蚯蚓堆肥进行强化处理,探究不同生物炭剂量(污泥干质量的2%、4%、6%、8%)对城市污泥蚯蚓堆肥过程中重金属有效态以及赋存形态的影... 为探讨稻壳炭强化蚯蚓堆肥对污泥性质和重金属的影响,本研究以城市污泥为研究对象,添加不同比例稻壳炭对蚯蚓堆肥进行强化处理,探究不同生物炭剂量(污泥干质量的2%、4%、6%、8%)对城市污泥蚯蚓堆肥过程中重金属有效态以及赋存形态的影响。结果表明:堆肥过程中pH呈先上升后降低的趋势,电导率先降低后升高,有机质呈下降趋势;与对照组(不添加稻壳炭)相比,添加不同比例稻壳炭强化后的电导率、有机质分别降低28.96%~47.46%、2.84%~18.87%;稻壳炭强化的污泥堆肥中养分增加,总氮、总磷和总钾在8%添加量时分别提高9.89%、24.39%和2.51%。当稻壳炭添加到蚯蚓堆肥后,重金属从易迁移转化形态向稳定态转化,在8%添加比例时,Cd、Cu、Ni的残渣态占比较对照组分别提高3.57、19.12、9.27个百分点,有效态分别降低56.25%、34.22%、28.20%;添加4%稻壳炭使Pb由可交换态、碳酸盐结合态向稳定的有机结合态转化,且有效态降低27.69%。相关性分析发现稻壳炭强化蚯蚓堆肥,升高堆体pH降低了污泥中Cd、Cu、Ni、Pb有效态含量。研究表明,稻壳炭强化蚯蚓堆肥可显著提升城市污泥营养元素,改善理化性质,提高污泥中重金属钝化效率。 展开更多
关键词 蚯蚓 稻壳炭 城市污泥堆肥 重金属形态
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有机肥配施生物质炭对根际/非根际土壤氮赋存形态的影响 被引量:1
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作者 李越 王颖 +3 位作者 熊子怡 谢军 王子芳 高明 《土壤学报》 CAS CSCD 北大核心 2024年第2期495-505,共11页
阐明化肥和有机肥配施生物质炭对根际/非根际土壤养分和氮赋存形态的影响,有助于农田氮的高效利用及科学管理。采用盆栽试验方法,设置不施肥(CK)、单施化肥(CF)、施有机肥(M)、化肥配施生物质炭(CFB)、有机肥配施生物质炭(MB)、新鲜有... 阐明化肥和有机肥配施生物质炭对根际/非根际土壤养分和氮赋存形态的影响,有助于农田氮的高效利用及科学管理。采用盆栽试验方法,设置不施肥(CK)、单施化肥(CF)、施有机肥(M)、化肥配施生物质炭(CFB)、有机肥配施生物质炭(MB)、新鲜有机肥配施生物质炭(FMB)6个处理,通过测定根际及非根际土壤养分含量和土壤氮赋存形态,阐明不同施肥处理对氮形态转化的影响。结果表明:与CK处理相比,MB处理提高非根际及根际土壤pH 0.32和0.28个单位,FMB处理提高根际土壤pH 0.63个单位;MB和FMB处理分别提高根际土壤有机质含量25.4%和84.9%,同时显著提高根际土壤全氮含量25.4%和50.9%,表现出明显的根际效应。施肥能显著提高土壤离子交换态氮(IEF-N)含量,以CF和CFB处理的效果最好。施用有机肥和生物质炭能显著提高土壤碳酸盐结合态氮(CF-N)含量,以M和MB处理效果最好,且CF-N存在根际富集效应。配施生物质炭(CFB、MB和FMB)处理能促进土壤非可转化态氮(NTF-N)向铁锰氧化物结合态氮(IMOF-N)和有机硫化物结合态氮(OSF-N)这两种活性更高的氮形态转化,其中IMOF-N和OSF-N分别占可转化态氮的35.9%~61.7%和26.7%~46.6%,是根际及非根际土壤可转化态氮(TF-N)的主要成分。因此,有机肥配施生物质炭是改善根际及非根际土壤养分和调控氮转化有效的方式。 展开更多
关键词 有机肥 生物质炭 根际土 非根际土 土壤养分 氮形态
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喷气涡流纺长片段竹节段彩纱的设计与生产
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作者 张会青 马洪才 +1 位作者 王秀燕 孔令乾 《棉纺织技术》 CAS 2024年第8期77-80,共4页
探讨有色超短纤维在喷气涡流纺花式纱开发中的应用及生产要点。采用有色粘胶超短纤维与本色竹浆纤维、椰炭改性涤纶纤维,在并条机上加装竹节装置,利用喷气涡流纺纱技术纺制成长片段竹节段彩纱。针对粘胶纤维长度相对较短的特点,工艺上... 探讨有色超短纤维在喷气涡流纺花式纱开发中的应用及生产要点。采用有色粘胶超短纤维与本色竹浆纤维、椰炭改性涤纶纤维,在并条机上加装竹节装置,利用喷气涡流纺纱技术纺制成长片段竹节段彩纱。针对粘胶纤维长度相对较短的特点,工艺上尝试采用短流程、减小隔距、降低打击件速度等技术措施。结果表明:开发的喷气涡流纺段彩纱具有段彩片段长、生产效率高的特点,其在布面上色点朦胧,时而形成连续分布,时而散点分布,形成不同于传统段彩纱的独特风格。 展开更多
关键词 超短粘胶纤维 椰炭改性涤纶 竹浆纤维 竹节段彩纱 喷气涡流纺 新型花式纱线
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灰竹炭纤维/大麻纤维/Coolplus纤维/棉精梳混纺柔洁纱的可纺性研究与生产实践 被引量:1
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作者 赵博 《江苏丝绸》 2024年第2期10-17,共8页
本文结合生产实践,通过设备改造和半制品及纱测试,分析和讨论各因素对灰竹炭纤维/大麻纤维/Coolplus纤维/棉精梳混纺柔洁纱质量的影响,研究前纺工序和细纱工序通过优化工艺参数、采用新型纺纱专件、合理控制车间的温湿度等,明显地提高... 本文结合生产实践,通过设备改造和半制品及纱测试,分析和讨论各因素对灰竹炭纤维/大麻纤维/Coolplus纤维/棉精梳混纺柔洁纱质量的影响,研究前纺工序和细纱工序通过优化工艺参数、采用新型纺纱专件、合理控制车间的温湿度等,明显地提高了灰竹炭纤维/大麻纤维/Coolplus纤维/棉精梳混纺柔洁纱质量。 展开更多
关键词 大麻纤维 灰竹炭纤维 COOLPLUS纤维 混纺柔洁纱 设计工艺 因素 分析 措施
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梨木炭蒸汽气化制取富氢燃气的试验研究
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作者 张彪 兰祯 别如山 《工业锅炉》 2024年第1期1-7,共7页
生物质气化技术已得到广泛的应用,但气化过程产生的焦油会影响设备稳定运行。为了大幅减少焦油的干扰,以梨木的热解炭为原料,在管式炉中进行水蒸气气化制取富氢燃气试验研究,探究了反应温度、K_(2)CO_(3)添加量及利用次数对气化特性的... 生物质气化技术已得到广泛的应用,但气化过程产生的焦油会影响设备稳定运行。为了大幅减少焦油的干扰,以梨木的热解炭为原料,在管式炉中进行水蒸气气化制取富氢燃气试验研究,探究了反应温度、K_(2)CO_(3)添加量及利用次数对气化特性的影响。结果表明:900℃时H_(2)的产气量为2.19 L/g,合成气中H_(2)含量超过58%;K_(2)CO_(3)添加量为10%时产气效果最佳,此时合成气中H_(2)+CO含量达到了88.5%。当K_(2)CO_(3)催化剂在第三次利用时,仍有较好的催化效果。 展开更多
关键词 梨木炭 蒸汽气化 K_(2)CO_(3) 富氢气体
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刺竹活性炭的制备及吸附性能研究 被引量:4
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作者 田华宇 刘焕 +3 位作者 王国睿 郝海彦 王天赐 张文标 《浙江农林大学学报》 CAS CSCD 北大核心 2024年第2期429-436,共8页
【目的】为充分利用刺竹Bambusa sinospinosa材,提高其利用率,进一步探究刺竹活性炭的生产工艺及使用领域,以达到提升其附加值的目的。【方法】以刺竹炭为原料,使用水蒸气活化法,采用单因素实验法探究温度、时间、水蒸气量对刺竹活性炭... 【目的】为充分利用刺竹Bambusa sinospinosa材,提高其利用率,进一步探究刺竹活性炭的生产工艺及使用领域,以达到提升其附加值的目的。【方法】以刺竹炭为原料,使用水蒸气活化法,采用单因素实验法探究温度、时间、水蒸气量对刺竹活性炭的得率及吸附性能的影响。使用傅里叶红外吸收光谱仪(FTIR)、X-射线衍射仪(XRD)、比表面积及孔隙度分析仪(BET)、扫描电子显微镜(SEM)等对刺竹活性炭进行测试和表征。【结果】①刺竹活性炭的最优活化工艺为:活化温度875℃、活化时间2.0 h、水蒸气量0.50 L·h^(−1)。在该工艺下制备的刺竹活性炭得率为29.07%,强度达97.68%,碘吸附值为1235.03 mg·g^(−1),亚甲基蓝吸附值为276 mg·g^(−1),吸附性能较好。②红外吸收光谱表明:经活化之后峰值在3130、3010、1670 cm^(−1)等处变弱,876、809、747 cm^(−1)处吸收峰消失,但主要峰依然存在;XRD分析表明:活性炭中含有石墨α轴结构;经比表面积测试和电镜观察,最优工艺活化后的刺竹活性炭孔隙发达,孔容、孔径都有不同程度的提升,总孔容为0.489 cm^(3)·g^(−1),微孔容为0.388 cm^(3)·g^(−1),平均孔径为23.378 nm,BET比表面积为837.005 m^(2)·g^(−1)。【结论】使用最优活化工艺所制备的刺竹活性炭具有较好的性能,可用于吸附、除污等不同场合。 展开更多
关键词 刺竹 活性炭 水蒸气活化 吸附性能 活化工艺
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生物炭与传统碳质材料的关系
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作者 吴郅俊 戴荣 +2 位作者 文俊 宋洪川 廖承菌 《材料导报》 EI CAS CSCD 北大核心 2024年第S02期89-92,共4页
近年来生物炭已成为多学科的研究热点。但生物炭与传统碳质材料之间的关系尚未有学者给出明确的结论。因此,本文以生物炭和传统碳质材料的概念为切入点,对它们之间的关系进行分析。随着研究的深入,生物炭的研究将会与木炭、黑炭、火炭... 近年来生物炭已成为多学科的研究热点。但生物炭与传统碳质材料之间的关系尚未有学者给出明确的结论。因此,本文以生物炭和传统碳质材料的概念为切入点,对它们之间的关系进行分析。随着研究的深入,生物炭的研究将会与木炭、黑炭、火炭和活性炭等传统碳质材料在广度和深度上互相支撑,从而进一步推动生物炭的研究。 展开更多
关键词 生物炭 木炭 黑炭 火炭 活性炭
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竹炭掺杂铋系光催化剂的制备及其对有机污染物的降解研究
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作者 朱亚玮 房桂干 +4 位作者 盘爱享 尹航 谢章红 沈葵忠 田庆文 《中国造纸》 CAS 北大核心 2024年第7期191-198,共8页
本研究以竹浆备料废弃物为原料,通过磷酸活化法制得竹炭,再利用水热法制备了竹炭/BiOCl复合催化剂,并探究了竹炭添加量和水热温度对复合催化剂光催化性能的影响。结果表明,竹炭保留了竹子本身的孔道结构,改变竹炭的添加量可实现对竹炭/B... 本研究以竹浆备料废弃物为原料,通过磷酸活化法制得竹炭,再利用水热法制备了竹炭/BiOCl复合催化剂,并探究了竹炭添加量和水热温度对复合催化剂光催化性能的影响。结果表明,竹炭保留了竹子本身的孔道结构,改变竹炭的添加量可实现对竹炭/BiOCl复合催化剂形貌的调控,为吸附污染物提供了良好的条件。竹炭和BiOCl之间发生的强相互作用,显著改善了BiOCl的吸附-光催化性能和氧空位含量,提高了光生电子传输效率,从而优化了复合催化剂的光催化降解效果。在水热温度140℃和竹炭添加量5%的条件下所制复合催化剂5BC-140,其可见光催化性能最佳,对罗丹明B的去除率在30 min内即可达86.5%,一阶动力学常数k为BiOCl的4.2倍,且具有优异的稳定性和可循环性能。 展开更多
关键词 竹材废弃物 竹炭 光催化 BiOCl 高值化利用
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Ti_(1)Li_(3)Al_(2)-LDHs@OBAC的结构及其光催化CO_(2)还原特性
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作者 凌洁 周安宁 +2 位作者 王文珍 李瑞琪 李纹龙 《石油学报(石油加工)》 EI CAS CSCD 北大核心 2024年第5期1275-1286,共12页
采用尿素水热法制备了类水滑石(Ti_(1)Li_(3)Al_(2)-LDHs),将其负载于氧化椰壳活性炭(OBAC)表面制得Ti_(1)Li_(3)Al_(2)-LDHs@OBAC光催化剂,通过XRD、FT-IR、SEM、TEM、N_(2)吸附-脱附等温线、XPS、CO_(2)静态吸附等温线、CO_(2)-TPD、U... 采用尿素水热法制备了类水滑石(Ti_(1)Li_(3)Al_(2)-LDHs),将其负载于氧化椰壳活性炭(OBAC)表面制得Ti_(1)Li_(3)Al_(2)-LDHs@OBAC光催化剂,通过XRD、FT-IR、SEM、TEM、N_(2)吸附-脱附等温线、XPS、CO_(2)静态吸附等温线、CO_(2)-TPD、UV-Vis和EIS等手段对其进行表征,基于Ti_(1)Li_(3)Al_(2)-LDHs构建Ti_(1)Li_(3)Al_(2)-LDHs@OBAC的结构模型,利用CO_(2)-水反应体系研究其光催化CO_(2)还原特性。结果表明:Ti_(1)Li_(3)Al_(2)-LDHs中Ti^(4+)、Li^(+)取代MgAl-LDHs中Mg^(2+)形成以Ti^(4+)、Li^(+)为中心的八面体结构,斜方堆积(3R)形成2D层片结构,层间阴离子为CO_(2)-3。Ti_(1)Li_(3)Al_(2)-LDHs@OBAC呈球状包覆结构,六边形层片Ti_(1)Li_(3)Al_(2)-LDHs垂直生长于OBAC表面;在反应温度80℃、反应时间8 h条件下,Ti_(1)Li_(3)Al_(2)-LDHs@OBAC的光催化CO_(2)还原CO产率、CH 4产率和CO/CH 4产率比分别为42.62、1.18μmol/g和36。OBAC的碳缺陷增强了催化剂对CO_(2)的吸附活化能力,显著提高Ti_(1)Li_(3)Al_(2)-LDHs@OBAC光催化CO_(2)还原活性。 展开更多
关键词 类水滑石 光催化 CO_(2)还原 活性炭 结构 复合材料
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淀粉胶枣木基炭缓释肥的制备及缓释性能分析
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作者 赵苏亚 杨艳爱 +3 位作者 周岭 吕喜风 姚江 卢亚玲 《新疆农业科学》 CAS CSCD 北大核心 2024年第9期2315-2322,共8页
【目的】研究淀粉胶枣木基炭缓释肥的制备及缓释性能。【方法】以枣木炭基为载体、自制改性淀粉为胶黏剂、尿素为肥料,在自制成型模具上制造出枣木炭基缓释肥,研究5个因素(即水分加入量、成型温度、成型压力、炭肥比以及胶粘剂加入量)... 【目的】研究淀粉胶枣木基炭缓释肥的制备及缓释性能。【方法】以枣木炭基为载体、自制改性淀粉为胶黏剂、尿素为肥料,在自制成型模具上制造出枣木炭基缓释肥,研究5个因素(即水分加入量、成型温度、成型压力、炭肥比以及胶粘剂加入量)等对缓释肥抗压性能和缓释性能的影响,优化缓释肥成型的工艺参数、缓释性能以及机械性能。【结果】在7 kN的成型压力、20%的含水量、60℃的成型温度,对纯炭粉体的成形与抗压性能有较好的影响;将尿素与炭粉混合后成型,可以提高颗粒的强度,相同成肥情况下,枣木炭和尿素比例为4:1时,此时颗粒的抗压强度最高,而胶粘剂比例为4%时,颗粒的抗压强度最高。【结论】采用不同比例配制得的缓释肥,与传统相比,其对氮的积累释放率都较好,且以4%的胶黏剂添加用量为佳。与纯尿素肥料相比,所制备的缓释肥颗粒具有较好的抗压能力,可以有效地改善缓释性能。 展开更多
关键词 枣木炭 尿素 缓释肥料 抗压性能 缓释特性
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非金属掺杂生物质多孔碳基材料的合成及对MgH_(2)储氢性能的研究
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作者 阎帅 宋静雅 +3 位作者 游卓 左逾 叶宏亮 张田力 《化工新型材料》 CAS CSCD 北大核心 2024年第S01期122-127,共6页
氢化镁(MgH_(2))作为一种固态储氢材料,因其安全性高、储氢量大及镁资源丰富等优点,吸引了大量的学者对其进行研究。然而其稳定的热力学性能、较差的动力学性能及欠佳的循环稳定性导致其商业化道路受阻。采用一步溶剂热法和高温碳化法... 氢化镁(MgH_(2))作为一种固态储氢材料,因其安全性高、储氢量大及镁资源丰富等优点,吸引了大量的学者对其进行研究。然而其稳定的热力学性能、较差的动力学性能及欠佳的循环稳定性导致其商业化道路受阻。采用一步溶剂热法和高温碳化法制备了以廉价生物质原料为基体的非金属磷掺杂碳基材料(P/BC),并通过进一步的高能球磨将其引入MgH_(2)储氢体系中,得到MgH_(2)@P/BC复合储氢体系。结果表明:P/BC降低了MgH_(2)晶粒的尺寸大小,且极大地提升了该复合储氢体系的储氢性能,使其在400℃下,10min内可释放约6%的氢气,同时该体系的放氢活化能相比纯MgH_(2)体系降低了16.77kJ/mol。P/BC材料较大的比表面积和优异的孔隙结构,增加了氢气的吸附速率并提供更多的活性位点,如表面缺陷和多相界面等。此外,P元素的掺杂可以调控碳基体的表面电子结构,与多孔碳共同形成了催化-限域效应,进而对复合储氢材料的吸放氢性能起到了积极的促进作用。 展开更多
关键词 储氢 氢化镁 生物质炭 催化效应 限域效应
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