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Ablative Properties of SiC_(p) Doped C_(f)/Li_(2)O-Al_(2)O_(3)-SiO_(2) Composites
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作者 LIN Yuanwei JING Zhao +4 位作者 CHEN Hetuo LI Jiaheng QIN Xianpeng ZHOU Guohong WANG Shiwei 《无机材料学报》 北大核心 2025年第10期1153-1162,共10页
In a high heat flux ablative environment,the surface temperature of aircraft rises rapidly,leading to traditional high thermal conductivity materials being ineffective at protecting internal metal components.In this s... In a high heat flux ablative environment,the surface temperature of aircraft rises rapidly,leading to traditional high thermal conductivity materials being ineffective at protecting internal metal components.In this study,continuous carbon fiber reinforced Li_(2)O-Al_(2)O_(3)-SiO_(2)(C_(f)/LAS)glass ceramic composites doped with SiC particles(SiC_(p))were prepared by slurry immersion winding and hot pressing sintering.Effect of matrix crystallinity on ablative properties of the composites under ultra-high heat flux was investigated.By utilizing heat absorption and low thermal conductivity characteristics associated with SiO_(2)gasification within composite materials,both surface and internal temperatures of these materials are effectively reduced,thereby ensuring the safe operation of aircraft and electronic devices.Results indicate that the average linear ablation rate of composites doped with 10%(in mass)of SiC_(p)significantly decreases at a heat flux of 20 MW/m^(2).Transmission electron microscope observation reveals that the doped glass matrix exhibits increased crystallinity,reduced internal stress,and minimized lattice distortion,thereby enhancing the composites’high-temperature performance.However,excessive SiC_(p)doping leads to reduced crystallinity and deteriorated ablation performance.Ultimately,the average linear ablation rate of C_(f)/LAS composites with 10%(in mass)SiC_(p)at 20 MW/m^(2)heat flux is comparable to that of commercial carbon/carbon composites,accompanied by providing lower thermal conductivity and higher bending strength.This novel high-performance C_(f)/LAS composite is cost-effective,short-cycled,and suitable for mass production,offering promising potential for widespread application in ablation-resistant components of hypersonic vehicles. 展开更多
关键词 ablation-resistant C_(f)/LAS composite sic doping crystallinity of glass matrix long-range ordered
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Joining and machining of(ZrB2-SiC)and(Cf-SiC)based composites
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作者 R.V.Krishnarao G.Madhusudan reddy V.V.Bhanuprasad 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2018年第5期385-395,共11页
Filler materials of(ZrB_2-SiC-B_4C-YAG) composite were developed for gas tungsten arc welding(GTAW) of the ZrB_2-SiC and Cf-SiC based composites to themselves and to each other. Reaction with filler material,porosity ... Filler materials of(ZrB_2-SiC-B_4C-YAG) composite were developed for gas tungsten arc welding(GTAW) of the ZrB_2-SiC and Cf-SiC based composites to themselves and to each other. Reaction with filler material,porosity and cracks were not observed at weld interfaces of all the joints. Penetration of filler material in to voids and pores existing in the Cf-SiC composites was observed. Average shear strength of 25.7 MPa was achieved for joints of Cf-SiC composites. By incorporation of Cf-SiC(CVD) ground short fibre reinforcement the(ZrB_2-SiC-B_4C-YAG) composite was machinable with tungsten carbide tool. The joint and machined composites were resistance to oxidation and thermal shock when exposed to the oxy-propane flame at 2300℃ for 300s. The combination of(ZrB_2-SiC-B_4C-YAG) and Cf-SiC based composites can be used for making parts like thermal protection system or nozzles for high temperature applications. 展开更多
关键词 ZRB2-sic composite SINTERING MACHINING Gas TUNGSTEN ARC welding
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Research on the Characters of the Cutting Force in Vibration Cutting Particle Reinforced Metal Matrix Composites SiC_p/Al 被引量:3
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作者 LIU Chuan-shao 1, ZHAO Bo 1,2, GAO Guo-fu 1, JIAO F eng 1 (1. Department of Mechanical Engineering, Jiaozuo Institute of Techno logy, Henan 454000, China 2. Institute of Mechanical Engineering, Shanghai Jiaotong University, Shanghai 200030, China) 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期74-75,共2页
In this paper, turning experiments of machining particle reinforced metal matri x composites(PRMMCs) SiC p/Al with PCD tools have been carried out. The cutting force characteristics in ultrasonic vibration turning com... In this paper, turning experiments of machining particle reinforced metal matri x composites(PRMMCs) SiC p/Al with PCD tools have been carried out. The cutting force characteristics in ultrasonic vibration turning compared with that in com mon turning were studied. Through the single factor experiments and multiple fac tor orthogonal experiments, the influences of three kinds of cutting conditions such as cutting velocity, amount of feed and cutting depth on cutting force were analyzed in detail. Meanwhile, according to the experimental data, the empirica l formula of main cutting force in ultrasonic vibration turning was conclude d. According to the test results, the cutting force is direct proportion to cutt ing depth basically according to the relation between cutting force and other fa ctors, which is similar to that of common cutting, so is the feed rate, but the influence is not so big. The influence of cutting speed is larger than that of f eed rate on cutting force because the efficient cutting time increases in vibrat ion cycle with the increase of cutting speed, which causes cutting force to incr ease. The research results indicate: (1) Ultrasonic vibration turning possesses much lower main cutting force than that in common turning when adopting smaller cutting parameters. If using larger cutting parameters, the difference will inco nspicuous. (2) There are remarkable differences of cutting force-cutting veloci ty characteristics in ultrasonic vibration turning from that in common turning m ainly because built-up edge does not emerge in ultrasonic turning unlike common turning in corresponding velocity range. (3) In ultrasonic vibration cutting, t he influence of cutting velocity on cutting force is most obvious among thre e cutting parameters and the influence of feed is smallest. So adopting lower cu tting velocity and larger cutting depth not only can reduce cutting force effect ively but also can ensure cutting efficiency. (4) The conclusions are useful in precision and super precision manufacturing thin-wall pieces. 展开更多
关键词 composite sic p/Al PCD tool ultrasonic vibrati on turning cutting force
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GE公司预浸料-熔渗工艺SiCf/SiC复合材料应用研究历程及启示 被引量:1
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作者 王雅娜 李天山 +1 位作者 王海润 焦健 《航空材料学报》 北大核心 2025年第2期1-17,共17页
美国通用电气航空公司(简称GE公司)自20世纪80年代开始预浸料-熔渗工艺SiCf/SiC复合材料的研发,组织数百名科学家和工程师,历时30年、累计投入近15亿美金,最终实现了该材料在发动机领域的成功应用与商业化。本文详细阐述了GE公司预浸料... 美国通用电气航空公司(简称GE公司)自20世纪80年代开始预浸料-熔渗工艺SiCf/SiC复合材料的研发,组织数百名科学家和工程师,历时30年、累计投入近15亿美金,最终实现了该材料在发动机领域的成功应用与商业化。本文详细阐述了GE公司预浸料-熔渗工艺SiCf/SiC复合材料螺旋式的发展历程,聚焦其在燃气轮机和航空发动机热端部件领域的创新实践,通过多个典型热端构件研发的案例分析,揭示了GE公司以“需求牵引-技术验证-工程迭代”为核心的研发范式,并深度解构了GE公司的7FA发动机涡轮外环组件跨越10年的渐进式设计迭代路径,层层解构其服役失效逆向反馈与正向设计牵引的协同优化逻辑。针对国外发展现状,本文进一步解读了GE公司通过垂直整合制造链,引入数字孪生工艺优化,建立机器学习检测体系,构建“材料-工艺-检测”三位一体的技术壁垒。GE公司发展经验表明,技术突破需兼顾长期基础研究与敏捷工程迭代,国内应通过技术体系革新,以典型构件为牵引,建立“设计-制造-考核”闭环的研发流程,建立多学科平等协同机制。强化基础能力,依托高校和国家级研发中心开展机理研究,实施热-力-化学多场耦合约束下的多维度协同优化,尽快推进产业生态构建,整合零散资源,搭建“产学研”快速验证平台。提早布局数字化赋能,实施全链条数据采集与AI嵌入。最后通过深度凝练外在相关技术领域的成功经验,结合国内实际情况,提出了涵盖“基础研究-中试验证-标准建设-产业协同”的自主化发展路线图,旨在为国内高推重比航空发动机用陶瓷基复合材料技术攻关提供方法论层面的战略参考。 展开更多
关键词 sicF/sic复合材料 预浸料-熔渗 发动机 应用研究
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Improved oxidation resistance of chemical vapor reaction SiC coating modified with silica for carbon/carbon composites 被引量:4
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作者 杨鑫 邹艳红 +4 位作者 黄启忠 苏哲安 常新 张明瑜 肖勇 《Journal of Central South University》 SCIE EI CAS 2010年第1期1-6,共6页
To protect carbon/carbon (C/C) composites from oxidation, a SiC coating modified with SiO2 was prepared by a complex technology. The inner SiC coating with thickness varying from 150 to 300 μm was initially coated by... To protect carbon/carbon (C/C) composites from oxidation, a SiC coating modified with SiO2 was prepared by a complex technology. The inner SiC coating with thickness varying from 150 to 300 μm was initially coated by chemical vapor reaction (CVR): a simple and cheap technique to prepare the SiC coating via siliconizing the substrate that was exposed to the mixed vapor (Si and SiO2) at high temperatures (1 923?2 273 K). Then the as-prepared coating was processed by a dipping and drying procedure with tetraethoxysilane as source materials to form SiO2 to fill the cracks and holes. Oxidation tests show that, after oxidation in air at 1 623 K for 10 h and thermal cycling between 1 623 K and room temperature 5 times, the mass loss of the CVR coated sample is up to 18.21%, while the sample coated with modified coating is only 5.96%, exhibiting an obvious improvement of oxidation and thermal shock resistance of the coating. The mass loss of the modified sample is mainly contributed to the reaction of C/C substrate with oxygen diffusing through the penetrating cracks formed in thermal shock tests. 展开更多
关键词 carbon/carbon composites COATING OXIDATION sic
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钎焊金刚石铣磨头加工Cf/SiC复合材料微孔的试验研究
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作者 洪猛杰 陈卓 +3 位作者 周嘉怡 王海旭 王建宇 黄国钦 《中国机械工程》 北大核心 2025年第3期391-397,共7页
Cf/SiC陶瓷基复合材料是一种集各向异性和非均质结构为一体的典型高硬脆性难加工材料,对其进行孔径小于5 mm的微孔加工难度大,一直都是业界研究热点。采用三种小直径金刚石铣磨头进行制孔加工试验,研究铣磨头制备的方法和末端几何形状... Cf/SiC陶瓷基复合材料是一种集各向异性和非均质结构为一体的典型高硬脆性难加工材料,对其进行孔径小于5 mm的微孔加工难度大,一直都是业界研究热点。采用三种小直径金刚石铣磨头进行制孔加工试验,研究铣磨头制备的方法和末端几何形状对钻进力、使用寿命、微孔缺陷及工具表面质量的影响。结果表明,取芯钎焊铣磨头所制微孔缺陷最少且使用寿命为平底电镀铣磨头的3.6倍、平底钎焊铣磨头的2倍;取芯钎焊铣磨头具有端面取芯结构,可有效减小钻进力,在工具使用寿命和工件加工表面质量上与另两种铣磨头相较也有明显提升。 展开更多
关键词 cf/sic陶瓷基复合材料 各向异性 微孔加工 以磨代铣 金刚石铣磨头
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Processing and properties of 2D SiC/SiC composites by precursor infiltration and pyrolysis 被引量:2
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作者 于海蛟 周新贵 +3 位作者 王洪磊 赵爽 羊建高 黄泽兰 《Journal of Central South University》 SCIE EI CAS 2009年第2期190-194,共5页
Two-dimensional plain-weave silicon carbide fiber fabric reinforced silicon carbide(2D-SiC/SiC)composites were molded by stacking method and densified through precursor infiltration and pyrolysis(PIP)process.SiC coati... Two-dimensional plain-weave silicon carbide fiber fabric reinforced silicon carbide(2D-SiC/SiC)composites were molded by stacking method and densified through precursor infiltration and pyrolysis(PIP)process.SiC coating was deposited as the fiber/matrix interphase layer by chemical vapor deposition(CVD)technique.Fiber/matrix debonding and relatively long fiber pullouts were observed on the fracture surfaces.Additionally,the flexural strength and elastic modulus of the composites with and without fiber/matrix interphase layer were investigated using three-point bending test and single-edge notched beam test.The results show that the fiber fraction and the porosity of 2D-SiC/SiC composites with and without coating are 27.2%(volume fraction)and 11.1%,and 40.7%(volume fraction)and 7.5%,respectively.And the flexural strength and elastic modulus of 2D-SiC/SiC composites with and without coating are 363.3 MPa and 127.8 GPa,and 180.2 MPa and 97.2 GPa,respectively.With a proper thickness,the coating can effectively adjust the fiber/matrix interface,thus causing a dramatic increase in the mechanical properties of the composites. 展开更多
关键词 sic/sic composites COATING precursor infiltration and pyrolysis chemical vapor deposition
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Corrosion behavior of SiC foam ceramic reinforced Al-23Si composites in NaCl solution 被引量:1
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作者 诸建彬 闫洪 +1 位作者 叶何远 艾凡荣 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第9期1934-1940,共7页
SiC foam ceramic reinforced aluminum matrix composites(SFCAMCs)were prepared by squeeze casting aluminum alloy(Al-23Si)into the SiC foam ceramic with different pore sizes,and the corrosion behavior of the SFCAMCs was ... SiC foam ceramic reinforced aluminum matrix composites(SFCAMCs)were prepared by squeeze casting aluminum alloy(Al-23Si)into the SiC foam ceramic with different pore sizes,and the corrosion behavior of the SFCAMCs was studied in NaCl solutions.Static immersion corrosion tests were conducted at 20°C,50°C and 80°C,respectively.Corrosion morphology and products were analyzed by scanning electron microscope,energy dispersive system and X-ray diffraction.It was found that the corrosion rate of SFCAMCs increases as the temperature rising,and the bigger pore size of SiC foam ceramic reinforcement,the better corrosion resistance of SFCAMCs. 展开更多
关键词 sic ceramic foam aluminum matrix composites corrosion NACL
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Gas tungsten arc welding of ZrB_2-SiC based ultra high temperature ceramic composites 被引量:2
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作者 R.V.KRISHNARAO G.MADHUSUDHAN REDDY 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2015年第3期188-196,共9页
The difficulty in fabricating the large size or complex shape limits the application of ZrB2-SiC composites. Joining them by fusion welding without or with preheating, controlled cooling under protective gas shield le... The difficulty in fabricating the large size or complex shape limits the application of ZrB2-SiC composites. Joining them by fusion welding without or with preheating, controlled cooling under protective gas shield leads to thermal shock failure or porosity at the weld interface. In the present work, a filler material of(ZrB2-SiC-B4C-YAG) composite with oxidation resistance and thermal shock resistance was produced in the form of welding wire. Using the filler, gas tungsten arc welding(GTAW) was performed without employing preheating, post controlled cooling and extraneous protective gas shield to join hot pressed ZrB2-SiC(ZS), and pressureless sintered ZrB2-SiC-B4C-YAG(ZSBY) composites to themselves. The fusion welding resulted in cracking and non-uniform joining without any filler material. The weld interfaces of the composites were very clean and coherent. The Vickers micro-hardness across the weld interface was found to increase due to the increase in the volume % of both SiC and B4C in the filler material. The shear strength of the weld was about 50% of the flextural strength of the parent composite. 展开更多
关键词 陶瓷基复合材料 焊接界面 钨极氩弧焊 气体保护 超高温 填充材料 ZRB2 形状复杂
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Research on the Surface Micro-configuration in Vibration Cutting Particle Reinforced Metallic Matrix Composites SiC_p/Al
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作者 ZHAO Bo 1,2, LIU Chuan-shao 2, ZHU Xun-sheng 1, XU Ke-wei 1 (1. Institute of Mechanical Engineering, Shanghai Jiaotong U niversity, Shanghai 200030, China 2. Department of Mechanical Engineering, Jiaozuo Institute of Technology, Hena n 454000, China) 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期71-72,共2页
The cutting performance of particulate reinforced me tallic matrix composites(PRMMCs) SiC p/Al in ultrasonic vibration cutting and c ommon cutting with carbide tools and PCD tools was researched in the paper. Mic rost... The cutting performance of particulate reinforced me tallic matrix composites(PRMMCs) SiC p/Al in ultrasonic vibration cutting and c ommon cutting with carbide tools and PCD tools was researched in the paper. Mic rostructure of machined surface was described, the relation between cutting para meters and surface roughness was presented, and characteristic of the surface re mained stress was also presented. Furthermore, wear regularity and abrasion resi stance ability of tools in ultrasonic vibration cutting and common cutting o f PRMMCs were discussed in detail. The test results show: (1) The surface config urations are obviously different when using different tools to machine such PRMM Cs. The surface machined with carbide tools looks luminous and orderly and there are seldom surface defects on it. The reason is that the soft basal body is apt to flow during cutting, therefore a layer of Al matrix film covers machined sur face. On the contrary, the surface machined with PCD tools looks lackluster. But the profile of machined surface is very clear. Superfine grooves, pits and blac k reinforce particulates can be seen easily without obvious Al film. (2) Because of unstable cutting process in common cutting, the surface is easy to produce s ome defects such as burrs, built-up edges and so on so that the quality of surf ace becomes very poor. Vibration cutting can reduce the influence of tearing, pl astic deformation and built-up edge in cutting and can restrain flutter so as t o make cutting process more stable. Therefore, surface roughness of vibration cu tting is better than that of common cutting. (3) There is an optimum value of fe ed rate in vibration cutting of PRMMCs due to the influence of material characte ristics. Whether feed rate is more than or less than this optimum value, surface roughness will increase. (4) According to analyzing the wear rate of tools in v ibration cutting PRMMCs, it can be concluded that abrasion resistance of tools w ill be improved remarkably when vibration cutting composites have a lower pe rcentage of reinforce particulate. If the percentage of reinforce particulate is higher, the influence on abrasion resistance of carbide tool in vibration cut ting will not be obvious. The research result indicates that vibration cutting effect has a close relation with material characteristics. 展开更多
关键词 PCD tools composite sic p/Al surface micro-c onfiguration tool wear
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Rolling of Al-SiC_p Composites
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作者 Rajesh Purohit Anil Kumar Das Rakesh Sagar 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期103-105,共3页
Aluminum based metal matrix composites are offering o utstanding properties in a number of automotive and aircraft components and body structures. The major advantages of these composite materials are their high st re... Aluminum based metal matrix composites are offering o utstanding properties in a number of automotive and aircraft components and body structures. The major advantages of these composite materials are their high st rength to weight ratio, high stiffness, high hardness, wear resistance, low coef ficient of thermal expansion, superior dimensional stability and versatility to designer. In addition to these their isotropic properties, good forming characte ristics, easy availability of cheaper reinforcements along with the availability of comparatively low cost, high volume production methods have made them a prom ising material for future growth. Weight reduction is a major goal of automotive innovations. Lighter vehicles/ ai rcraft means less fuel consumption, reduced emissions, and improved performance. Components made from highly loaded aluminium matrix composites are attractive r elative to iron based materials because of their low density, high stiffness (eq uivalent to nodular iron) and better heat transfer characteristics. The basic co st of materials is higher with these advanced composites; however, manufacturing the part to near net shape may offset basic material costs. A good aluminium based material design can improves safety. The aluminium-based composites can give cars better acceleration and braking, improved handling, ex cellent durability, and ease of repair. Tha aluminum-based composite performs a s well or better in crash than conventional steel-structured cars because of th eir larger volume, which can absorb more crash energy. Another excellent advanta ge of Al-SiC p composite in auto design is better stability and response, and reduced noise, vibration/harshness (NHV). These advantages stem from reduced veh icle weight combined with high structural stiffness and also lead to improved st ability and turning response. In the present work Al-SiC p composite plates of 10 to 12 mm thickness w ere cast using sand casting as well as die casting process. The plates were furt her machined to 3 to 4 mm thicknesses. The machined plates were subjected to col d as well hot rolling. The cold rolling of Al-3 wt.% SiC composite plates was done on 2 high experimental cold rolling mill at Indian Oil Corporation Ltd., R esearch and Development centre, Faridabad. For hot rolling, the Al-5 weight % SiC p composite plates were heat treated at 500 ℃ temperature and Al-15 weight % SiC p composite plates were heat treate d at 550 ℃ temperature for 20 minutes. The plates were hot rolled on 2 high ro lling mill of one ton capacity at IIT Delhi. The maximum percentage reduction ob tained after hot rolling of Al-5 weight % SiC p composite and Al- 15 weight % SiC p composite plates for 10 passes was 11 % and 6 % respectively. During col d rolling of Al-SiC p composites cracks (particle fracture) were observed due to the low ductility of Al-SiC p composties at room temperature. The various m echanical properties such as tensile strength, hardness and wear resistance were measured for the rolled and un-rolled Al-SiC p composite plates. The tensile strength of un-rolled and rolled Al-5wt.% SiC p composites are shown in Tab. 1. Table shows that the tensile strength decreases after rolling. This may be du e to the damage of the bonding between aluminum and silicon carbide particulates . The Rockwell hardness values of Al-5 wt.% SiC p composites measured before a nd after hot rolling are shown in Tab.2. The hardness was found to decrease afte r hot rolling, which may be due to the annealing of composites during heating. T he Rockwell hardness values of Al-3 wt.% SiC p composites before and after cold rolling are shown in Tab.3. The Table shows that the Rockwell hardness of Al-SiC p compostes increases after cold rolling due to the workhardening effec t. The wear resistance of rolled and un-rolled Al-SiC p composites were teste d on reciprocating ball on flat wear testing machine. The wear resistance of Al -SiC p composites decreases after hot rolling due to decrease in hardness 展开更多
关键词 sic Rolling of Al-sic_p composites AL
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Cf/SiC复合材料制备工艺研究 被引量:6
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作者 周长城 张长瑞 +1 位作者 胡海峰 张玉娣 《材料导报》 EI CAS CSCD 北大核心 2007年第2期148-150,共3页
结合材料复合过程中纤维编织体易变形的问题,系统研究了复合材料制备过程中编织体变形的规律,以及对所制备复合材料结构和性能的影响。通过实验研究发现,编织体体积控制有利于复合材料增强体纤维的均匀分布,实现复合材料结构和性能的均... 结合材料复合过程中纤维编织体易变形的问题,系统研究了复合材料制备过程中编织体变形的规律,以及对所制备复合材料结构和性能的影响。通过实验研究发现,编织体体积控制有利于复合材料增强体纤维的均匀分布,实现复合材料结构和性能的均一化,有利于复合材料整体性能的提高,并且,编织体体积控制有利于提高复合材料的致密化速率,最终获得高致密度、高性能的复合材料。 展开更多
关键词 cf/sic 先驱体浸渍裂解 体积控制 复合材料
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不同碳纤维表面状态对Cf/SiC复合材料性能的影响 被引量:4
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作者 王建方 陈朝辉 +2 位作者 刘维民 齐尚奎 谢征芳 《材料导报》 EI CAS CSCD 2002年第3期67-69,共3页
采用XPS对两种不同的碳纤维表面进行了分析,制备了束丝Cf/SiC复合材料,并采用束丝拉仲强度表征其性能。结果表明,碳纤维表面主要有C、O两种元素存在,其中碳主要有C-C和C-O两种存在方式,并且两种纤维的Ols/Cls有明显的不同。当氧含量高时... 采用XPS对两种不同的碳纤维表面进行了分析,制备了束丝Cf/SiC复合材料,并采用束丝拉仲强度表征其性能。结果表明,碳纤维表面主要有C、O两种元素存在,其中碳主要有C-C和C-O两种存在方式,并且两种纤维的Ols/Cls有明显的不同。当氧含量高时,纤维在经历高温处理后强度下降幅度较大,所制备的Cf/SiC复合材料性能较差。 展开更多
关键词 碳纤维 表面状态 XPS cf/sic复合材料 碳纤维 碳化硅 性能
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Cf/SiC复合材料抗氧化涂层的制备及性能 被引量:4
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作者 邹世钦 张长瑞 +2 位作者 周新贵 曹英斌 周长城 《国防科技大学学报》 EI CAS CSCD 北大核心 2004年第4期57-61,共5页
在氧化性环境中,高于400℃时碳纤维开始氧化,限制了Cf SiC复合材料的应用。通过在Cf SiC复合材料表面制备抗氧化涂层体系,可以有效地保护碳纤维不被氧化。本实验制备了含CVD SiC粘接层、自愈合功能层和CVD SiC抗冲蚀层的三层涂层体系,... 在氧化性环境中,高于400℃时碳纤维开始氧化,限制了Cf SiC复合材料的应用。通过在Cf SiC复合材料表面制备抗氧化涂层体系,可以有效地保护碳纤维不被氧化。本实验制备了含CVD SiC粘接层、自愈合功能层和CVD SiC抗冲蚀层的三层涂层体系,并进行了氧化失重试验。氧化失重试验结果表明,仅有CVD SiC涂层的试样氧化失重率较大,不能有效地保护材料,而含有自愈合功能层的三层涂层体系的材料试样,在800℃~1200℃的氧化失重率非常小,1000℃下氧化288h的失重率仅为2.3%,弯曲强度仍保持为452.9MPa。同时实验发现,试样在氧化失重试验后,其CVD SiC涂层的表面形貌有明显改变,这主要是由SiC氧化形成SiO2薄膜所致,并且在1200℃下所生成的SiO2薄膜有表面收缩趋势,具有液相膜的部分特征。 展开更多
关键词 抗氧化涂层 cf/sic复合材料 氧化试验
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PIP法制备Cf/SiC复合材料过程中碳纤维的化学损伤 被引量:3
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作者 王建方 吴文健 +2 位作者 胡碧茹 满亚辉 陈朝辉 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2006年第10期1982-1985,共4页
对先驱体聚碳硅烷浸渍裂解工艺(PIP)制备Cf/SiC复合材料过程中碳纤维损伤严重的问题,系统地分析了在Cf/SiC复合材料制备过程中先驱体裂解对碳纤维的化学损伤.研究结果表明,PIP工艺中碳纤维的化学损伤包括界面反应和基体向碳纤维内部的... 对先驱体聚碳硅烷浸渍裂解工艺(PIP)制备Cf/SiC复合材料过程中碳纤维损伤严重的问题,系统地分析了在Cf/SiC复合材料制备过程中先驱体裂解对碳纤维的化学损伤.研究结果表明,PIP工艺中碳纤维的化学损伤包括界面反应和基体向碳纤维内部的扩散反应.其中聚碳硅烷(PCS)中的活性基团和碳纤维的化学反应并不严重,而微量的氧气和杂质对碳纤维的化学损伤影响很大;基体中硅等元素可向碳纤维内部扩散,随着高温处理时间的延长而加深,并形成脆性的界面层,使碳纤维截面积减小.在第一周期浸渍裂解过程中,先驱体对碳纤维的化学损伤很少,在后续周期中,随着基体致密度的提高,碳纤维的化学损伤有所增加. 展开更多
关键词 cf/sic复合材料 碳纤维 化学损伤
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Ni基高温钎料对Cf/SiC陶瓷基复合材料的润湿性研究 被引量:3
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作者 张勇 张国庆 +2 位作者 何志勇 冯涤 李周 《材料工程》 EI CAS CSCD 北大核心 2008年第3期5-8,共4页
研究了温度和活性元素Cr对Ni基高温钎料在3D-Cf/SiC陶瓷基复合材料上润湿的影响。采用扫描电镜与能谱仪检查界面微观结构与元素分布,通过X射线衍射仪检测界面产物。实验结果表明:升高温度,Ni基钎料在Cf/SiC上的润湿角减小;并且随钎料中... 研究了温度和活性元素Cr对Ni基高温钎料在3D-Cf/SiC陶瓷基复合材料上润湿的影响。采用扫描电镜与能谱仪检查界面微观结构与元素分布,通过X射线衍射仪检测界面产物。实验结果表明:升高温度,Ni基钎料在Cf/SiC上的润湿角减小;并且随钎料中的Cr的质量分数增加,润湿角减小。润湿过程属于反应润湿,润湿界面生成多种碳化物和硅化物。 展开更多
关键词 Ni基高温钎料 润湿性 活性元素 cf/sic
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激光毛化对Cf/SiC与TC4钎焊接头组织及性能的影响 被引量:3
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作者 李海刚 毕建勋 +2 位作者 马武军 邱金莲 李栋 《宇航材料工艺》 CAS CSCD 北大核心 2017年第1期42-46,共5页
由于线胀系数差异大,Cf/Si C复合材料与TC4钛合金钎焊接头容易形成较大的内应力而开裂失效。为了进一步提高接头强度,应用激光毛化工艺在Cf/Si C表面烧蚀出微孔,采用银基钎料对Cf/Si C与TC4进行钎焊。焊后对接头力学性能进行测试,对接... 由于线胀系数差异大,Cf/Si C复合材料与TC4钛合金钎焊接头容易形成较大的内应力而开裂失效。为了进一步提高接头强度,应用激光毛化工艺在Cf/Si C表面烧蚀出微孔,采用银基钎料对Cf/Si C与TC4进行钎焊。焊后对接头力学性能进行测试,对接头界面及断口显微组织进行观察。结果表明:焊前对Cf/Si C表面进行激光毛化处理,钎料能够填充微孔并形成良好的钎焊界面,能够提高Cf/Si C与TC4钎焊接头的剪切强度。 展开更多
关键词 激光毛化 cfsic陶瓷基复合材料 钛合金 钎焊
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Cf/SiC复合材料表面抗氧化涂层研究进展 被引量:3
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作者 汤素芳 杨嘉 +1 位作者 唐鹏举 胡成龙 《材料工程》 EI CAS CSCD 北大核心 2023年第3期17-28,共12页
Cf/SiC复合材料因其低密度,高比强度,优异的抗热震、抗氧化和抗烧蚀性能以及高温强度保持率,被认为是高速飞行器的重要热防护材料之一。然而,由于碳纤维在500℃以上发生显著氧化导致材料逐渐失效,因此需对其进行有效的氧化防护。抗氧化... Cf/SiC复合材料因其低密度,高比强度,优异的抗热震、抗氧化和抗烧蚀性能以及高温强度保持率,被认为是高速飞行器的重要热防护材料之一。然而,由于碳纤维在500℃以上发生显著氧化导致材料逐渐失效,因此需对其进行有效的氧化防护。抗氧化涂层被认为是实现Cf/SiC复合材料长时氧化防护的有效手段。本文基于热防护系统对Cf/SiC复合材料抗氧化性能的苛刻要求,综述了现有Cf/SiC复合材料表面抗氧化涂层的研究进展,着重对抗氧化涂层制备技术及涂层体系进行了梳理。提升Cf/SiC复合材料抗氧化涂层使用温度(≥1800℃)及结合强度是当前需要重点解决的问题,制备更长服役时间、更高服役温度同时兼具抗氧化、抗水蒸气腐蚀乃至较好隔热性能的多功能涂层是未来发展的重要方向。 展开更多
关键词 抗氧化涂层 cf/sic复合材料 超高温陶瓷 氧化 烧蚀 热防护
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SiCf/SiC复合材料界面相研究进展 被引量:20
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作者 刘海韬 程海峰 +1 位作者 王军 唐耿平 《材料导报》 EI CAS CSCD 北大核心 2010年第1期10-14,30,共6页
分析了连续纤维增强陶瓷基复合材料(CFRCMCs)中界面相类型以及各界面相在CFRCMCs中的作用,综述了热解碳(PyC)、氮化硼(BN)、难熔氧化物以及复合界面相在SiCf/SiC复合材料中的应用现状,最后展望了SiCf/SiC复合材料界面相的发展方向。
关键词 sicF/sic复合材料 界面相 力学性能
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升温速率对PIP工艺制备的3D-Cf/SiC复合材料性能及结构的影响 被引量:2
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作者 陈志彦 邹世钦 《中南林业科技大学学报》 CAS CSCD 北大核心 2012年第1期150-153,共4页
研究了不同升温裂解速率对PIP工艺制备的3D-Cf/SiC复合材料性能的影响。采用了3种升温制度,每次裂解时间分别为3 900 min、1 500 min和1 000 min。实验发现3种升温制度下制备的材料的力学性能差别比较小,1 000 min裂解制备的试样的弯曲... 研究了不同升温裂解速率对PIP工艺制备的3D-Cf/SiC复合材料性能的影响。采用了3种升温制度,每次裂解时间分别为3 900 min、1 500 min和1 000 min。实验发现3种升温制度下制备的材料的力学性能差别比较小,1 000 min裂解制备的试样的弯曲强度高达762.5 MPa,其弯曲强度和断裂韧性常数还略高于另外2种。不同升温速率下试样断口的SEM照片均显示很长的纤维拔出,增韧效果显著。研究表明,适当提高升温速率并没有降低Cf/SiC复合材料的力学性能。 展开更多
关键词 cf/sic复合材料 聚碳硅烷 先驱体浸渍-裂解工艺 快速裂解
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