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Experimental investigation on the anti-detonation performance of composite structure containing foam geopolymer backfill material
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作者 Hang Zhou Hujun Li +6 位作者 Zhen Wang Dongming Yan Wenxin Wang Guokai Zhang Zirui Cheng Song Sun Mingyang Wang 《Defence Technology(防务技术)》 2025年第1期304-318,共15页
The compression and energy absorption properties of foam geopolymers increase stress wave attenuation under explosion impacts,reducing the vibration effect on the structure.Explosion tests were conducted using several... The compression and energy absorption properties of foam geopolymers increase stress wave attenuation under explosion impacts,reducing the vibration effect on the structure.Explosion tests were conducted using several composite structure models,including a concrete lining structure(CLS)without foam geopolymer and six foam geopolymer composite structures(FGCS)with different backfill parameters,to study the dynamic response and wave dissipation mechanisms of FGCS under explosive loading.Pressure,strain,and vibration responses at different locations were synchronously tested.The damage modes and dynamic responses of different models were compared,and how wave elimination and energy absorption efficiencies were affected by foam geopolymer backfill parameters was analyzed.The results showed that the foam geopolymer absorbed and dissipated the impact energy through continuous compressive deformation under high strain rates and dynamic loading,reducing the strain in the liner structure by 52%and increasing the pressure attenuation rate by 28%.Additionally,the foam geopolymer backfill reduced structural vibration and liner deformation,with the FGCS structure showing 35%less displacement and 70%less acceleration compared to the CLS.The FGCS model with thicker,less dense foam geopolymer backfill,having more pores and higher porosity,demonstrated better compression and energy absorption under dynamic impact,increasing stress wave attenuation efficiency.By analyzing the stress wave propagation and the compression characteristics of the porous medium,it was concluded that the stress transfer ratio of FGCS-ρ-579 was 77%lower than that of CLS,and the transmitted wave energy was 90%lower.The results of this study provide a scientific basis for optimizing underground composite structure interlayer parameters. 展开更多
关键词 Explosion load Composite structure Geopolymer foam Energy absorption
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Nitric acid oxidation treatment promoting microwave absorption performance of carbonized melamine foam
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作者 MAO Ming-zhen XIA Peng-kun +3 位作者 MA Lei HUANG Sheng-xiang GAO Xiao-hui DENG Lian-wen 《Journal of Central South University》 2025年第5期1630-1640,共11页
Carbonized melamine foam has been recognized as a promising material for microwave absorption due to its exceptional thermal stability,lightweight,and remarkable dielectric properties.In this study,we investigated the... Carbonized melamine foam has been recognized as a promising material for microwave absorption due to its exceptional thermal stability,lightweight,and remarkable dielectric properties.In this study,we investigated the impact of nitric acid oxidation on the surface of carbonized melamine foam and its microwave absorption properties.The treated foam exhibits optimal reflection loss of−21.51 dB at 13.20 GHz,with an effective absorption bandwidth of 7.04 GHz.The enhanced absorption properties are primarily attributed to the strengthened dielectric loss,improved impedance matching,and increased polarization losses resulting from the oxidized surfaces.This research demonstrates a promising new approach for research into surface treatments to improve the performances of microwave absorbers. 展开更多
关键词 carbonized melamine foam nitric acid hydrothermal treatment interface modification microwave absorption performance
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Dynamic response of polymethacrylimide foam sandwich structures with different core layers under water impact loading
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作者 Peilin Zhu Jili Rong +2 位作者 Shenglong Wang Zichao Chen Zifan Jiang 《Defence Technology(防务技术)》 2025年第7期203-222,共20页
Polymethacrylimide(PMI)foam has the highest specific stiffness and strength among polymer foams,with excellent radar-absorbing capabilities,which provide it with broad prospects in underwater ap-plications.To evaluate... Polymethacrylimide(PMI)foam has the highest specific stiffness and strength among polymer foams,with excellent radar-absorbing capabilities,which provide it with broad prospects in underwater ap-plications.To evaluate the impact resistance of PMI foam sandwich structures,the dynamic response and energy absorption characteristics of PMI foam sandwich structures with different core layers under various water impact loads were investigated using combined experimental and numerical methods.A fluid-structure interaction device with a diffusion angle was used for water impact testing of the PMI foam sandwich structures.The 3D-DIC technique was employed to process the deformation images of the sandwich-structure back panel captured by the high-speed cameras.Numerical simulations were performed to analyze the dynamic deformation process of the PMI foam core.The results indicated that the maximum deformation of the back panel exhibited a nonlinear relationship with the impulse.Below the critical impulse,the maximum deformation of the back panel plateaued,which was determined by the core density.Beyond the critical impulse,the rate of deformation increased with the impulse was governed by the core thickness.Compared with different sandwich panels,PMI foam sandwich struc-tures demonstrate significant advantages in terms of impact resistance under high-impulse conditions. 展开更多
关键词 PMI foam sandwich structure Underwater impact loading Impact resistance Energy absorption characteristics
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Ti foam-Ni-Sn/Bi电极制备及其电还原NO_(3)^(-)-N的性能
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作者 张海兵 刘云遏 +1 位作者 黄志昊 沈蓉 《化工进展》 北大核心 2025年第2期1100-1109,共10页
水体中硝酸盐氮(NO_(3)^(-)-N)的污染不仅会造成水生态环境的恶化,还对人类健康构成严重威胁,已引起世界广泛关注。本文通过在泡沫钛板(Ti foam)上化学镀Ni-电沉积镀Sn/Bi的方法制备出一种新型含有中间层的Ti foam-Ni-Sn/Bi电极。扫描... 水体中硝酸盐氮(NO_(3)^(-)-N)的污染不仅会造成水生态环境的恶化,还对人类健康构成严重威胁,已引起世界广泛关注。本文通过在泡沫钛板(Ti foam)上化学镀Ni-电沉积镀Sn/Bi的方法制备出一种新型含有中间层的Ti foam-Ni-Sn/Bi电极。扫描电子显微镜、X射线衍射仪以及电极性能特性测试结果表明Ni以及Sn/Bi被分别成功沉积到了Ti基底和Ni中间层上,并具备较大的电化学活性面积和较多的活性位点。以制备的Ti foam-Ni-Sn/Bi电极为阴极、Ti/RuO_(2)-Ir_(2)O_(3)电极为阳极构建电还原体系,对水中NO_(3)^(-)-N进行电还原处理。实验结果表明,在初始NO_(3)^(-)-N浓度为150mg/L、电流密度为20m A/cm^(2)、pH为3、搅拌速率600r/min、板间距为3cm时,电还原6h后NO_(3)^(-)-N去除率达87.43%,氮气(N_(2))选择性为90.73%。因此,本方法制备的Ti foam-Ni-Sn/Bi电极在NO_(3)^(-)-N电还原过程中表现出较好的还原性能和较高的N_(2)选择性。 展开更多
关键词 Ti foam-Ni-Sn/Bi电极 硝酸盐氮 电还原 氮气选择性
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Experimental investigation on weak shock wave mitigation characteristics of flexible polyurethane foam and polyurea 被引量:2
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作者 Shiyu Jia Cheng Wang +2 位作者 Wenlong Xu Dong Ma Fangfang Qi 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第1期179-191,共13页
In recent years,explosion shock wave has been considered as a signature injury of the current military conflicts.Although strong shock wave is lethal to the human body,weak shock wave can cause many more lasting conse... In recent years,explosion shock wave has been considered as a signature injury of the current military conflicts.Although strong shock wave is lethal to the human body,weak shock wave can cause many more lasting consequences.To investigate the protection ability and characteristics of flexible materials and structures under weak shock wave loading,the blast wave produced by TNT explosive is loaded on the polyurethane foam with the density of 200.0 kg/m3(F-200)and 400.0 kg/m3(F-400),polyurea with the density of 1100.0 kg/m^(3)(P-1100)and structures composed of the two materials,which are intended for individual protection.Experimental results indicate that the shock wave is attenuated to weak pressure disturbance after interacting with the flexible materials which are not damaged.The shock wave protective capability of single-layer materials is dependent on their thickness,density and microscopic characteristics.The overpressure,maximum pressure rise rate and impulse of transmitted wave decrease exponentially with increase in sample thickness.For the same thickness,F-400 provides better protective capability than F-200 while P-1100 shows the best protective capability among the three materials.In this study,as the materials are not destroyed,F-200 with a thickness more than10.0 mm,F-400 with a thickness more than 4.0 mm,and P-1100 with a thickness more than 1.0 mm can attenuate the overpressure amplitude more than 90.0%.Further,multi-layer flexible composites are designed.Different layer layouts of designed structures and layer thickness of the single-layer materials can affect the protective performance.Within the research range,the structure in which polyurea is placed on the impact side shows the optimal shock wave protective performance,and the thicknesses of polyurea and polyurethane foam are 1.0 mm and 4.0 mm respectively.The overpressure attenuation rate reached maximum value of 93.3%and impulse attenuation capacity of this structure are better than those of single-layer polyurea and polyurethane foam with higher areal density. 展开更多
关键词 Free-field explosion Weak shock wave mitigation POLYUREA Polyurethane foam Multi-layered composites
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Propagation Properties of Shock Waves in Polyurethane Foam based on Atomistic Simulations 被引量:1
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作者 Zhiqiang Hu Jianli Shao +2 位作者 Shiyu Jia Weidong Song Cheng Wang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第1期117-129,共13页
Porous materials are widely used in the field of protection because of their excellent energy absorption characteristics.In this work,a series of polyurethane microscopic models are established and the effect of poros... Porous materials are widely used in the field of protection because of their excellent energy absorption characteristics.In this work,a series of polyurethane microscopic models are established and the effect of porosity on the shock waves is studied with classical molecular dynamics simulations.Firstly,shock Hugoniot relations for different porosities are obtained,which compare well with the experimental data.The pores collapse and form local stress wave,which results in the complex multi-wave structure of the shock wave.The microstructure analysis shows that the local stress increases and the local velocity decreases gradually during the process of pore collapse to complete compaction.Finally,it leads to stress relaxation and velocity homogenization.The shock stress peaks can be fitted with two exponential functions,and the amplitude of attenuation coefficient decreases with the increase of density.Besides,the pore collapse under shock or non-shock are discussed by the entropy increase rate of the system.The energy is dissipated mainly through the multiple interactions of the waves under shock.The energy is dissipated mainly by the friction between atoms under non-shock. 展开更多
关键词 Polyurethane foam Shock wave ATTENUATION Atomistic simulation
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Non-dimensional analysis on blast wave propagation in foam concrete:Minimum thickness to avoid stress enhancement 被引量:1
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作者 Ya Yang Xiangzhen Kong Qin Fang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第6期30-46,共17页
Foam concrete is a prospective material in defense engineering to protect structures due to its high energy absorption capability resulted from the long plateau stage.However,stress enhancement rather than stress miti... Foam concrete is a prospective material in defense engineering to protect structures due to its high energy absorption capability resulted from the long plateau stage.However,stress enhancement rather than stress mitigation may happen when foam concrete is used as sacrificial claddings placed in the path of an incoming blast load.To investigate this interesting phenomenon,a one-dimensional difference model for blast wave propagation in foam concrete is firstly proposed and numerically solved by improving the second-order Godunov method.The difference model and numerical algorithm are validated against experimental results including both the stress mitigation and the stress enhancement.The difference model is then used to numerically analyze the blast wave propagation and deformation of material in which the effects of blast loads,stress-strain relation and length of foam concrete are considered.In particular,the concept of minimum thickness of foam concrete to avoid stress enhancement is proposed.Finally,non-dimensional analysis on the minimum thickness is conducted and an empirical formula is proposed by curve-fitting the numerical data,which can provide a reference for the application of foam concrete in defense engineering. 展开更多
关键词 foam concrete Blast wave propagation Non-dimensional analysis Stress enhancement
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Semi-quantitative analysis of the structural evolution of mesophase pitch-based carbon foams by Raman and FTIR spectroscopy
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作者 LIU Yue CHANG Sheng-kai +3 位作者 SU Zhan-peng HUANG Zu-jian QIN Ji YANG Jian-xiao 《新型炭材料(中英文)》 SCIE EI CAS CSCD 北大核心 2024年第4期668-680,共13页
Graphitized carbon foams(GFms)were prepared using mesophase pitch(MP)as a raw material by foaming(450℃),pre-oxidation(320℃),carbonization(1000℃)and graphitization(2800℃).The differences in structure and properties... Graphitized carbon foams(GFms)were prepared using mesophase pitch(MP)as a raw material by foaming(450℃),pre-oxidation(320℃),carbonization(1000℃)and graphitization(2800℃).The differences in structure and properties of GFms prepared from different MP precursors pretreated by ball milling or liquid phase extraction were investigated and compared,and semi-quantitative calculations were conducted on the Raman and FTIR spectra of samples at each preparation stage.Semi-quantitat-ive spectroscopic analysis provided detailed information on the structure and chemical composition changes of the MP and GFm de-rived from it.Combined with microscopic observations,the change from precursor to GFm was analyzed.The results showed that ball milling concentrated the distribution of aromatic molecules in the pitch,which contributed to uniform foaming to give a GFm with a uniform pore distribution and good properties.Liquid phase extraction helped remove light components while retaining large aromatics to form graphitic planes with the largest average size during post-treatment to produce a GFm with the highest degree of graphitization and the fewest open pores,giving the best compression resistance(2.47 MPa),the highest thermal conductivity(64.47 W/(m·K))and the lowest electrical resistance(13.02μΩ·m).Characterization combining semi-quantitative spectroscopic ana-lysis with microscopic observations allowed us to control the preparation of the MP-derived GFms. 展开更多
关键词 Mesophase pitch Carbon foams RAMAN FTIR GRAPHITIZATION
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Protective performance of shear stiffening gel-modified foam against ballistic impact:Experimental and numerical study
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作者 Huan Tu Haowei Yang +9 位作者 Pengzhao Xu Zhe Yang Fan Tang Cheng Dong Yuchao Chen Lei Ren Wenjian Cao Chenguang Huang Yacong Guo Yanpeng Wei 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第2期510-520,共11页
As one of the most widely used personal protective equipment(PPE),body armors play an important role in protecting the human body from the high-velocity impact of bullets or projectiles.The body torso and critical org... As one of the most widely used personal protective equipment(PPE),body armors play an important role in protecting the human body from the high-velocity impact of bullets or projectiles.The body torso and critical organs of the wear may suffer severe behind-armor blunt trauma(BABT)even though the impactor is stopped by the body armor.A type of novel composite material through incorporating shear stiffening gel(STG)into ethylene-vinyl acetate(EVA)foam is developed and used as buffer layers to reduce BABT.In this paper,the protective performance of body armors composed of fabric bulletproof layers and a buffer layer made of foam material is investigated both experimentally and numerically.The effectiveness of STG-modified EVA in damage relief is verified by ballistic tests.In parallel with the experimental study,numerical simulations are conducted by LS-DYNA®to investigate the dynamic response of each component and capture the key mechanical parameters,which are hardly obtained from field tests.To fully describe the material behavior under the transient impact,the selected constitutive models take the failure and strain rate effect into consideration.A good agreement between the experimental observations and numerical results is achieved to prove the validity of the modelling method.The tests and simulations show that the impact-induced deformation on the human body is significantly reduced by using STG-modified EVA as the buffering material.The improvement of protective performance is attributed to better dynamic properties and more outstanding energy absorption capability of the composite foam. 展开更多
关键词 Ballistic behavior Composite foam Shear stiffening gel Finite element analysis Protective mechanism
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miR-34b-5p通过靶向调控IGFBP1表达对动脉粥样硬化泡沫细胞形成及炎症反应的影响 被引量:1
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作者 惠慧 吴光鹏 +1 位作者 廖梅 李光智 《中国免疫学杂志》 北大核心 2025年第4期879-884,共6页
目的:探究miR-34b-5p在动脉粥样硬化(AS)泡沫细胞形成及炎症反应中的作用及可能机制。方法:检测34例AS患者和20例健康体检者血清中miR-34b-5p和胰岛素样生长因子结合蛋白1(IGFBP1)mRNA的表达差异。使用氧化低密度脂蛋白(ox-LDL)诱导RAW2... 目的:探究miR-34b-5p在动脉粥样硬化(AS)泡沫细胞形成及炎症反应中的作用及可能机制。方法:检测34例AS患者和20例健康体检者血清中miR-34b-5p和胰岛素样生长因子结合蛋白1(IGFBP1)mRNA的表达差异。使用氧化低密度脂蛋白(ox-LDL)诱导RAW264.7巨噬细胞构建AS泡沫细胞模型,检测细胞中miR-34b-5p和IGFBP1 mRNA表达水平。双荧光素酶报告基因实验验证miR-34b-5p和IGFBP1的相互作用关系。将miR-34b-5p抑制剂(inhibitor)、抑制剂阴性对照(inhibitor-NC)、IGFBP1 siRNA质粒(si-IGFBP1)和siRNA阴性对照(si-NC)分别或共转染至AS泡沫细胞模型,观察泡沫细胞沉积脂质能力及胞内总胆固醇(TC)、IL-1β、IL-6、TNF-α水平。结果:与健康体检者相比,AS患者血清中miR-34b-5p水平显著升高(P<0.05),IGFBP1 mRNA水平显著降低(P<0.05)。ox-LDL处理的RAW264.7巨噬细胞中miR-34b-5p表达水平显著升高(P<0.05),IGFBP1 mRNA表达水平显著降低(P<0.05)。双荧光素酶报告基因实验显示,IGFBP1是miR-34b-5p的靶基因。与inhibitor-NC组比较,inhibitor组RAW264.7巨噬细胞中IGFBP1蛋白表达水平显著升高(P<0.05)。ox-LDL诱导后,下调miR-34b-5p表达可抑制巨噬细胞脂质沉积能力,降低胞内TC含量及IL-1β、IL-6和TNF-α水平;而干扰IGFBP1基因表达可通过增强巨噬细胞脂质沉积能力,提高胞内TC、IL-1β、IL-6和TNF-α水平,并逆转miR-34b-5p inhibitor对巨噬细胞的干预作用。结论:下调miR-34b-5p表达可抑制AS泡沫细胞的形成,并降低其炎症反应,其机制可能通过靶向上调IGFBP1表达实现。 展开更多
关键词 动脉粥样硬化 miR-34b-5p 胰岛素样生长因子结合蛋白1 泡沫细胞 炎症
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泡排井地面集气管流特性模拟实验 被引量:1
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作者 孙杰 崔淑云 +4 位作者 冯永振 张家伟 邓家岳 阎晓雨 KARIMOV Rinat M 《西安石油大学学报(自然科学版)》 北大核心 2025年第1期79-89,共11页
泡排采气工艺因经济高效、施工便捷等优势在国内外各大气田应用广泛,在众多排水采气工艺中扮演主力军角色。为准确揭示泡排井集气管流流型、压降规律及泡沫稳定性,设计加工了一套泡排井集气管流特性模拟实验装置,以含聚合物的气井地层... 泡排采气工艺因经济高效、施工便捷等优势在国内外各大气田应用广泛,在众多排水采气工艺中扮演主力军角色。为准确揭示泡排井集气管流流型、压降规律及泡沫稳定性,设计加工了一套泡排井集气管流特性模拟实验装置,以含聚合物的气井地层水为介质对其进行可靠性验证。实验选用UT-5D型起泡剂,在气液比0.55~137.42范围内,测试分析起泡剂浓度、起始温度、管径等7个因素影响下的气-液-泡沫多相管流流型、阻力特性及泡沫稳定性。基于相关性和多元回归分析方法,揭示了泡沫高度、压力梯度与各因素的内在关系。结果表明:随气液比增加,管内依次出现液-泡沫分层流、气-泡沫段塞流、气-泡沫波动流、气-泡沫分层流4种流型;气液比、起泡剂浓度和管长对压力梯度和泡沫高度影响显著,其余因素影响均较小,不同因素影响泡沫高度和压降的显著性强弱分别为气液比>起泡剂浓度>管长>温度>弯管>聚合物>管壁粗糙度>管径、气液比>起泡剂浓度>管长>管径>管壁粗糙度>温度>弯管>聚合物;泡沫高度、压力梯度与气液比均表现为强负相关,上述研究可为泡排采气工艺参数优化提供指导。 展开更多
关键词 泡排采气 多相流动 流型 阻力特性 泡沫稳定性
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涌潮冲击桩柱体最大压强及最大载荷的计算方法
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作者 王旭 屈科 +1 位作者 杨元平 王超 《振动与冲击》 北大核心 2025年第6期90-103,共14页
涌潮是一种蕴含着巨大能量的特殊强非线性间断流,因此涌潮区域内桥墩等桩柱体建筑物会受到极大的涌潮冲击力,可能会对桩柱体等涉水结构造成严重毁坏。基于开源程序OpenFOAM和wave2Foam构建高精度涌潮数值水槽,求解雷诺平均的Navier-Sto... 涌潮是一种蕴含着巨大能量的特殊强非线性间断流,因此涌潮区域内桥墩等桩柱体建筑物会受到极大的涌潮冲击力,可能会对桩柱体等涉水结构造成严重毁坏。基于开源程序OpenFOAM和wave2Foam构建高精度涌潮数值水槽,求解雷诺平均的Navier-Stokes方程。首先,进行高精度涌潮数值水槽计算涌潮传播、演变及与桩柱体相互作用的能力;然后,数值计算涌潮与桩柱体相互作用过程中涌潮传播、演变及桩柱体结构动力响应特性的变化规律,并阐明不同形态涌潮与桩柱体发生相互作用时涌潮复杂水动力特性机理;最后,系统分析不同涌潮高度、潮前水深、桩柱体斜置角度和作用方向对涌潮水动力载荷和最大冲击压强的影响。结果表明:涌潮与桩柱体发生相互作用时,涌潮最大水动力载荷和最大冲击压强随着涌潮高度的增加显著增加,呈现出线性增大趋势;波状涌潮和弱旋滚涌潮的最大水动力载荷和最大冲击压强随潮前水深的增大而增大,然而强漩滚涌潮冲击桩柱体时的最大水动力载荷和最大冲击压强随潮前水深的变化没有明显增大的趋势;涌潮冲击桩柱体过程中,相比垂直桩柱体涌潮对正向斜置桩柱体作用的水动力载荷较小,且最大冲击压强的大小也因桩柱体的斜置发生了明显的减小现象。基于对涌潮最大水动力载荷和最大冲击压强数据结果进行系统整理,结合理论特性分析,提出适合不同形态涌潮冲击桩柱体时的最大水动力载荷和涌潮最大冲击压强的理论计算公式。为强潮区域桥梁基础结构的设计提供参考意义。 展开更多
关键词 涌潮 桩柱体 水动力特性 理论分析 wave2foam
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氧化石墨烯接枝黄原胶的制备和提升泡沫驱油研究
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作者 王磊 杨陆涛 +3 位作者 钱国全 时维才 屈霜 姚峰 《南京大学学报(自然科学版)》 北大核心 2025年第1期140-147,共8页
纳米材料具有良好的稳泡效果,材料经改性后能进一步提升泡沫性能,提高三次采油泡沫驱原油采收率.以氧化石墨烯(Graphene Oxide,GO)为基体,通过表面羧基化改性,利用乙二胺(Ethylenediamine,EDA)为桥梁,接枝具有耐盐和增黏效果的黄原胶(Xa... 纳米材料具有良好的稳泡效果,材料经改性后能进一步提升泡沫性能,提高三次采油泡沫驱原油采收率.以氧化石墨烯(Graphene Oxide,GO)为基体,通过表面羧基化改性,利用乙二胺(Ethylenediamine,EDA)为桥梁,接枝具有耐盐和增黏效果的黄原胶(Xanthan Gum,XG)作为新型稳泡剂.通过FT-IR,XPS,Raman,TEM对不同改性阶段的材料的形貌、结构以及官能团进行表征分析.同时,考察了浓度、矿化度、pH对体系的影响.结果表明,和XG体系相比,新型稳泡剂的效果随着其浓度的增加而更加明显,还具有更好的抗盐性和pH稳定性.在85℃老化30 d后,新型稳泡剂损失13%,大幅减小了损失率.体系的界面张力值达到10-2,具有良好的界面性能.在85°C,4 MPa条件下,进行了双管驱替室内实验,结果表明,泡沫体系在高渗透岩心实现了封堵,改善了低渗透岩心的驱替效果,最终提高采收率达21.11%. 展开更多
关键词 氧化石墨烯 黄原胶 稳泡 泡沫驱 提高采收率
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过氧化物改进的热硫化有机硅/EPDM微孔材料结构与性能研究
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作者 雷卫华 张倩 +3 位作者 余凤湄 曹君 陈立新 崔锦林 《化工新型材料》 北大核心 2025年第3期197-202,共6页
研究了热硫化有机硅/三元乙丙橡胶(EPDM)微孔材料的过氧化物改性技术,并表征了改性泡沫的结构与性能。采用有机过氧化物/乙醇溶液,经过表面涂覆、渗透、高温反应,获得了改性的泡沫材料。结果表明:随着处理剂用量的增加,泡沫表面明显粗糙... 研究了热硫化有机硅/三元乙丙橡胶(EPDM)微孔材料的过氧化物改性技术,并表征了改性泡沫的结构与性能。采用有机过氧化物/乙醇溶液,经过表面涂覆、渗透、高温反应,获得了改性的泡沫材料。结果表明:随着处理剂用量的增加,泡沫表面明显粗糙化,与乙二醇的接触角逐渐增大,泡沫的定伸应力逐渐增大,压缩永久变形和伸长率逐渐减小,而拉伸强度在逐渐增大后逐渐减小。随着EPDM含量的增加,泡沫的定伸应力逐渐上升、伸长率逐渐下降,拉伸强度则出现最大值、在处理剂大用量下波动较小。在改性处理后,有机硅/EPDM(70%)微孔泡沫的压缩应力在10%~40%出现明显抬升,泡沫压缩松弛和永久变形大幅减小,伸长率降低、扯断强度略有提高,泡沫具有良好的回弹性。 展开更多
关键词 过氧化物 改性 有机硅 三元乙丙橡胶 微孔泡沫
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微泡沫稠油混合流体的消泡特性研究
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作者 敬加强 韩青松 +3 位作者 郭雨莹 王秋月 杨建平 孙杰 《石油化工》 北大核心 2025年第6期847-854,共8页
采用自制的耐油抗盐型水基泡沫,结合影像分析技术,从泡沫微观结构层面,深入评估了四种消泡剂的综合消泡性能。针对微泡沫稠油混合流体(泡沫油)体系,考虑管道中泡沫-稠油界面间剪切作用,探讨消泡剂类型与添加量对泡沫直径分布、泡沫数量... 采用自制的耐油抗盐型水基泡沫,结合影像分析技术,从泡沫微观结构层面,深入评估了四种消泡剂的综合消泡性能。针对微泡沫稠油混合流体(泡沫油)体系,考虑管道中泡沫-稠油界面间剪切作用,探讨消泡剂类型与添加量对泡沫直径分布、泡沫数量及气泡平均直径的影响。实验结果表明,消泡剂H44在水基泡沫及泡沫油体系中消泡时间均最短;泡沫体积不高于10%(φ)时,消泡剂H47性能更佳;而当泡沫体积高于10%(φ)时,消泡剂H43的消泡性能则优于H47;消泡剂添加量在0.6%~1.4%(φ)时,添加量越高,气泡平均直径越大,消泡率也越高。 展开更多
关键词 含稠油泡沫体系 水基泡沫 消泡剂 消泡率 泡沫直径分布
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泡沫镍/树脂多孔复合材料的压缩强度和比强度
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作者 刘培生 程瑜扬 +2 位作者 程伟 陈斌 李翔宇 《材料工程》 北大核心 2025年第3期153-158,共6页
对泡沫镍(平均孔径约为2.7 mm,孔隙率为93.1%)孔棱进行环氧树脂覆层复合,获得孔棱呈复层结构的泡沫镍/树脂多孔复合材料。对所得复合样品进行压缩性能实验,重点分析复合体的机械强度。结果表明:复合样品的压缩强度和比强度均显著高于原... 对泡沫镍(平均孔径约为2.7 mm,孔隙率为93.1%)孔棱进行环氧树脂覆层复合,获得孔棱呈复层结构的泡沫镍/树脂多孔复合材料。对所得复合样品进行压缩性能实验,重点分析复合体的机械强度。结果表明:复合样品的压缩强度和比强度均显著高于原泡沫镍。当泡沫镍(体密度ρr约0.6 g·cm^(-3))施加覆层制成泡沫镍/树脂复合样品(体密度约0.72~0.82 g·cm^(-3))后,其压缩强度从0.75 MPa提高到2.24~2.68 MPa,其对应比强度从1.23 MPa·cm^(3)·g^(-1)提高到3.09~3.27 MPa·cm^(3)·g^(-1)。复合样品的压缩强度与孔隙率符合基于八面体模型理论得出的对应数理关系。根据对应力学模型可知,复合样品整体失效由孔棱芯部优先破坏造成。 展开更多
关键词 多孔材料 泡沫金属 多孔复合材料 泡沫金属复合材料 力学性能 压缩强度
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全生物降解发泡材料的研究进展
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作者 郭鹏 徐玮良 +3 位作者 吕明福 徐耀辉 张宗胤 高达利 《石油化工》 北大核心 2025年第2期278-287,共10页
开发生物可降解发泡材料是解决由传统石油基发泡材料引起的白色污染和微塑料问题的重要手段。首先介绍了生物可降解发泡材料的主要类型,接着评述了改性技术对材料流变特性及发泡性能的影响。概述了主要的发泡工艺,并分析了发泡过程中遇... 开发生物可降解发泡材料是解决由传统石油基发泡材料引起的白色污染和微塑料问题的重要手段。首先介绍了生物可降解发泡材料的主要类型,接着评述了改性技术对材料流变特性及发泡性能的影响。概述了主要的发泡工艺,并分析了发泡过程中遇到的问题及其可能的解决方案。同时,探讨了生物可降解发泡材料的潜在应用领域。最后,提出了该领域未来研究和应用的发展方向。 展开更多
关键词 全生物降解塑料 发泡 改性 循环利用
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功能性石墨烯量子点起泡剂的制备及性能
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作者 吴景春 代勇辉 +3 位作者 石芳 殷鹏 蓝斌斌 张春龙 《精细化工》 北大核心 2025年第8期1841-1848,共8页
为制备一种稳泡能力较强,降黏与起泡能力优异的石墨烯量子点(GQDs)起泡剂,采用柠檬酸水热法制备了GQDs,然后对其进行γ-甲基丙烯酰氧基丙基三甲氧基硅烷偶联剂功能改性,制备了两亲性石墨烯量子点型起泡剂(D12-5-GQDs)。采用FTIR、纳米... 为制备一种稳泡能力较强,降黏与起泡能力优异的石墨烯量子点(GQDs)起泡剂,采用柠檬酸水热法制备了GQDs,然后对其进行γ-甲基丙烯酰氧基丙基三甲氧基硅烷偶联剂功能改性,制备了两亲性石墨烯量子点型起泡剂(D12-5-GQDs)。采用FTIR、纳米粒度电位仪、UV-Vis对D12-5-GQDs进行了结构表征和性能测试,通过评价静/动态吸附量、界面张力、起泡高度和分流率,阐明了不同实验条件下D12-5-GQDs的发泡能力、稳泡剂协同特性以及降黏调驱等能力。结果表明,温度31℃时,质量浓度1.0 g/L的D12-5-GQDs的能力最佳,15 min内载液量可达187 mL;D12-5-GQDs应用范围在30~350℃,质量浓度1.0 g/L的D12-5-GQDs水溶液在350℃时起泡体积仍能>200 mL;D12-5-GQDs的抗吸附能力较强,最终平衡吸附量约为0.18 mg/g;质量浓度1.0 g/L的D12-5-GQDs溶液调驱能力较好,级差4.6与16.6对应的高、低渗最终分流率之比分别为61∶38和70∶29;D12-5-GQDs在0.5 PV(孔隙体积)的注入量下可迅速起效调驱,并在1.5 PV左右使分流率趋于稳定。 展开更多
关键词 起泡剂 石墨烯量子点 泡沫复合驱 稠油热采 提高采收率 油田化学品
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基于响应曲面法的水库底泥泡沫混凝土配合比优化研究 被引量:2
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作者 李彦苍 宁钰 +7 位作者 石华旺 冯胜雷 张晓雄 张春元 于铠源 朱骥 靳子栋 乔威涛 《水利水电技术(中英文)》 北大核心 2025年第4期211-224,共14页
【目的】为了提高水库底泥的高值化利用率,拟使用水库底泥来制备泡沫混凝土,以水胶比、底泥掺量、泡沫掺量为变量【方法】采用Design-Expert 13.0软件中响应曲面法对水库底泥泡沫混凝土的配合比进行优化设计,分析变量对水库底泥泡沫混... 【目的】为了提高水库底泥的高值化利用率,拟使用水库底泥来制备泡沫混凝土,以水胶比、底泥掺量、泡沫掺量为变量【方法】采用Design-Expert 13.0软件中响应曲面法对水库底泥泡沫混凝土的配合比进行优化设计,分析变量对水库底泥泡沫混凝土抗压强度和导热系数的影响。采用SEM和XRD探究了底泥泡沫混凝土微观结构。【结果】研究结果显示,对水库底泥泡沫混凝土28 d抗压强度影响顺序为:水胶比>泡沫掺量>底泥掺量,而导热系数的影响顺序为:水胶比>底泥掺量>泡沫掺量。随着水胶比增加,抗压强度先升高后下降,导热系数逐渐降低。增加泡沫和底泥掺量会导致抗压强度和导热系数均下降。孔隙率与导热系数呈现负相关,符合指数模型。【结论】经优化配比,水库底泥泡沫混凝土在水胶比0.4、底泥掺量30%、泡沫掺量4.2%条件下制备,其28 d抗压强度为18.19 MPa,导热系数为0.1214W/(m·K),表观密度为701.2 kg/m^(3)。微观结果分析表明,底泥掺入量为30%条件下,试块内部物相结合紧密,孔隙分布均匀。研究成果为水库底泥在建筑材料领域的利用提供了新途径。 展开更多
关键词 水库底泥 泡沫混凝土 响应曲面法 抗压强度 导热系数 影响因素 水胶比 SEM图
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车用聚丙烯模内装饰-微孔发泡注塑成型传热特性与成型质量研究
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作者 金鑫 黄常翼 +3 位作者 黄振敏 陆龙福 严岿 郭巍 《塑料工业》 北大核心 2025年第4期161-168,共8页
针对车用聚丙烯(PP)内外饰件在微孔发泡注塑成型过程中面临的表观质量问题,本文提出一种创新的模内装饰-微孔发泡注塑(IMD-MIM)成型工艺。通过物理实验和Ansys有限元仿真,分析了Cu、PP和聚对苯二甲酸乙二醇酯(PET)装饰膜对IMD-MIM成型... 针对车用聚丙烯(PP)内外饰件在微孔发泡注塑成型过程中面临的表观质量问题,本文提出一种创新的模内装饰-微孔发泡注塑(IMD-MIM)成型工艺。通过物理实验和Ansys有限元仿真,分析了Cu、PP和聚对苯二甲酸乙二醇酯(PET)装饰膜对IMD-MIM成型工艺制件的传热特性、泡孔结构、表面形貌和力学性能的影响。研究发现,装饰膜增加了熔体和模具的热阻,聚合物膜的滞热效应高于Cu膜。装饰膜显著改善了制件泡孔结构和表面质量,其中PP膜提升表面质量和力学性能最为显著。PP膜装饰件的拉伸强度提升至22.37 MPa以上,表面粗糙度(Ra)降至0.244μm,缺口冲击强度提升至6.8 kJ/m^(2)以上。研究为提高IMD-MIM成型工艺效率和产品质量提供了新视角。 展开更多
关键词 聚丙烯 微孔发泡注塑 模内装饰 微观结构
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