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Ce^(3+)和Sm^(3+)共掺杂钒酸钇荧光粉合成及发光性能研究 被引量:1
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作者 肖尊宏 邓琦亮 《化工新型材料》 CAS CSCD 北大核心 2017年第6期89-91,共3页
用均相共沉淀法将铈离子(Ce^(3+))、钐离子(Sm^(3+))共掺杂钒酸钇(YVO_4)制得(Sm_(0.01)Y_(0.99-x))VO_4∶Ce_x^(3+)荧光粉。采用X-射线衍射仪(XRD)、扫描电镜(SEM)、荧光光谱仪(PL)对制得荧光粉的晶体结构、颗粒形貌以及发光特性进行... 用均相共沉淀法将铈离子(Ce^(3+))、钐离子(Sm^(3+))共掺杂钒酸钇(YVO_4)制得(Sm_(0.01)Y_(0.99-x))VO_4∶Ce_x^(3+)荧光粉。采用X-射线衍射仪(XRD)、扫描电镜(SEM)、荧光光谱仪(PL)对制得荧光粉的晶体结构、颗粒形貌以及发光特性进行了分析。结果表明,Ce^(3+)、Sm^(3+)掺入YVO_4荧光粉的相结构仍为四方锆型结构,随着Ce^(3+)离子掺杂浓度的增大,XRD的衍射峰更加明显,SEM显示Ce^(3+)离子掺杂浓度的增大,荧光粉颗粒团聚更加严重,颗粒尺寸约80nm。荧光粉的激发峰在460nm,与蓝光LED的发射峰吻合,发射峰在580nm左右,属于橙光,且随着Ce^(3+)浓度的增加,荧光变强,有利于提高LED的显色指数。 展开更多
关键词 共沉淀法 (Sm0.01 Y0.99-x)VO4∶Ce3+x LED Ce^3+、Sm^3+共掺杂
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Microstructural,magnetic and dielectric performance of rare earth ion(Sm^(3+))-doped MgCd ferrites
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作者 Dandan Wen Xia Chen +4 位作者 Dasen Luo Yi Lu Yixin Chen Renpu Li Wei Cui 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第7期643-647,共5页
The combined effects of Sm^(3+)substitution together with the addition of 3 wt%Bi_(2)O_(3)endow Mg Cd ferrites with excellent magnetic permeability and dielectric permittivity.Various concentrations of Sm^(3+)(x=0,0.0... The combined effects of Sm^(3+)substitution together with the addition of 3 wt%Bi_(2)O_(3)endow Mg Cd ferrites with excellent magnetic permeability and dielectric permittivity.Various concentrations of Sm^(3+)(x=0,0.03,0.06,0.09,0.12and 0.15)were employed to modify the permeability(μ)and permittivity(ε)of the Mg Cd ferrites.X-ray diffraction,scanning electron microscopy(SEM),vibrating sample magnetometry and vector network analysis techniques were used to characterize the samples.The measurement results reveal that the ferrites processed a saturation magnetization of up to 36.8 emu/g and coercivity of up to 29.2 Oe via the conventional solid-state reaction method.The surface morphology SEM confirms that with increasing Sm^(3+)concentration,the grain shape changes from a polygon to a circle.Moreover,the dielectric permittivity can reach a value of 23.The excellent properties obtained in Sm^(3+)-substituted Mg ferrites suggest that they could be promising candidates for modern high-frequency antenna substrates or multilayer devices. 展开更多
关键词 ferrites Sm^(3+)ions SUBSTITUTion magnetic permeability dielectric permittivity
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