Ultrafine,highly dispersed Pt clusters were immobilized onto the Co nanoparticle surfaces by one-step pyrolysis of the precursor Pt(Ⅱ)-encapsulating Co-MOF-74.Owing to the small size effects of Pt clusters as well as...Ultrafine,highly dispersed Pt clusters were immobilized onto the Co nanoparticle surfaces by one-step pyrolysis of the precursor Pt(Ⅱ)-encapsulating Co-MOF-74.Owing to the small size effects of Pt clusters as well as the strongly enhanced synergistic interactions between Pt and Co atoms,the obtained Pt-on-Co/C400 catalysts exhib-ited excellent catalytic activity toward the hydrolysis of ammonia borane with an extremely high turnover frequency(TOF)value of 3022 min^(-1)at 303 K.Durability test indicated that the obtained Pt-on-Co/C400 catalysts possessed high catalytic stability,and there were no changes in the catalyst structures and catalytic activities after 10 cycles.展开更多
An aluminoborate,Na_(2.5)Rb[Al{B_(5)O_(10)}{B_(3)O_(5)}]·0.5NO_(3)·H_(2)O(1),was synthesized under hydrothermal condition,which was built by mixed oxoboron clusters and AlO_(4)tetrahedra.In the structure,the...An aluminoborate,Na_(2.5)Rb[Al{B_(5)O_(10)}{B_(3)O_(5)}]·0.5NO_(3)·H_(2)O(1),was synthesized under hydrothermal condition,which was built by mixed oxoboron clusters and AlO_(4)tetrahedra.In the structure,the[B_(5)O_(10)]^(5-)and[B_(3)O_(7)]^(5-)clusters are alternately connected to form 1D[B_(8)O_(15)]_(n)^(6n-)chains,which are further linked by AlO_(4)units to form a 2D monolayer with 7‑membered ring and 10‑membered ring windows.Two adjacent monolayers with opposite orientations further form a porous‑layered structure with six channels through B—O—Al bonds.Compound 1 was characterized by single crystal X‑ray diffraction,powder X‑ray diffraction(PXRD),IR spectroscopy,UV‑Vis diffuse reflection spectroscopy,and thermogravimetric analysis(TGA),respectively.UV‑Vis diffuse reflectance analysis indicates that compound 1 shows a wide transparency range with a short cutoff edge of 201 nm,suggesting it may have potential application in UV regions.CCDC:2383923.展开更多
Hierarchical clustering analysis based on statistic s is one of the most important mining algorithms, but the traditionary hierarchica l clustering method is based on global comparing, which only takes in Q clusteri n...Hierarchical clustering analysis based on statistic s is one of the most important mining algorithms, but the traditionary hierarchica l clustering method is based on global comparing, which only takes in Q clusteri ng while ignoring R clustering in practice, so it has some limitation especially when the number of sample and index is very large. Furthermore, because of igno ring the association between the different indexes, the clustering result is not good & true. In this paper, we present the model and the algorithm of two-level hierarchi cal clustering which integrates Q clustering with R clustering. Moreover, becaus e two-level hierarchical clustering is based on the respective clustering resul t of each class, the classification of the indexes directly effects on the a ccuracy of the final clustering result, how to appropriately classify the inde xes is the chief and difficult problem we must handle in advance. Although some literatures also have referred to the issue of the classificati on of the indexes, but the articles classify the indexes only according to their superficial signification, which is unscientific. The reasons are as follow s: First, the superficial signification of some indexes usually takes on different meanings and it is easy to be misapprehended by different person. Furthermore, t his classification method seldom make use of history data, the classification re sult is not so objective. Second, for some indexes, its superficial signification didn’t show any mean ings, so simply from the superficial signification, we can’t classify them to c ertain classes. Third, this classification method need the users have higher level knowledge of this field, otherwise it is difficult for the users to understand the signifi cation of some indexes, which sometimes is not available. So in this paper, to this question, we first use R clustering method to cluste ring indexes, dividing p dimension indexes into q classes, then adopt two-level clustering method to get the final result. Obviously, the classification result is more objective and accurate. Moreover, after the first step, we can get the relation of the different indexes and their interaction. We can also know under a certain class indexes, which samples can be clustering to a class. (These semi finished results sometimes are very useful.) The experiments also indicates the effective and accurate of the algorithms. And, the result of R clustering ca n be easily used for the later practice.展开更多
When performing tasks,unmanned clusters often face a variety of strategy choices.One of the key issues in unmanned cluster tasks is the method through which to design autonomous collaboration and cooperative evolution...When performing tasks,unmanned clusters often face a variety of strategy choices.One of the key issues in unmanned cluster tasks is the method through which to design autonomous collaboration and cooperative evolution mechanisms that allow for unmanned clusters to maximize their overall task effective-ness under the condition of strategic diversity.This paper ana-lyzes these task requirements from three perspectives:the diver-sity of the decision space,information network construction,and the autonomous collaboration mechanism.Then,this paper pro-poses a method for solving the problem of strategy selection diversity under two network structures.Next,this paper presents a Moran-rule-based evolution dynamics model for unmanned cluster strategies and a vision-driven-mechanism-based evolu-tion dynamics model for unmanned cluster strategy in the con-text of strategy selection diversity according to various unmanned cluster application scenarios.Finally,this paper pro-vides a simulation analysis of the effects of relevant parameters such as the payoff factor and cluster size on cooperative evolu-tion in autonomous cluster collaboration for the two types of models.On this basis,this paper presents advice for effectively addressing diverse choices in unmanned cluster tasks,thereby providing decision support for practical applications of unmanned cluster tasks.展开更多
Unmanned aerial vehicles(UAVs)have become one of the key technologies to achieve future data collection due to their high mobility,rapid deployment,low cost,and the ability to establish line-of-sight communication lin...Unmanned aerial vehicles(UAVs)have become one of the key technologies to achieve future data collection due to their high mobility,rapid deployment,low cost,and the ability to establish line-of-sight communication links.However,when UAV swarm perform tasks in narrow spaces,they often encounter various spatial obstacles,building shielding materials,and high-speed node movements,which result in intermittent network communication links and cannot support the smooth comple-tion of tasks.In this paper,a high mobility and dynamic topol-ogy of the UAV swarm is particularly considered and the high dynamic mobile topology-based clustering(HDMTC)algorithm is proposed.Simulation and real flight verification results verify that the proposed HDMTC algorithm achieves higher stability of net-work,longer link expiration time(LET),and longer node lifetime,all of which improve the communication performance for UAV swarm networks.展开更多
文摘Ultrafine,highly dispersed Pt clusters were immobilized onto the Co nanoparticle surfaces by one-step pyrolysis of the precursor Pt(Ⅱ)-encapsulating Co-MOF-74.Owing to the small size effects of Pt clusters as well as the strongly enhanced synergistic interactions between Pt and Co atoms,the obtained Pt-on-Co/C400 catalysts exhib-ited excellent catalytic activity toward the hydrolysis of ammonia borane with an extremely high turnover frequency(TOF)value of 3022 min^(-1)at 303 K.Durability test indicated that the obtained Pt-on-Co/C400 catalysts possessed high catalytic stability,and there were no changes in the catalyst structures and catalytic activities after 10 cycles.
文摘An aluminoborate,Na_(2.5)Rb[Al{B_(5)O_(10)}{B_(3)O_(5)}]·0.5NO_(3)·H_(2)O(1),was synthesized under hydrothermal condition,which was built by mixed oxoboron clusters and AlO_(4)tetrahedra.In the structure,the[B_(5)O_(10)]^(5-)and[B_(3)O_(7)]^(5-)clusters are alternately connected to form 1D[B_(8)O_(15)]_(n)^(6n-)chains,which are further linked by AlO_(4)units to form a 2D monolayer with 7‑membered ring and 10‑membered ring windows.Two adjacent monolayers with opposite orientations further form a porous‑layered structure with six channels through B—O—Al bonds.Compound 1 was characterized by single crystal X‑ray diffraction,powder X‑ray diffraction(PXRD),IR spectroscopy,UV‑Vis diffuse reflection spectroscopy,and thermogravimetric analysis(TGA),respectively.UV‑Vis diffuse reflectance analysis indicates that compound 1 shows a wide transparency range with a short cutoff edge of 201 nm,suggesting it may have potential application in UV regions.CCDC:2383923.
文摘Hierarchical clustering analysis based on statistic s is one of the most important mining algorithms, but the traditionary hierarchica l clustering method is based on global comparing, which only takes in Q clusteri ng while ignoring R clustering in practice, so it has some limitation especially when the number of sample and index is very large. Furthermore, because of igno ring the association between the different indexes, the clustering result is not good & true. In this paper, we present the model and the algorithm of two-level hierarchi cal clustering which integrates Q clustering with R clustering. Moreover, becaus e two-level hierarchical clustering is based on the respective clustering resul t of each class, the classification of the indexes directly effects on the a ccuracy of the final clustering result, how to appropriately classify the inde xes is the chief and difficult problem we must handle in advance. Although some literatures also have referred to the issue of the classificati on of the indexes, but the articles classify the indexes only according to their superficial signification, which is unscientific. The reasons are as follow s: First, the superficial signification of some indexes usually takes on different meanings and it is easy to be misapprehended by different person. Furthermore, t his classification method seldom make use of history data, the classification re sult is not so objective. Second, for some indexes, its superficial signification didn’t show any mean ings, so simply from the superficial signification, we can’t classify them to c ertain classes. Third, this classification method need the users have higher level knowledge of this field, otherwise it is difficult for the users to understand the signifi cation of some indexes, which sometimes is not available. So in this paper, to this question, we first use R clustering method to cluste ring indexes, dividing p dimension indexes into q classes, then adopt two-level clustering method to get the final result. Obviously, the classification result is more objective and accurate. Moreover, after the first step, we can get the relation of the different indexes and their interaction. We can also know under a certain class indexes, which samples can be clustering to a class. (These semi finished results sometimes are very useful.) The experiments also indicates the effective and accurate of the algorithms. And, the result of R clustering ca n be easily used for the later practice.
基金supported by the National Natural Science Foundation of China(72471240).
文摘When performing tasks,unmanned clusters often face a variety of strategy choices.One of the key issues in unmanned cluster tasks is the method through which to design autonomous collaboration and cooperative evolution mechanisms that allow for unmanned clusters to maximize their overall task effective-ness under the condition of strategic diversity.This paper ana-lyzes these task requirements from three perspectives:the diver-sity of the decision space,information network construction,and the autonomous collaboration mechanism.Then,this paper pro-poses a method for solving the problem of strategy selection diversity under two network structures.Next,this paper presents a Moran-rule-based evolution dynamics model for unmanned cluster strategies and a vision-driven-mechanism-based evolu-tion dynamics model for unmanned cluster strategy in the con-text of strategy selection diversity according to various unmanned cluster application scenarios.Finally,this paper pro-vides a simulation analysis of the effects of relevant parameters such as the payoff factor and cluster size on cooperative evolu-tion in autonomous cluster collaboration for the two types of models.On this basis,this paper presents advice for effectively addressing diverse choices in unmanned cluster tasks,thereby providing decision support for practical applications of unmanned cluster tasks.
基金supported by the National Key Research and Development Program of China(2024YFB4504500)Shanghai Collaborative Innovation Project(24xtcx00500).
文摘Unmanned aerial vehicles(UAVs)have become one of the key technologies to achieve future data collection due to their high mobility,rapid deployment,low cost,and the ability to establish line-of-sight communication links.However,when UAV swarm perform tasks in narrow spaces,they often encounter various spatial obstacles,building shielding materials,and high-speed node movements,which result in intermittent network communication links and cannot support the smooth comple-tion of tasks.In this paper,a high mobility and dynamic topol-ogy of the UAV swarm is particularly considered and the high dynamic mobile topology-based clustering(HDMTC)algorithm is proposed.Simulation and real flight verification results verify that the proposed HDMTC algorithm achieves higher stability of net-work,longer link expiration time(LET),and longer node lifetime,all of which improve the communication performance for UAV swarm networks.
基金supported by Natural Science Research Project of High Education of Anhui Province (KJ2012Z080)Young Teachers Fund of Anhui University of Science and Technology(2012QNZ13)the Talent Foundation of High Education of Anhui Province for Outstanding Youth(2009QRZ056)
基金supported by the Program of the Young Teachers of College in Anhui Province(2008jq1118)The Youth Pro-gram of Fuyang Teachers College(2008LQ05,2008LQ04)~~
基金Supported by the Talent Foundation of High Education of Anhui Province for Outstanding Youth under Grant(2009SQRZ056)Young Teachers Fund of Anhui University of Science and Technology tinder Grant(2012QNZ13)Master,Doctorate Fund of Anhui University of Science and Technology under Grant(200911176)
