A new molybdophosphate, (NH3CH2CH2NH3)2Mo5O15(HPO4)2 has been synthesized under hydrothermal conditions and structurally characterized by single crystal X ray diffractions. The compound crystallizes in the monoclinic,...A new molybdophosphate, (NH3CH2CH2NH3)2Mo5O15(HPO4)2 has been synthesized under hydrothermal conditions and structurally characterized by single crystal X ray diffractions. The compound crystallizes in the monoclinic, space group C2/c, a=1.7633(2)nm, b=1.00122(11) nm, c=1.37624(13)nm, β=96.974(5)°, V=2.4117(5)nm3, Z=4, Dc=2.853g·cm-3, μ(MoKα)=2.766mm-1, F(000)=1992. The structure contains the isolated polyanions of [Mo5O15(HPO4)2]4- units around which the portonated ethylenediamine ions are pos itioned. By hydrogen bond interactions the polyanions are interconnected to form a three dimensional network. Other characterizations by powder XRD, IR and thermal analysis are also described. CCDC: 206321.展开更多
A homoleptic lanthanide guanidinate complex [（CH2）5NC（NiPr）2]3Yb was synthesized by the metathesis reaction of lithium guanidinate with anhydrous YbCl3 in 3∶1 molar ratio in THF.Its crystal structure was determin...A homoleptic lanthanide guanidinate complex [（CH2）5NC（NiPr）2]3Yb was synthesized by the metathesis reaction of lithium guanidinate with anhydrous YbCl3 in 3∶1 molar ratio in THF.Its crystal structure was determined by X-ray diffraction.The crystallographic data:C36H72N9Yb,Mr=804.07,orthorhombic,space group P212121（#19）,a=10.3168（7）,b=11.443（7）,c=35.5649（2）?,V=4199.1（5）?3,Z=4,Dc=1.272 g/cm3,F（000）=1684.00,T=193.1K,λ（MoKα）=0.7107?,μ=22.61 cm-1,R=0.040,wR=0.126 for 8653 observed reflections with（I>3.00 σ（I））.The ytterbium is six-coordinate by six nitrogen atoms of three chelation bidentate guanidinate ligands.展开更多
文摘A new molybdophosphate, (NH3CH2CH2NH3)2Mo5O15(HPO4)2 has been synthesized under hydrothermal conditions and structurally characterized by single crystal X ray diffractions. The compound crystallizes in the monoclinic, space group C2/c, a=1.7633(2)nm, b=1.00122(11) nm, c=1.37624(13)nm, β=96.974(5)°, V=2.4117(5)nm3, Z=4, Dc=2.853g·cm-3, μ(MoKα)=2.766mm-1, F(000)=1992. The structure contains the isolated polyanions of [Mo5O15(HPO4)2]4- units around which the portonated ethylenediamine ions are pos itioned. By hydrogen bond interactions the polyanions are interconnected to form a three dimensional network. Other characterizations by powder XRD, IR and thermal analysis are also described. CCDC: 206321.
文摘A homoleptic lanthanide guanidinate complex [（CH2）5NC（NiPr）2]3Yb was synthesized by the metathesis reaction of lithium guanidinate with anhydrous YbCl3 in 3∶1 molar ratio in THF.Its crystal structure was determined by X-ray diffraction.The crystallographic data:C36H72N9Yb,Mr=804.07,orthorhombic,space group P212121（#19）,a=10.3168（7）,b=11.443（7）,c=35.5649（2）?,V=4199.1（5）?3,Z=4,Dc=1.272 g/cm3,F（000）=1684.00,T=193.1K,λ（MoKα）=0.7107?,μ=22.61 cm-1,R=0.040,wR=0.126 for 8653 observed reflections with（I>3.00 σ（I））.The ytterbium is six-coordinate by six nitrogen atoms of three chelation bidentate guanidinate ligands.
