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Fabrication and absolute calibration of B-dot probe for magnetic field measurement on a high power laser facility 被引量:1
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作者 Longyu KUANG Feibiao XUE +10 位作者 Longfei JING Ruizhen YU Huabing DU Tao YI Tingshuai LI Hang LI Yi YU Feng WANG Shaoen JIANG Guangyue HU Jian ZHENG 《Plasma Science and Technology》 SCIE EI CAS CSCD 2020年第8期71-75,共5页
The fabrication and absolute calibration of a B-dot probe is employed to measure the pulsed magnetic field at the Shenguang-Ⅱhigh power laser facility.Copper enameled silk with a cross section diameter of 0.1 mm is u... The fabrication and absolute calibration of a B-dot probe is employed to measure the pulsed magnetic field at the Shenguang-Ⅱhigh power laser facility.Copper enameled silk with a cross section diameter of 0.1 mm is used to wind the one-turn coil with a 1 mm diameter.Two coils are paired and reversely linked to their respective circuits to form a differential B-dot probe that is sealed in and protected by a quartz shell.This B-dot probe is experimentally calibrated and then used to measure the pulsed magnetic field in laser targeting experiments at the Shenguang-Ⅱhigh power laser facility.Signals show a high performance of this B-dot probe.The common mode noise can be effectively canceled out by the differential pair.The magnetic field of over 300 T can be extrapolated at the location close to the target. 展开更多
关键词 b-dot MAGNETIC FIELD DIAGNOSTIC laser TARGETING
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Design and photophysical characterization of quasi-intrinsic fluorescent probes utilized in DNA sequencing
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作者 Yaning Zhang Yongkang Lyu +3 位作者 Zhizheng Cao Xiaolin Chen Qingtian Meng Changzhe Zhang 《Chinese Physics B》 2025年第2期241-248,共8页
To understand the gene-based biological processes in-depth,the single-molecule real-time sequencing has drawn increasing attention with promoted by the Human Genome Project.Herein,a set of newly designed canonical flu... To understand the gene-based biological processes in-depth,the single-molecule real-time sequencing has drawn increasing attention with promoted by the Human Genome Project.Herein,a set of newly designed canonical fluorescent bases(A_(y),tC,G_(b),T_(p))are proposed for four-color DNA sequencing.These quasi-intrinsic probes are derived from the fluorophore replacement and ring expansion on natural bases,which still keep the pyrimidine or purine underlying skeleton and Watson–Crick hydrogen bonding face to allow minimal perturbation to the native DNA duplex.More importantly,these nucleobase analogues possess red-shifted absorption and efficient photoluminescence due to the enhancedπ-conjugation in character.Meanwhile,the four analogues could generate distinct emission wavelength(Δλ~50 nm)for real-time sequencing.To assess the biological employment of the proposed biosensors,the effects of base pairing and linking deoxyribose are also considered. 展开更多
关键词 DNA sequencing base analogues fluorescent probe
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一种角向传输线B-dot标定平台的设计
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作者 张信军 罗维熙 +2 位作者 呼义翔 尹佳辉 周文渊 《强激光与粒子束》 CAS CSCD 北大核心 2024年第5期9-14,共6页
基于感应电压叠加器感应腔角向传输线电流探头离线标定的需求,设计了离线标定平台。离线标定平台为平板传输线结构,与在线标定相比,对标定信号的畸变更低。分析了跨平台标定误差的来源,并针对性提出降低误差的措施。分析表明,安装偏心... 基于感应电压叠加器感应腔角向传输线电流探头离线标定的需求,设计了离线标定平台。离线标定平台为平板传输线结构,与在线标定相比,对标定信号的畸变更低。分析了跨平台标定误差的来源,并针对性提出降低误差的措施。分析表明,安装偏心及探头纵向安装深度是跨平台标定误差的最大来源,需要在工程设计中重点关注。实际建立了离线标定平台并开展误差分析,得到跨平台标定误差3.3%的结果。 展开更多
关键词 感应腔 角向传输线 b-dot 标定
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Tb^(3+)-nucleic acid probe-based label-free and rapid detection of mercury pollution in food 被引量:1
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作者 Xuhan Xia Chenxi Zhou +7 位作者 Yulin Zhu Yi Dong Qiang He Mohammad Rizwan Khan Yuanlong Chi Rosa Busquets Ruijie Deng Yao Ren 《Food Science and Human Wellness》 SCIE CSCD 2024年第2期993-998,共6页
Mercury is a threatening pollutant in food,herein,we developed a Tb^(3+)-nucleic acid probe-based label-free assay for mix-and-read,rapid detection of mercury pollution.The assay utilized the feature of light-up fluor... Mercury is a threatening pollutant in food,herein,we developed a Tb^(3+)-nucleic acid probe-based label-free assay for mix-and-read,rapid detection of mercury pollution.The assay utilized the feature of light-up fluorescence of terbium ions(Tb^(3+))via binding with single-strand DNA.Mercury ion,Hg^(2+)induced thymine(T)-rich DNA strand to form a double-strand structure(T-Hg^(2+)-T),thus leading to fluorescence reduction.Based on the principle,Hg^(2+)can be quantified based on the fluorescence of Tb^(3+),the limit of detection was 0.0689μmol/L and the linear range was 0.1-6.0μmol/L.Due to the specificity of T-Hg^(2+)-T artificial base pair,the assay could distinguish Hg^(2+)from other metal ions.The recovery rate was ranged in 98.71%-101.34%for detecting mercury pollution in three food samples.The assay is low-cost,separation-free and mix-to-read,thus was a competitive tool for detection of mercury pollution to ensure food safety. 展开更多
关键词 Mercury pollution Food safety Nucleic acid probe LABEL-FREE TERBIUM
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Cryogenic Digital Image Correlation as a Probe of Strain in Iron-Based Superconductors
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作者 Ziye Mo Chunyi Li +4 位作者 Wenting Zhang Chang Liu Yongxin Sun Ruixian Liu Xingye Lu 《Chinese Physics Letters》 SCIE EI CAS CSCD 2024年第10期84-89,共6页
Uniaxial strain is a powerful tuning parameter that can control symmetry and anisotropic electronic properties in iron-based superconductors.However,accurately characterizing anisotropic strain can be challenging and ... Uniaxial strain is a powerful tuning parameter that can control symmetry and anisotropic electronic properties in iron-based superconductors.However,accurately characterizing anisotropic strain can be challenging and complex.Here,we utilize a cryogenic optical system equipped with a high-spatial-resolution microscope to characterize surface strains in iron-based superconductors using the digital image correlation method.Compared with other methods such as high-resolution x-ray diffraction,strain gauge,and capacitive sensor,digital image correlation offers a non-contact full-field measurement approach,acting as an optical virtual strain gauge that provides high spatial resolution.The results measured on detwinned BaFe_(2)As_(2)are quantitatively consistent with the distortion measured by x-ray diffraction and neutron Larmor diffraction.These findings highlight the potential of cryogenic digital image correlation as an effective and accessible tool for probing the isotropic and anisotropic strains,facilitating applications of uniaxial strain tuning in research of quantum materials. 展开更多
关键词 ANISOTROPIC GAUGE probe
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Activatable fluorescent probes for imaging and diagnosis of rheumatoid arthritis
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作者 Pan Luo Fu-Qiang Gao +5 位作者 Wei Sun Jun-You Li Cheng Wang Qing-Yu Zhang Zhi-Zhuo Li Peng Xu 《Military Medical Research》 SCIE CAS CSCD 2024年第2期287-307,共21页
Rheumatoid arthritis(RA)is a systemic autoimmune disease that is primarily manifested as synovitis and polyarticular opacity and typically leads to serious joint damage and irreversible disability,thus adversely affec... Rheumatoid arthritis(RA)is a systemic autoimmune disease that is primarily manifested as synovitis and polyarticular opacity and typically leads to serious joint damage and irreversible disability,thus adversely affecting locomotion ability and life quality.Consequently,good prognosis heavily relies on the early diagnosis and effective therapeutic monitoring of RA.Activatable fluorescent probes play vital roles in the detection and imaging of biomarkers for disease diagnosis and in vivo imaging.Herein,we review the fluorescent probes developed for the detection and imaging of RA biomarkers,namely reactive oxygen/nitrogen species(hypochlorous acid,peroxynitrite,hydroxyl radical,nitroxyl),pH,and cysteine,and address the related challenges and prospects to inspire the design of novel fluorescent probes and the improvement of their performance in RA studies. 展开更多
关键词 Rheumatoid arthritis Fluorescent probe IMAGING DIAGNOSIS BIOMARKER
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Plasma potential measurements using an emissive probe made of oxide cathode
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作者 李建泉 马海杰 陆文琪 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期571-577,共7页
A novel emissive probe consisting of an oxide cathode coating is developed to achieve a low operating temperature and long service life.The properties of the novel emissive probe are investigated in detail,in comparis... A novel emissive probe consisting of an oxide cathode coating is developed to achieve a low operating temperature and long service life.The properties of the novel emissive probe are investigated in detail,in comparison with a traditional tungsten emissive probe,including the operating temperature,the electron emission capability and the plasma potential measurement.Studies of the operating temperature and electron emission capability show that the tungsten emissive probe usually works at a temperature of 1800 K-2200 K while the oxide cathode emissive probe can function at about 1200 K-1400 K.In addition,plasma potential measurements using the oxide cathode emissive probe with different techniques have been accomplished in microwave electron cyclotron resonance plasmas with different discharge powers.It is found that a reliable plasma potential can be obtained using the improved inflection point method and the hot probe with zero emission limit method,while the floating point method is invalid for the oxide cathode emissive probe. 展开更多
关键词 emissive probe oxide cathode plasma potential filament temperature
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Design of compact integrated diamond nitrogen-vacancy center quantum probe
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作者 夏圣开 卢文韬 +10 位作者 赵旭彤 薛雅文 许增博 葛仕宇 汪洋 虞林嫣 卞雨辰 安思瀚 杨博 向建军 杜关祥 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期409-415,共7页
An integrated quantum probe for magnetic field imaging is proposed,where the nitrogen–vacancy(NV)center fixed at the fiber tip is located on the periphery of flexible ring resonator.Using flexible polyimide(PI)as the... An integrated quantum probe for magnetic field imaging is proposed,where the nitrogen–vacancy(NV)center fixed at the fiber tip is located on the periphery of flexible ring resonator.Using flexible polyimide(PI)as the substrate medium,we design a circular microstrip antenna,which can achieve a bandwidth of 140 MHz at Zeeman splitting frequency of 2.87 GHz,specifically suitable for NV center experiments.Subsequently,this antenna is seamlessly fixed at a three-dimensional-printed cylindrical support,allowing the optical fiber tip to extend out of a dedicated aperture.To mitigate errors originating from processing,precise tuning within a narrow range can be achieved by adjusting the conformal amplitude.Finally,we image the microwave magnetic field around the integrated probe with high resolution,and determine the suitable area for placing the fiber tip(SAP). 展开更多
关键词 nitrogen-vacancy center conformal antenna integrated probe magnetic field imaging
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Metal-organic cage as fluorescent probe for LiPF_(6)in lithium batteries
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作者 Xi Li Dehua Xu +3 位作者 Aoxuan Wang Chengxin Peng Xingjiang Liu Jiayan Luo 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第10期1592-1600,共9页
Lithium hexafluorophosphate(LiPF_(6)),the most commonly used lithium battery electrolyte salt,is vulnerable to heat and humidity.Quantitative and qualitative determination the variation of LiPF_(6)have always relied o... Lithium hexafluorophosphate(LiPF_(6)),the most commonly used lithium battery electrolyte salt,is vulnerable to heat and humidity.Quantitative and qualitative determination the variation of LiPF_(6)have always relied on advanced equipment.Herein,we develop a fast,convenient,high-selective fluorescence detection method based on metal-organic cages(MOC),whose emission is enhanced by nearly 20 times in the presence of LiPF_(6)with good stability and photobleaching resistance.The fluorescent probe can also detect moisture in battery electrolyte.We propose and verify that the luminescence enhancement is due to the presence of hydrogen bond-induced enhanced emission effect in cages.Fluorescent excitation-emission matrix spectra and variable-temperature nuclear magnetic resonance spectroscopy are employed to clarify the role of hydrogen bonds in guest-loaded cages.Density functional theory(DFT)calculation is applied to simulate the structure of host-guest complexes and estimate the adsorption energy involved in the system.The precisely matched lock-and-key model paves a new way for designing and fabricating novel host structures,enabling specific recognition of other target compounds. 展开更多
关键词 Metal-organic cage Selective fluorescence probe Moisture detection Hydrogen bond Host-guest complex
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Poloidal magnetic field reconstruction by laser-driven ion-beam trace probe in spherical tokamak
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作者 Zuyu ZHANG Tianchao XU +4 位作者 Chijie XIAO Xianli HUANG Renchuan HE Ruixin YUAN Xiaoyi YANG 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第11期58-64,共7页
The poloidal magnetic field( B_(p)) plays a critical role in plasma equilibrium, confinement and transport of magnetic confinement devices. Multiple diagnostic methods are needed to complement each other to obtain a m... The poloidal magnetic field( B_(p)) plays a critical role in plasma equilibrium, confinement and transport of magnetic confinement devices. Multiple diagnostic methods are needed to complement each other to obtain a more accurate B_(p) profile. Recently, the laser-driven ion-beam trace probe(LITP) has been proposed as a promising tool for diagnosing B_(p) and radial electric field( E_(r)) profiles in tokamaks [Yang X Y et al 2014 Rev. Sci. Instrum. 85 11E429]. The spherical tokamak(ST) is a promising compact device with high plasma beta and naturally large elongation. However, when applying LITP to diagnosing B_(p) in STs, the larger B_(p) invalidates the linear reconstruction relationship for conventional tokamaks, necessitating the development of a nonlinear reconstruction principle tailored to STs. This novel approach employs an iterative reconstruction method based on Newton's method to solve the nonlinear equation. Subsequently,a simulation model to reconstruct the B_(p) profile of STs is developed and the experimental setup of LITP is designed for EXL-50, a middle-sized ST. Simulation results of the reconstruction show that the relative errors of B_(p) reconstruction are mostly below 5%. Moreover, even with 5 mm measurement error on beam traces or 1 cm flux surface shape error, the average relative error of reconstruction remains below 15%, initially demonstrating the robustness of LITP in diagnosing B_(p) profiles in STs. 展开更多
关键词 laser-driven ion-beam trace probe poloidal magnetic field diagnostic iterative reconstruction
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Study of plasma parameters of coaxial plasma source using triple Langmuir probe and Faraday cup diagnostics
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作者 Sunil KANCHI Rohit SHUKLA Archana SHARMA 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第4期94-100,共7页
Coaxial plasma guns are a type of plasma source that produces plasma which propagates radially and axially controlled by the shape of the ground electrode, which has attracted much interest in several applications. In... Coaxial plasma guns are a type of plasma source that produces plasma which propagates radially and axially controlled by the shape of the ground electrode, which has attracted much interest in several applications. In this work, a 120° opening angle of CPG nozzle is used as a plasma gun configuration that operates at the energy of 150 J. The ionization of polyethylene insulator between the electrodes of the gun produces a cloud of hydrogen and carbon plasma.The triple Langmuir probe and Faraday cup are used to measure plasma density and plasma temperature. These methods are used to measure the on-axis and off-axis plasma divergence of the coaxial plasma gun. The peak values of ion densities measured at a distance of 25 mm on-axis from the plasma gun are(1.6±0.5)×10^(19)m^(-3)and(2.8±0.6)×10^(19)m^(-3)for hydrogen and carbon plasma respectively and the peak temperature is 3.02±0.5 eV. The mean propagation velocity of plasma is calculated using the transit times of plasma at different distances from the plasma gun and is found to be 4.54±0.25 cm/μs and 1.81±0.18 cm/μs for hydrogen and carbon plasma respectively. The Debye radius is obtained from the measured experimental data that satisfies the thin sheath approximation. The shot-to-shot stability of plasma parameters facilitates the use of plasma guns in laboratory experiments. These types of plasma sources can be used in many applications like plasma opening switches, plasma devices, and as plasma sources. 展开更多
关键词 coaxial plasma source triple Langmuir probe Faraday cup plasma density plasma temperature
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Multinuclear MR and MRI study of lithium-ion cells using a variable field magnet and a fixed frequency RF probe
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作者 Andrés Ramírez Aguilera Florin Marica +4 位作者 Kevin J.Sanders Md Al Raihan C.Adam Dyker Gillian R.Goward Bruce J.Balcom 《Magnetic Resonance Letters》 2024年第1期10-20,共11页
An exploratory multinuclear magnetic resonance(MR)and magnetic resonance imaging(MRI)study was performed on lithium-ion battery cells with ^(7)Li,^(19)F,and ^(1)H measurements.A variable field superconducting magnet w... An exploratory multinuclear magnetic resonance(MR)and magnetic resonance imaging(MRI)study was performed on lithium-ion battery cells with ^(7)Li,^(19)F,and ^(1)H measurements.A variable field superconducting magnet with a fixed frequency parallel-plate radiofrequency(RF)probe was employed in the study.The magnetic field was changed to set the resonance frequency of each nucleus to the fixed RF probe frequency of 33.7 MHz.Two cartridge-like lithium-ion cells,with graphite anodes and LiNi_(0.5)Mn_(0.3)Co_(0.2)O_(2)(NMC)cathodes,were interrogated.One cell was pristine,and one was charged to a cell voltage of 4.2 V.The results presented demonstrate the great potential of the variable field magnet approach in multinuclear measurement of lithium-ion batteries.These methods open the door for developing faster and simpler methods for detecting,quantifying,and interpreting MR and MRI data from lithium-ion and other batteries. 展开更多
关键词 Multinuclear MR/MRI Variable field magnet Lithium-ion battery Parallel-plate rf probe
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A ratiometric fluorescent probe for hypoxanthine detection in aquatic products based on the enzyme mimics and fluorescence of cobalt-doped carbon nitride
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作者 Xin Wang Chengyi Hong +1 位作者 Zhengzhong Lin Zhiyong Huang 《Food Science and Human Wellness》 SCIE CSCD 2024年第2期879-884,共6页
A ratiometric fluorescent probe for hypoxanthine(Hx)detection was established based on the mimic enzyme and fluorescence characteristics of cobalt-doped graphite-phase carbon nitride(Co doped g-C_(3)N_(4)).In addition... A ratiometric fluorescent probe for hypoxanthine(Hx)detection was established based on the mimic enzyme and fluorescence characteristics of cobalt-doped graphite-phase carbon nitride(Co doped g-C_(3)N_(4)).In addition to emitting strong fluorescence,the peroxidase activity of Co doped g-C_(3)N_(4)can catalyze the reaction of O-phenylenediamine and H_(2)O_(2)to produce diallyl phthalate which can emit yellow fluorescence at 570 nm.Through the decomposition of Hx by xanthine oxidase,Hx can be indirectly detected by the generating hydrogen peroxide based on the measurement of fluorescent ratio I(F_(570)/F_(370)).The linear range was 1.7-272.2 mg/kg(R^(2)=0.997),and the detection limit was 1.52 mg/kg(3σ/K,n=9).The established method was applied to Hx detection in bass,grass carp,and shrimp,and the data were verified by HPLC.The result shows that the established probe is sensitive,accurate,and reliable,and can be used for Hx detection in aquatic products. 展开更多
关键词 Co doped g-C_(3)N_(4) Ratiometric fluorescent probe HYPOXANTHINE FRESHNESS Aquatic products
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A Filtering Coaxial Probe for Passive Intermodulation Characterization
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作者 BAI Yongjiang YANG Jiye +2 位作者 ZHU Shaohao YANG Ye YE Ming 《ZTE Communications》 2024年第4期59-66,共8页
Passive intermodulation(PIM)in communication systems is an unwanted interference caused by weak nonlinear currentvoltage characteristics of radio frequency(RF)passive components.Characterization of PIM is important fo... Passive intermodulation(PIM)in communication systems is an unwanted interference caused by weak nonlinear currentvoltage characteristics of radio frequency(RF)passive components.Characterization of PIM is important for both the study of PIM mechanisms and the location/suppression of PIM sources.PIM probes,made of open-ended coaxial transmission lines,have almost the same coupling strength to carriers and PIM products,and are usually used for near-field PIM characterization.Namely,it doesn’t have any filtering capability.Therefore,it cannot stop the carrier power from entering into PIM tester’s receiver,which may trigger active intermodulation of the receiver and degrade the PIM tester’s performance.To overcome this drawback,a passive filtering coaxial probe is proposed here.Compared with existing passive coaxial PIM probes,it has stronger coupling strength for PIM products than for carriers.Thus,the probe itself can block part of the carrier power entering into the PIM tester’s receiver.This advantage helps improve PIM tester’s overall performance.Both theoretical analysis and experiments are conducted for demonstration.The proposed probe brings more possibility to PIM characterization. 展开更多
关键词 coupling gap passive intermodulation filtering coaxial probe
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An experimental study on the magnetic field permeability of an inductive-pulsed plasma thruster
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作者 Bi-Xuan Che Jian-Jun Wu +3 位作者 Mou-Sen Cheng Xiao-Kang Li Yu Zhang Da-Wei Guo 《Chinese Physics B》 2025年第2期342-350,共9页
Inductive-pulsed plasma thruster is an in-space propulsion device that generates thrust by ionizing and accelerating plasma through pulsed electromagnetic field.In this paper,the correlation between plasma structure e... Inductive-pulsed plasma thruster is an in-space propulsion device that generates thrust by ionizing and accelerating plasma through pulsed electromagnetic field.In this paper,the correlation between plasma structure evolution and magnetic field permeability is studied using a B-dot probe array system,combing with high-speed camera and electrical parameter measurement.Further discussions explained the mechanism how the magnetic permeation characteristics affect the energy deposition between circuit and plasma. 展开更多
关键词 inductive-pulsed plasma thruster electric propulsion b-dot probe plasma structure
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有机小分子荧光探针结合静电纺丝用于爆炸物检测研究进展
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作者 成乐琴 陶韵琦 +1 位作者 张跃伟 于雪 《发光学报》 北大核心 2025年第1期126-139,共14页
近年来,随着炸药制备和隐蔽性水平的进一步提高,爆炸物探测也面临更加严峻的挑战。有机小分子荧光探针具有高灵敏度、高选择性、低检测限等优点,近年来在爆炸物识别方面得到了广泛应用。然而,这些荧光探针对爆炸物的识别通常需要在溶液... 近年来,随着炸药制备和隐蔽性水平的进一步提高,爆炸物探测也面临更加严峻的挑战。有机小分子荧光探针具有高灵敏度、高选择性、低检测限等优点,近年来在爆炸物识别方面得到了广泛应用。然而,这些荧光探针对爆炸物的识别通常需要在溶液中进行,导致其应用受到很大限制。静电纺丝是一种制备直径可控、形态均匀的纳米纤维的有效技术。将荧光探针与静电纺丝技术结合制备出具有携带方便、可重复性好、检测限低等优点的荧光纳米纤维膜,有效地拓宽了荧光探针在检测爆炸物方面的应用。本文对有机小分子材料的荧光传感单元结构进行分类,总结了有机小分子荧光纳米纤维膜传感器对常见爆炸物三硝基甲苯(Trinitrotoluene,TNT)、三硝基苯酚(Trinitrophenol,TNP)、2,4-二硝基甲苯(2,4-Dinitrotoluene,DNT)、环三亚甲基三硝胺(Cyclotrimethylene trinitramine,RDX)、三过氧化三丙酮(Triacetone triperoxide,TATP)等进行荧光识别和检测,为实际爆炸物检测中静电纺荧光纳米纤维膜的设计提供指导,同时为荧光探针在复杂环境中的实际应用提供了新思路。 展开更多
关键词 荧光探针 静电纺丝 爆炸物检测 纳米薄膜纤维
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小茴香荧光碳点的制备及水中Cr^(6+)的检测
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作者 张丽珍 张利娜 +2 位作者 杨冬业 黄晓艳 覃思银 《化工新型材料》 北大核心 2025年第2期247-251,257,共6页
以自然界中生物质为前体合成功能性碳量子点(C-CDs)是一种绿色环保的合成策略。本研究以小茴香阴干草质茎作为碳源,通过简单的一步水热法合成水溶性良好的C-CDs。该C-CDs在紫外灯照射下能够发出明亮的蓝色荧光,最佳激发波长和最佳发射... 以自然界中生物质为前体合成功能性碳量子点(C-CDs)是一种绿色环保的合成策略。本研究以小茴香阴干草质茎作为碳源,通过简单的一步水热法合成水溶性良好的C-CDs。该C-CDs在紫外灯照射下能够发出明亮的蓝色荧光,最佳激发波长和最佳发射波长分别为381nm和460nm。实验发现,C-CDs具有良好的抗光漂白性,以及优秀的pH稳定性。此外,C-CDs对金属Cr^(6+)具有较高的选择性,在460nm处的荧光强度随Cr^(6+)浓度的增加而降低,具有显著的荧光猝灭效应。C-CDs的荧光猝灭与Cr^(6+)浓度在0~100μmol/L范围内呈线性关系(R^(2)=0.9964),最低检出限为0.30nmol/L。在实际应用中,自来水和湖水中的Cr^(6+)检测回收率在97.1%~100.25%。因此,小茴香C-CDs可作为荧光探针检测Cr^(6+)。 展开更多
关键词 小茴香 荧光碳点 水热法 荧光探针 Cr^(6+)
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氮、氧杂苯并菲基元取代的α-氰基二苯乙烯对硝基芳环类爆炸物的探针性能研究
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作者 张宇金 陈自然 +3 位作者 李博 张宇红 何旭东 张莉萍 《原子与分子物理学报》 CAS 北大核心 2025年第5期27-34,共8页
快速选择性检测苦味酸(PA)、三硝基芴酮(TNF)等硝基芳环爆炸物已成为当前研究的热点之一.基于B3LYP/6-311+g(d,p)理论水平,对氮杂苯并菲基元取代的α-氰基二苯乙烯(TPN-Ar-DPA:a)、氮、氧杂苯并菲基元取代的α-氰基二苯乙烯(TPNO-Ar-DPA... 快速选择性检测苦味酸(PA)、三硝基芴酮(TNF)等硝基芳环爆炸物已成为当前研究的热点之一.基于B3LYP/6-311+g(d,p)理论水平,对氮杂苯并菲基元取代的α-氰基二苯乙烯(TPN-Ar-DPA:a)、氮、氧杂苯并菲基元取代的α-氰基二苯乙烯(TPNO-Ar-DPA:b)探针分子及八个被检硝基芳环分子进行结构优化与频率计算;对a、b分子稳定结构分别计算气态和四氢呋喃(C_(4)H_(8)O)溶剂中的电子吸收光谱及荧光光谱;对a、b探针分子与硝基芳环所形成二聚体分子的结合能分别计算;最后对二聚体分子进行了简约化密度梯度(RDG)分析.研究结果表明,分子b的平面性优于a,分子b的能隙值小于a.气相与C_(4)H_(8)O溶剂中,分子b吸收光谱与荧光光谱比分子a均明显红移,但在C_(4)H_(8)O溶剂中,两个分子的荧光光谱均有不同程度的蓝移;与分子a相比,分子b与八个被检物所形成二聚体的结合能绝对值相对较大,对硝基芳香环检测物的选择性和灵敏度更好,可设计为对硝基酚(PNP)、TNF、PA、3,4-二硝基苯甲酸(DNBA)的探针分子.探针分子对硝基芳环具有较好地选择性和灵敏度,主要源于二聚体分子间存在较强的氢键作用. 展开更多
关键词 苯并菲基元 硝基芳环 爆炸物 探针性能 密度泛函理论 简化密度梯度分析
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太阳模拟器热平衡试验设备及技术综述
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作者 吴东亮 高庆哲 +1 位作者 张鹏嵩 廖韬 《航天器环境工程》 2025年第1期7-15,共9页
太阳模拟器能够较精确地模拟太阳辐照的准直性、均匀性和光谱特性。深空探测器等航天器的构形日益复杂,其表面热光学性能的差异化愈发显著,使太阳模拟器在热平衡试验中的重要作用愈发凸显。文章介绍了太阳模拟器的基本构成、工作原理及... 太阳模拟器能够较精确地模拟太阳辐照的准直性、均匀性和光谱特性。深空探测器等航天器的构形日益复杂,其表面热光学性能的差异化愈发显著,使太阳模拟器在热平衡试验中的重要作用愈发凸显。文章介绍了太阳模拟器的基本构成、工作原理及性能参数,综述了国内外太阳模拟器设备和性能指标。并结合我国航天器的发展提出利用太阳模拟器开展试验的具体需求,分析了国内外典型太阳模拟器热平衡试验案例,对我国用于热平衡试验的太阳模拟器的技术发展提出意见和建议。 展开更多
关键词 太阳模拟器 深空探测器 热平衡试验 试验需求 综述
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用于测量强流脉冲电子束的B-dot 被引量:8
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作者 李勤 李洪 +3 位作者 陈楠 高峰 王永伟 王莉萍 《强激光与粒子束》 EI CAS CSCD 北大核心 2009年第9期1390-1394,共5页
描述了B-dot探头测量脉冲电子束流强度和束质心位置的原理,分析了B-dot探头工作于自积分和微分模式的条件,并根据所测电子束流信号的前沿和脉冲宽度特点,确定B-dot探头工作于微分模式,设计其电感参数约为60 nH。在电子束流模拟装置上对B... 描述了B-dot探头测量脉冲电子束流强度和束质心位置的原理,分析了B-dot探头工作于自积分和微分模式的条件,并根据所测电子束流信号的前沿和脉冲宽度特点,确定B-dot探头工作于微分模式,设计其电感参数约为60 nH。在电子束流模拟装置上对B-dot探头的灵敏度系数和偏心曲线进行了标定,标定得到B-dot探头及测试线路的灵敏度系数为4 147 A/V。将探测器安装在神龙一号加速器上进行束测实验,多次实验结果表明该探测器可以实现电子束流强度和质心位置的准确测量。 展开更多
关键词 b-dot探头 脉冲 电子束 电流大小 质心位置 测量
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