Gas chromatography-mass spectrometry(GC-MS) and the chemometric resolution method(alternative moving window factor analysis,AMWFA) were used for comparative analysis of volatile constituents in herbal pair(HP) flos lo...Gas chromatography-mass spectrometry(GC-MS) and the chemometric resolution method(alternative moving window factor analysis,AMWFA) were used for comparative analysis of volatile constituents in herbal pair(HP) flos lonicerae-caulis lonicerae(FL-CL) and its single herbs.The temperature-programmed retention index(PTRI) was also employed for the identification of compounds.In total,44,39,and 50 volatile chemical components in volatile oil of FL,CL and HP FL-CL were separately determined qualitatively and quantitatively,accounting for 87.22%,94.54% and 90.08% total contents of volatile oil of FL,CL and HP FL-CL,respectively.The results show that there are 32 common volatile constituents between HP FL-CL and single herb FL,33 common volatile constituents between HP FL-CL and single herb CL,and 10 new constituents in the volatile oil of HP FL-CL.展开更多
Identification of the aging condition and the failure probability of oil-paper insulation in transformer is important for improving the reliability of electric power transmission system and applying life cycle cost (L...Identification of the aging condition and the failure probability of oil-paper insulation in transformer is important for improving the reliability of electric power transmission system and applying life cycle cost (LCC) management to electrical equipment. Based on data obtained in a series of multi-accelerated-aging experiments, two approaches for calculating failure probability of oil-paper insulation were compared in aspects of degree of polymerization (DP) and condition ranking. In the experiments, mineral oil and cellulose paper are sub- jected to electrical and thermal stresses, and several parameters, including dissolved gases’ volume fraction, furfural content, moisture content, and degree of polymerization, are measured after the aging process. Results show that weight of carbon oxide, which has a close relationship with cellulose paper degradation, is much higher in DP model than in condition ranking model. Moreover, it is concluded that DP model is more practically accurate than condition ranking model, because aging of cellulose paper rather than mineral oil is the key and critical factor of oil-paper insulation aging.展开更多
油中溶解气体分析(dissolved gas analysis,DGA)监测技术数据质量的管理、维护及保障体系不完善,导致目前油中溶解气体数据质量存在一定缺陷。提出一种适合油中溶解气体时序数据的趋势预测方法,通过对油中溶解气体在线监测时序数据的特...油中溶解气体分析(dissolved gas analysis,DGA)监测技术数据质量的管理、维护及保障体系不完善,导致目前油中溶解气体数据质量存在一定缺陷。提出一种适合油中溶解气体时序数据的趋势预测方法,通过对油中溶解气体在线监测时序数据的特征进行深入分析,选择了泛化性能优越的统计模型,并借鉴加性模型的优点,对存在缺失值的油中溶解气体数据进行拟合,并对预测效果进行分析。同时,与XGBoos(textreme gradient boosting,XGBoost)模型预测效果进行对比,通过实例对比了两者在预测效果上的差异。展开更多
油中溶解气体分析方法(dissolved gas analysis,DGA)是对局部放电进行检测和诊断的重要手段之一,但是目前其准确度有一定局限性,主要原因是缺乏对油中溶解气体和变压器实际故障之间关系的研究。该文基于3种常见的油纸绝缘局部放电模型...油中溶解气体分析方法(dissolved gas analysis,DGA)是对局部放电进行检测和诊断的重要手段之一,但是目前其准确度有一定局限性,主要原因是缺乏对油中溶解气体和变压器实际故障之间关系的研究。该文基于3种常见的油纸绝缘局部放电模型模拟实验,将典型相关分析方法应用于局部放电与油中产生气体的相关性研究。结果表明:典型相关分析法能定量地评估局部放电发展过程中的统计特征参数与油中溶解气体含量2组数据之间的相关性,以及不同参数向量对相关性的贡献,挖掘出每组参数中的主要特征向量,如沿面放电特征统计参数为偏斜度sk和峰值个数pk,特征气体为乙烯、乙烷。实验结果为局部放电产气机制研究和提高DGA法的准确度提供参考。展开更多
基金Project(20976017) supported by the National Natural Science Foundation of China
文摘Gas chromatography-mass spectrometry(GC-MS) and the chemometric resolution method(alternative moving window factor analysis,AMWFA) were used for comparative analysis of volatile constituents in herbal pair(HP) flos lonicerae-caulis lonicerae(FL-CL) and its single herbs.The temperature-programmed retention index(PTRI) was also employed for the identification of compounds.In total,44,39,and 50 volatile chemical components in volatile oil of FL,CL and HP FL-CL were separately determined qualitatively and quantitatively,accounting for 87.22%,94.54% and 90.08% total contents of volatile oil of FL,CL and HP FL-CL,respectively.The results show that there are 32 common volatile constituents between HP FL-CL and single herb FL,33 common volatile constituents between HP FL-CL and single herb CL,and 10 new constituents in the volatile oil of HP FL-CL.
基金Project supported by National Basic Research Program of China (973 Program) (2011CB 209404)
文摘Identification of the aging condition and the failure probability of oil-paper insulation in transformer is important for improving the reliability of electric power transmission system and applying life cycle cost (LCC) management to electrical equipment. Based on data obtained in a series of multi-accelerated-aging experiments, two approaches for calculating failure probability of oil-paper insulation were compared in aspects of degree of polymerization (DP) and condition ranking. In the experiments, mineral oil and cellulose paper are sub- jected to electrical and thermal stresses, and several parameters, including dissolved gases’ volume fraction, furfural content, moisture content, and degree of polymerization, are measured after the aging process. Results show that weight of carbon oxide, which has a close relationship with cellulose paper degradation, is much higher in DP model than in condition ranking model. Moreover, it is concluded that DP model is more practically accurate than condition ranking model, because aging of cellulose paper rather than mineral oil is the key and critical factor of oil-paper insulation aging.
文摘油中溶解气体分析(dissolved gas analysis,DGA)监测技术数据质量的管理、维护及保障体系不完善,导致目前油中溶解气体数据质量存在一定缺陷。提出一种适合油中溶解气体时序数据的趋势预测方法,通过对油中溶解气体在线监测时序数据的特征进行深入分析,选择了泛化性能优越的统计模型,并借鉴加性模型的优点,对存在缺失值的油中溶解气体数据进行拟合,并对预测效果进行分析。同时,与XGBoos(textreme gradient boosting,XGBoost)模型预测效果进行对比,通过实例对比了两者在预测效果上的差异。
文摘油中溶解气体分析方法(dissolved gas analysis,DGA)是对局部放电进行检测和诊断的重要手段之一,但是目前其准确度有一定局限性,主要原因是缺乏对油中溶解气体和变压器实际故障之间关系的研究。该文基于3种常见的油纸绝缘局部放电模型模拟实验,将典型相关分析方法应用于局部放电与油中产生气体的相关性研究。结果表明:典型相关分析法能定量地评估局部放电发展过程中的统计特征参数与油中溶解气体含量2组数据之间的相关性,以及不同参数向量对相关性的贡献,挖掘出每组参数中的主要特征向量,如沿面放电特征统计参数为偏斜度sk和峰值个数pk,特征气体为乙烯、乙烷。实验结果为局部放电产气机制研究和提高DGA法的准确度提供参考。
