Trimethoxybenzoyloxysolanesylamide（8） was first synthesized from solanesol in four steps. Thus, solanesyl bromide（5） prepared by the reaction of solanesol（4） and PBr3 was reacted with potassium phthalimide to gi...Trimethoxybenzoyloxysolanesylamide（8） was first synthesized from solanesol in four steps. Thus, solanesyl bromide（5） prepared by the reaction of solanesol（4） and PBr3 was reacted with potassium phthalimide to give N-solanesylphthalimide（6）, which was refluxed with N2H4·H2O in 95%EtOH to give solanesylamine（7）. Compound 7 was then reacted with 3,4,5-trimethoxybenzoyloxyl chloride to give the title compound. Its structure has been confirmed by IR, 1H NMR, MS and elemental analysis.展开更多
文摘Trimethoxybenzoyloxysolanesylamide（8） was first synthesized from solanesol in four steps. Thus, solanesyl bromide（5） prepared by the reaction of solanesol（4） and PBr3 was reacted with potassium phthalimide to give N-solanesylphthalimide（6）, which was refluxed with N2H4·H2O in 95%EtOH to give solanesylamine（7）. Compound 7 was then reacted with 3,4,5-trimethoxybenzoyloxyl chloride to give the title compound. Its structure has been confirmed by IR, 1H NMR, MS and elemental analysis.
