Ti(Ⅳ),Ni(Ⅱ),Cu(Ⅰ) complexes bearing mono(2-chlorobenzaldehyde)-thiosemicarbazone(HL) were synthesized in non-aqueous solvent containing ligand(HL) by the electrochemical oxidation of anodic metal with Ti,Ni and Cu,...Ti(Ⅳ),Ni(Ⅱ),Cu(Ⅰ) complexes bearing mono(2-chlorobenzaldehyde)-thiosemicarbazone(HL) were synthesized in non-aqueous solvent containing ligand(HL) by the electrochemical oxidation of anodic metal with Ti,Ni and Cu,respectively.The complexes were characterized by elemental analysis,IR,UV,magnetic susceptibility and molar conductivity etc.展开更多
A new complex hexaaquamagnesium(Ⅱ) bis [2-(thiosemicarbazonomethyl)-benzoato],has been prepared and characterized by elemental analysis,IR spectra,molar conductivity and single-crystal X-ray diffraction. The results ...A new complex hexaaquamagnesium(Ⅱ) bis [2-(thiosemicarbazonomethyl)-benzoato],has been prepared and characterized by elemental analysis,IR spectra,molar conductivity and single-crystal X-ray diffraction. The results of crystal structure show that each Mg(Ⅱ) ion is coordinated with six oxygen atoms from water molecules and the complex formed two dimensional layered structure through intramolecule and intermolecule hydrogen bonds. The antibacterial assay of the magnesium(Ⅱ) complex and the ligand were tested using a modified version of the 2-fold serial dilution method,the results show that the complex show considerable antibacterial activity against escherichia coli,bacillus subtilis and staphylococcus white,and the ligand did not show antibacterial activity.展开更多
文摘Ti(Ⅳ),Ni(Ⅱ),Cu(Ⅰ) complexes bearing mono(2-chlorobenzaldehyde)-thiosemicarbazone(HL) were synthesized in non-aqueous solvent containing ligand(HL) by the electrochemical oxidation of anodic metal with Ti,Ni and Cu,respectively.The complexes were characterized by elemental analysis,IR,UV,magnetic susceptibility and molar conductivity etc.
文摘使用溶剂热法,吡啶-2-甲醛缩氨基硫脲与Co(C lO4)2.6H2O反应制备了Co(Ⅲ)配合物[Co(C7H7N4S)2](C lO4),并用元素分析、红外光谱和紫外光谱对配合物进行表征。采用SRB法试验了配体和配合物对体外口腔黏膜癌细胞(KB)的敏感性,结果表明浓度为0.16 m g/L时,配合物对细胞杀伤力大于配体,金属与配体作用可能具有加合作用。
文摘A new complex hexaaquamagnesium(Ⅱ) bis [2-(thiosemicarbazonomethyl)-benzoato],has been prepared and characterized by elemental analysis,IR spectra,molar conductivity and single-crystal X-ray diffraction. The results of crystal structure show that each Mg(Ⅱ) ion is coordinated with six oxygen atoms from water molecules and the complex formed two dimensional layered structure through intramolecule and intermolecule hydrogen bonds. The antibacterial assay of the magnesium(Ⅱ) complex and the ligand were tested using a modified version of the 2-fold serial dilution method,the results show that the complex show considerable antibacterial activity against escherichia coli,bacillus subtilis and staphylococcus white,and the ligand did not show antibacterial activity.
