The hydrothermal reaction of Zn(NO3)2, NaN3, and 1-(4-pyridyl)-2-(2-cyanobenzene) ethylene (PCE), at the mole ratio 1∶2∶2 in methanol and water at 70 ℃ for two days afforded [Zn(PCE)2(N3)2], the structure of which ...The hydrothermal reaction of Zn(NO3)2, NaN3, and 1-(4-pyridyl)-2-(2-cyanobenzene) ethylene (PCE), at the mole ratio 1∶2∶2 in methanol and water at 70 ℃ for two days afforded [Zn(PCE)2(N3)2], the structure of which features a four-coordinated distorted tetrahedron geometry around zinc(Ⅱ). CCDC: 235945.展开更多
3-(pyridin-2-yl)-1,2,4-triazole was synthesized through two steps from the raw material 2-cyanopridine,and a series of derivatives(3a～3d)which were reported in this paper were synthesized by the reaction of 3-(pyridi...3-(pyridin-2-yl)-1,2,4-triazole was synthesized through two steps from the raw material 2-cyanopridine,and a series of derivatives(3a～3d)which were reported in this paper were synthesized by the reaction of 3-(pyridin-2-yl)-1,2,4-triazole with(o-,m-,p-)2-chloro-methyl pyridine.Their structures were characterized by elementary analyses,IR,1H NMR and 13C NMR.展开更多
文摘The hydrothermal reaction of Zn(NO3)2, NaN3, and 1-(4-pyridyl)-2-(2-cyanobenzene) ethylene (PCE), at the mole ratio 1∶2∶2 in methanol and water at 70 ℃ for two days afforded [Zn(PCE)2(N3)2], the structure of which features a four-coordinated distorted tetrahedron geometry around zinc(Ⅱ). CCDC: 235945.
文摘3-(pyridin-2-yl)-1,2,4-triazole was synthesized through two steps from the raw material 2-cyanopridine,and a series of derivatives(3a～3d)which were reported in this paper were synthesized by the reaction of 3-(pyridin-2-yl)-1,2,4-triazole with(o-,m-,p-)2-chloro-methyl pyridine.Their structures were characterized by elementary analyses,IR,1H NMR and 13C NMR.
