A novel organic disulfide, 2,2 diaminophenyloxydisulfide(DAPD) has been prepared by the reaction of o aminophenol with sulfur monochloride in THF. Its polymer films are formed by electropolymerization from a AN/THF ...A novel organic disulfide, 2,2 diaminophenyloxydisulfide(DAPD) has been prepared by the reaction of o aminophenol with sulfur monochloride in THF. Its polymer films are formed by electropolymerization from a AN/THF solution containing 0.1 mol/L LiClO 4, 0.1 mol/L HCl and 0.05 mol/L DAPD monomer on Pt electrode under continuous cycling between -0.30 V and 1.20 V vs . Ag/AgCl (sat. KCl) at scanning rate 50 mV/s. The cyclic voltammetry shows that its electrochemical behavior is similar to that of polyaniline. The redox peak current of the cyclic voltammograms increase with increasing of the cyclic times. The electronic conductivity of poly (DAPD) can reach from 2.1×10 -3 to 8.7×10 -3 S/cm. Two main facts are considered to be necessary for obtaining electroactive poly (DAPD) in electropolymerization process. One is the existence of sufficient concentration of the supporting electrolyte to enhance the ionic conductivity of AN/THF solution and the other is the existence of protons from the acid HCl. With an increase in acid content of the solution, the polymerization efficiency as well as the electroactivity of poly (DAPD) films show a striking enhancement and the electronic conductivity of poly (DAPD) film increases. But the concentration of HCl would be quite high to result in the decomposition of DAPD monomer.展开更多
The compound 2,2′-(2-amino-phenoxy)-ether [L] was synthesized from the reaction of diethylene glycol with tosyl chloride. AgClO4 and ZnCl2 each react with L to give two complexes [Ag2L2(H2O)(ClO4)2] (1) and [ZnLCl2]n...The compound 2,2′-(2-amino-phenoxy)-ether [L] was synthesized from the reaction of diethylene glycol with tosyl chloride. AgClO4 and ZnCl2 each react with L to give two complexes [Ag2L2(H2O)(ClO4)2] (1) and [ZnLCl2]n (2) respectively, and characterized by FTIR and single crystal X-ray diffraction. The results of structural analysis indicated that both complexes crystallize in the monoclinic system with space group P21/c. 1 is a dinuclear complex, and 2 forming 1D zigzag chain by Zn(Ⅱ) linking adjacent ligands in turn. When viewed from the top of the chain, the structure of 2 shows the unidimensional tube.展开更多
文摘A novel organic disulfide, 2,2 diaminophenyloxydisulfide(DAPD) has been prepared by the reaction of o aminophenol with sulfur monochloride in THF. Its polymer films are formed by electropolymerization from a AN/THF solution containing 0.1 mol/L LiClO 4, 0.1 mol/L HCl and 0.05 mol/L DAPD monomer on Pt electrode under continuous cycling between -0.30 V and 1.20 V vs . Ag/AgCl (sat. KCl) at scanning rate 50 mV/s. The cyclic voltammetry shows that its electrochemical behavior is similar to that of polyaniline. The redox peak current of the cyclic voltammograms increase with increasing of the cyclic times. The electronic conductivity of poly (DAPD) can reach from 2.1×10 -3 to 8.7×10 -3 S/cm. Two main facts are considered to be necessary for obtaining electroactive poly (DAPD) in electropolymerization process. One is the existence of sufficient concentration of the supporting electrolyte to enhance the ionic conductivity of AN/THF solution and the other is the existence of protons from the acid HCl. With an increase in acid content of the solution, the polymerization efficiency as well as the electroactivity of poly (DAPD) films show a striking enhancement and the electronic conductivity of poly (DAPD) film increases. But the concentration of HCl would be quite high to result in the decomposition of DAPD monomer.
文摘The compound 2,2′-(2-amino-phenoxy)-ether [L] was synthesized from the reaction of diethylene glycol with tosyl chloride. AgClO4 and ZnCl2 each react with L to give two complexes [Ag2L2(H2O)(ClO4)2] (1) and [ZnLCl2]n (2) respectively, and characterized by FTIR and single crystal X-ray diffraction. The results of structural analysis indicated that both complexes crystallize in the monoclinic system with space group P21/c. 1 is a dinuclear complex, and 2 forming 1D zigzag chain by Zn(Ⅱ) linking adjacent ligands in turn. When viewed from the top of the chain, the structure of 2 shows the unidimensional tube.
