The work addresses to the study of the molecular and crystal structure and properties of a new energyintensive compound 3,6-bis(2,2,2-trinitroethylnitramino)-1,2,4,5-tetrazine(NBTAT),first obtained by the authors in 2...The work addresses to the study of the molecular and crystal structure and properties of a new energyintensive compound 3,6-bis(2,2,2-trinitroethylnitramino)-1,2,4,5-tetrazine(NBTAT),first obtained by the authors in 2020.NBTAT compound crystallizes in the monoclinic system,space group P2(1)/n,density at room temperature 1.939 g/cm^(3).The energies of crystal packing and pairwise intermolecular interactions in NBTAT and its unnitrated analogue BTAT were calculated,and their comparative analysis was carried out.The enthalpy of formation of NBTAT molecules was calculated by quantum-chemical methods using Gaussian 09,and the enthalpy of formation of NBTAT in the solid phase(618 kJ/mol)was estimated.The energy capabilities of NBTAT as an oxidizer of solid composite propellants are estimated.It is shown that in metal-free compositions NBTAT is significantly superior to ammonium perchlorate(AP),dinitramide ammonium salt(ADN),HMX,BTAT at all stages of rocket systems,and is comparable to the superdense CL-20 yielding to the latter at the lower stages and slightly winning at the upper stages.展开更多
Background Studies on genetic variation and combining ability are essential tools to employ the suitable breeding programme,particularly for hybrid production,to exploit the heterosis in cross-pollinated crops like co...Background Studies on genetic variation and combining ability are essential tools to employ the suitable breeding programme,particularly for hybrid production,to exploit the heterosis in cross-pollinated crops like cotton.Thus,combining ability studies in desi cotton(Gossypium arboreum L.)was carried out using 13 diverse parents through diallel mating design,evaluating 78 F,hybrids along with their parents,without reciprocals using Griffing's and Hayman's approaches.Results Genotypes H 509,AC 3265,AKH 496,and PBN 565 exhibited superior per se performance,indicating their potential use as parents in future breeding programs to develop superior hybrids.The general combining ability(GCA)effect of the genotypes revealed that AC 3097 and AKA 13-SP1 were good general combiners for most traits in this study.Genotypes PBS 1127-SP1,AKH 496,H 509,N11-54-31-32,and AKA 13-SP1 exhibited strong combining ability,contributing to a significant specific combining ability(SCA)effect in seven selected crosses(AC 3265×PBS1127-SP1,AKH 496×H 509,AKH 496×AC 3097,PBS 1127-SP1×N11-54-31-32,AC 3216×AKA 13-SP1,H 503×N11-54-31-32,and H 509×AKA 13-SP1)for yield improvement.These crosses showed positive heterosis in a positive direction.Conclusion From the present study,five genotypes(AC 3097,AKA 13-SP1,N11-54-31-32,AC 3265,and H 509)were identified as good general combiners for producing hybrids,and seven combinations showed a promising hybrid for future breeding programs.展开更多
Background As the most widely cultivated fiber crop,cotton production depends on hybridization to unlock the yield potential of current varieties.A deep understanding of genetic dissection is crucial for the cultivati...Background As the most widely cultivated fiber crop,cotton production depends on hybridization to unlock the yield potential of current varieties.A deep understanding of genetic dissection is crucial for the cultivation of enhanced hybrid plants with desired traits,such as high yield and fine fiber quality.In this study,the general combining ability(GCA)and specific combining ability(SCA)of yield and fiber quality of nine cotton parents(six lines and three testers)and eighteen F1 crosses produced using a line×tester mating design were analyzed.Results The results revealed significant effects of genotypes,parents,crosses,and interactions between parents and crosses for most of the studied traits.Moreover,the effects of both additive and non-additive gene actions played a notably significant role in the inheritance of most of the yield and fiber quality attributes.The F1 hybrids of(Giza 90×Aust)×Giza 86,Uzbekistan 1×Giza 97,and Giza 96×Giza 97 demonstrated superior performance due to their favorable integration of high yield attributes and premium fiber quality characteristics.Path analysis revealed that lint yield has the highest positive direct effect on seed cotton yield,while lint percentage showed the highest negative direct effect on seed cotton yield.Principal component analysis identified specific parents and hybrids associated with higher cotton yield,fiber quality,and other agronomic traits.Conclusion This study provides insights into identifying potential single-and three-way cross hybrids with superior cotton yield and fiber quality characteristics,laying a foundation for future research on improving fiber quality in cotton.展开更多
基金The Ministry of Science and Higher Education of the Russian Federation(Agreement with Zelinsky Institute of Organic Chemistry RAS No 075-15-2020-803).
文摘The work addresses to the study of the molecular and crystal structure and properties of a new energyintensive compound 3,6-bis(2,2,2-trinitroethylnitramino)-1,2,4,5-tetrazine(NBTAT),first obtained by the authors in 2020.NBTAT compound crystallizes in the monoclinic system,space group P2(1)/n,density at room temperature 1.939 g/cm^(3).The energies of crystal packing and pairwise intermolecular interactions in NBTAT and its unnitrated analogue BTAT were calculated,and their comparative analysis was carried out.The enthalpy of formation of NBTAT molecules was calculated by quantum-chemical methods using Gaussian 09,and the enthalpy of formation of NBTAT in the solid phase(618 kJ/mol)was estimated.The energy capabilities of NBTAT as an oxidizer of solid composite propellants are estimated.It is shown that in metal-free compositions NBTAT is significantly superior to ammonium perchlorate(AP),dinitramide ammonium salt(ADN),HMX,BTAT at all stages of rocket systems,and is comparable to the superdense CL-20 yielding to the latter at the lower stages and slightly winning at the upper stages.
基金supported by ICAR-Central Institute for Cotton Research,Regional Station,Coimbatore,India。
文摘Background Studies on genetic variation and combining ability are essential tools to employ the suitable breeding programme,particularly for hybrid production,to exploit the heterosis in cross-pollinated crops like cotton.Thus,combining ability studies in desi cotton(Gossypium arboreum L.)was carried out using 13 diverse parents through diallel mating design,evaluating 78 F,hybrids along with their parents,without reciprocals using Griffing's and Hayman's approaches.Results Genotypes H 509,AC 3265,AKH 496,and PBN 565 exhibited superior per se performance,indicating their potential use as parents in future breeding programs to develop superior hybrids.The general combining ability(GCA)effect of the genotypes revealed that AC 3097 and AKA 13-SP1 were good general combiners for most traits in this study.Genotypes PBS 1127-SP1,AKH 496,H 509,N11-54-31-32,and AKA 13-SP1 exhibited strong combining ability,contributing to a significant specific combining ability(SCA)effect in seven selected crosses(AC 3265×PBS1127-SP1,AKH 496×H 509,AKH 496×AC 3097,PBS 1127-SP1×N11-54-31-32,AC 3216×AKA 13-SP1,H 503×N11-54-31-32,and H 509×AKA 13-SP1)for yield improvement.These crosses showed positive heterosis in a positive direction.Conclusion From the present study,five genotypes(AC 3097,AKA 13-SP1,N11-54-31-32,AC 3265,and H 509)were identified as good general combiners for producing hybrids,and seven combinations showed a promising hybrid for future breeding programs.
文摘Background As the most widely cultivated fiber crop,cotton production depends on hybridization to unlock the yield potential of current varieties.A deep understanding of genetic dissection is crucial for the cultivation of enhanced hybrid plants with desired traits,such as high yield and fine fiber quality.In this study,the general combining ability(GCA)and specific combining ability(SCA)of yield and fiber quality of nine cotton parents(six lines and three testers)and eighteen F1 crosses produced using a line×tester mating design were analyzed.Results The results revealed significant effects of genotypes,parents,crosses,and interactions between parents and crosses for most of the studied traits.Moreover,the effects of both additive and non-additive gene actions played a notably significant role in the inheritance of most of the yield and fiber quality attributes.The F1 hybrids of(Giza 90×Aust)×Giza 86,Uzbekistan 1×Giza 97,and Giza 96×Giza 97 demonstrated superior performance due to their favorable integration of high yield attributes and premium fiber quality characteristics.Path analysis revealed that lint yield has the highest positive direct effect on seed cotton yield,while lint percentage showed the highest negative direct effect on seed cotton yield.Principal component analysis identified specific parents and hybrids associated with higher cotton yield,fiber quality,and other agronomic traits.Conclusion This study provides insights into identifying potential single-and three-way cross hybrids with superior cotton yield and fiber quality characteristics,laying a foundation for future research on improving fiber quality in cotton.
