The effect of base oils,sulfur-containing multi-functional additives and dispersants in formulated diesel lubricants on lead corrosion was evaluated by a self-established high temperature corrosion bench test.Test lea...The effect of base oils,sulfur-containing multi-functional additives and dispersants in formulated diesel lubricants on lead corrosion was evaluated by a self-established high temperature corrosion bench test.Test lead coupons were analyzed by XPS to determine the resulting surface chemistry.The results showed a close correlation between the oxidation stability of base oil blend and the lead corrosion of formulated diesel lubricants.The zinc dialkyldithiophosphate(ZDDP)and zinc dialkyldithiocarbamate(ZDDC)have formed different protective films on lead coupon surfaces.A more or less amount of the protective film formed is the main factor affecting the degree of lead corrosion.The glassy zinc phosphates protective film formed by ZDDP is more effective than the zinc sulfides film formed by ZDDC.The interaction between dispersants and ZDDP had a significant impact on lead corrosion.展开更多
基金financilly supported by the Research Project of China Petroleum&Chemical Corporation(112066)
文摘The effect of base oils,sulfur-containing multi-functional additives and dispersants in formulated diesel lubricants on lead corrosion was evaluated by a self-established high temperature corrosion bench test.Test lead coupons were analyzed by XPS to determine the resulting surface chemistry.The results showed a close correlation between the oxidation stability of base oil blend and the lead corrosion of formulated diesel lubricants.The zinc dialkyldithiophosphate(ZDDP)and zinc dialkyldithiocarbamate(ZDDC)have formed different protective films on lead coupon surfaces.A more or less amount of the protective film formed is the main factor affecting the degree of lead corrosion.The glassy zinc phosphates protective film formed by ZDDP is more effective than the zinc sulfides film formed by ZDDC.The interaction between dispersants and ZDDP had a significant impact on lead corrosion.
