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高力学强度羟乙基纤维素/聚丙烯酸复合水凝胶的制备 被引量:7
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作者 郑坤 牛力 +3 位作者 刘玉鹏 陈莹 王春鹏 储富祥 《林产化学与工业》 EI CAS CSCD 北大核心 2018年第3期41-47,共7页
利用丙烯酸(AA)单体自由基聚合的方法,将羟乙基纤维素(HEC)作为大分子交联剂,引入聚丙烯酸(PAA)水凝胶中,制备了一种具有氢键交联网络结构的羟乙基纤维素/聚丙烯酸(HEC/PAA)复合水凝胶。当HEC质量分数(以水凝胶固含量计)为20.0%、33.3%... 利用丙烯酸(AA)单体自由基聚合的方法,将羟乙基纤维素(HEC)作为大分子交联剂,引入聚丙烯酸(PAA)水凝胶中,制备了一种具有氢键交联网络结构的羟乙基纤维素/聚丙烯酸(HEC/PAA)复合水凝胶。当HEC质量分数(以水凝胶固含量计)为20.0%、33.3%、42.9%、50.0%和55.5%时,制备的复合水凝胶分别标记为HEC/PAA-1~HEC/PAA-5。采用力学测试和红外光谱(IR)等手段对水凝胶的性能和结构进行了研究。力学测试结果表明:相比于PAA水凝胶较弱的机械性能,复合水凝胶HEC/PAA-2的压缩强度能达到9.52 MPa,对应的压缩断裂应变为91%,压缩断裂能量达到了513.6 kJ/m^3;同时,HEC/PAA水凝胶还表现出了优异的拉伸性能与可恢复性能,HEC/PAA-4的拉伸断裂应力为224.3 k Pa,断裂伸长率为198%,拉伸断裂能量为219.5 kJ/m^3。HEC/PAA-2溶胀150 h时的吸水溶胀率为2.23 g/g。以上结果表明:HEC/PAA复合水凝胶具有的优异力学性能可能源于PAA大分子与HEC大分子之间的氢键作用,它构成了复合水凝胶特殊的网络结构。 展开更多
关键词 氢键 高力学强度 羟乙基纤维素 聚丙烯酸 复合水凝胶
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高力学强度水凝胶的研究进展 被引量:10
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作者 秦绪平 赵芳 冯圣玉 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2012年第3期174-178,共5页
传统的水凝胶由于力学强度差而大大限制了其应用。近年来,从分子水平上改进水凝胶内部微结构提高水凝胶力学强度的方法越来越受到关注。文中综述了提高水凝胶力学强度的各种有效方法,期望研究者们能够在这些方法的基础上进一步深入探讨... 传统的水凝胶由于力学强度差而大大限制了其应用。近年来,从分子水平上改进水凝胶内部微结构提高水凝胶力学强度的方法越来越受到关注。文中综述了提高水凝胶力学强度的各种有效方法,期望研究者们能够在这些方法的基础上进一步深入探讨并扩展其应用领域。 展开更多
关键词 水凝胶 高力学强度 微结构 纳米复合
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高力学强度羟乙基纤维素/聚丙烯酰胺复合水凝胶的制备 被引量:5
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作者 郑坤 赵娇娇 +2 位作者 陈莹 王春鹏 储富祥 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2017年第11期6-11,共6页
通过自由基聚合一步合成了羟乙基纤维素/聚丙烯酰胺(HEC/PAM)复合水凝胶,这种水凝胶具有优异的拉伸性能和压缩性能,可能源于PAM链与HEC链之间的氢键相互作用。经测试,HEC/PAM复合水凝胶可被拉伸至原尺寸的24倍,对应的拉伸断裂应力为113k... 通过自由基聚合一步合成了羟乙基纤维素/聚丙烯酰胺(HEC/PAM)复合水凝胶,这种水凝胶具有优异的拉伸性能和压缩性能,可能源于PAM链与HEC链之间的氢键相互作用。经测试,HEC/PAM复合水凝胶可被拉伸至原尺寸的24倍,对应的拉伸断裂应力为113kPa;90%压缩形变对应的压缩强度达0.87 MPa;水凝胶的最大压缩形变达95%以上。同时,HEC/PAM水凝胶还表现出了优异的可恢复性能。因此,HEC/PAM复合水凝胶在生物医药领域有潜在的应用价值。 展开更多
关键词 羟乙基纤维素 聚丙烯酰胺 复合水凝胶 高力学强度
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Damage and fracture behavior and spatio-temporal evolution of acoustic emission of sandstone before and after laser radiation 被引量:1
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作者 GAO Ming-zhong LIU Jun-jun +6 位作者 LIChun-xiang YANG Ben-gao LI Fei ZHOU Xue-min YANG Lei YANG Zun-dong XIE Jing 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第9期3264-3280,共17页
Laser technology holds significant promise for enhancing rock-breaking efficiency.Experimental investigations were carried out on sandstone subjected to laser radiation,aiming to elucidate its response mechanism to su... Laser technology holds significant promise for enhancing rock-breaking efficiency.Experimental investigations were carried out on sandstone subjected to laser radiation,aiming to elucidate its response mechanism to such radiation.The uniaxial compressive strength of sandstone notably decreases by 22.1%–54.7%following exposure to a 750 W laser for 30 s,indicating a substantial weakening effect.Furthermore,the elastic modulus and Poisson ratio of sandstone exhibit an average decrease of 33.7%and 25.9%,respectively.Simultaneously,laser radiation reduces the brittleness of sandstone,increases the dissipated energy proportion,and shifts the failure mode from tensile to tension-shear composite failure.Following laser radiation,both the number and energy of acoustic emission events in the sandstone register a substantial increase,with a more dispersed distribution of these events.In summary,laser radiation induces notable damage to the mechanical properties of sandstone,leading to a substantial decrease in elastic energy storage capacity.Laser rock breaking technology is expected to be applied in hard rock breaking engineering to significantly reduce the difficulty of rock breaking and improve rock breaking efficiency. 展开更多
关键词 laser rock breaking efficient drilling acoustic emission mechanical damage strength reduction
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Dynamic recrystallization behavior and kinetics of high strength steel 被引量:3
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作者 吴光亮 周超洋 刘新彬 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第5期1007-1014,共8页
The dynamic recrystallization behavior of high strength steel during hot deformation was investigated.The hot compression test was conducted in the temperature range of 950-1150 °C under strain rates of 0.1,1 and... The dynamic recrystallization behavior of high strength steel during hot deformation was investigated.The hot compression test was conducted in the temperature range of 950-1150 °C under strain rates of 0.1,1 and 5 s-1.It is observed that dynamic recrystallization(DRX) is the main flow softening mechanism and the flow stress increases with decreasing temperature and increasing strain rate.The relationship between material constants(Q,n,α and ln A) and strain is identified by the sixth order polynomial fit.The constitutive model is developed to predict the flow stress of the material incorporating the strain softening effect and verified.Moreover,the critical characteristics of DRX are extracted from the stress-strain curves under different deformation conditions by linear regression.The dynamic recrystallization volume fraction decreases with increasing strain rate at a constant temperature or decreasing deformation temperature under a constant strain rate.The kinetics of DRX increases with increasing deformation temperature or strain rate. 展开更多
关键词 flow stress dynamic recrystallization kinetics high strength steel constitutive model material constants
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