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颗粒线度和非谐效应对传感器电极材料导电性能及其热稳定性的影响
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作者 高君华 郑瑞伦 《原子与分子物理学报》 CAS 北大核心 2022年第2期61-68,共8页
本文考虑到原子的非简谐振动,应用固体物理理论和方法,研究了氧传感器多孔电极材料导电性能及热稳定性随温度和颗粒线度的变化规律,探讨原子非简谐振动和材料颗粒线度的影响.结果表明:(1)多孔Pt电极材料的电导率随温度的升高而非线性减... 本文考虑到原子的非简谐振动,应用固体物理理论和方法,研究了氧传感器多孔电极材料导电性能及热稳定性随温度和颗粒线度的变化规律,探讨原子非简谐振动和材料颗粒线度的影响.结果表明:(1)多孔Pt电极材料的电导率随温度的升高而非线性减小;电导率随颗粒半径的增大而非线性增大;电导率随时间增长而减小,但变化极小;(2)多孔Pt电极材料的电导率远小于Pt纳米材料的电导率,也小于块状Pt电极材料的电导率,且颗粒越小,颗粒线度效应越显著;(3)电导率的温度稳定性系数随温度的升高和颗粒线度的减小以及表面层参数的增大而非线性减小,即温度越高、颗粒线度越小、表面层参数越大,电极材料导电性的热稳定性越好;(4)表面层的存在使电导率降低,且降低情况与温度和颗粒线度有关,即颗粒越小,温度越低,电导率下降越明显;非简谐效应对电极材料的电导率几乎没有影响. 展开更多
关键词 传感器多孔电极材料 电导率 电导率的温稳定性系数 颗粒线度 非简谐效应
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New double yield surface model for coarse granular materials incorporating nonlinear unified failure criterion 被引量:3
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作者 刘萌成 刘汉龙 高玉峰 《Journal of Central South University》 SCIE EI CAS 2012年第11期3236-3243,共8页
A new double-yield-sarface (DYS) model was developed to characterize the strength and deformation behaviors of coarse granular materials (CGMs). Two kinds of deformation mechanisms, including the shear and compres... A new double-yield-sarface (DYS) model was developed to characterize the strength and deformation behaviors of coarse granular materials (CGMs). Two kinds of deformation mechanisms, including the shear and compressive plastic deformation, were taken into account in this model, These two deformation mechanisms were described by the shear and compressive yield functions, respectively. The Lode angle dependent formulations of proposed model were deduced by incorporating a 3D nonlinear unified failure criterion. Some comparisons were presented between the numerical predictions of proposed model and test data of true triaxial tests on the modeled rockfills. The model predictions are in good agreement with the test data and capture the strain hardening and plastic volumetric dilation of CGMs. These findings verify the reasonability of current DYS model, and indicate that this model is well suited to reproduce the stress-strain-volume change behavior of CGMs in general. 展开更多
关键词 constitutive model coarse granular material failure criterion DILATANCY yield surface
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