The synthesized chiral amino acid modified porphyrinatozinc(II) exhibited characterized CD spectrum in Soret region. The coupling between the carbonyl group of the amino acid residue and the porphyrin unit is the orig...The synthesized chiral amino acid modified porphyrinatozinc(II) exhibited characterized CD spectrum in Soret region. The coupling between the carbonyl group of the amino acid residue and the porphyrin unit is the origin of the CD spectrum. The premise of the above coupling is the intramolecular interaction between the amino acid residue and the porphyrin unit.展开更多
文摘The synthesized chiral amino acid modified porphyrinatozinc(II) exhibited characterized CD spectrum in Soret region. The coupling between the carbonyl group of the amino acid residue and the porphyrin unit is the origin of the CD spectrum. The premise of the above coupling is the intramolecular interaction between the amino acid residue and the porphyrin unit.
