N-(m-ferrocenylphenyl)-formamide has been synthesized by the reaction of m-ferrocenyl-aniline with DMF, and characterized by elements analysis, IR, 1H NMR, and X-ray structure determination. The crystallized was in th...N-(m-ferrocenylphenyl)-formamide has been synthesized by the reaction of m-ferrocenyl-aniline with DMF, and characterized by elements analysis, IR, 1H NMR, and X-ray structure determination. The crystallized was in the monoclinic, P21/c space group, with a=0.140 94(3) nm, b=0.102 87(2) nm, c=0.100 26(2) nm, β=104.85(3)° and final R indices [I>2σ(I)] R1=0.072 7, wR2=0.184 5. An infinite one-dimensional chain is formed by intermolecular hydrogen bonding N-H...O. Cyclic voltammetry was studied comparing with the parent compound (m-ferrocenylaniline). CCDC: 243511.展开更多
The chlorodibenzyltin dithiopiperidylcarbamate was synthesized by the reaction of dibenzyltin dichloride with dithiopiperidylcarbamate and was characterized by elemental analysis, IR and 1H NMR. The crystal structure ...The chlorodibenzyltin dithiopiperidylcarbamate was synthesized by the reaction of dibenzyltin dichloride with dithiopiperidylcarbamate and was characterized by elemental analysis, IR and 1H NMR. The crystal structure was determined by X ray single crystal diffraction. The crystallographic data are as follows: monoclinic, space group P21, a=0.63464(13)nm, b=1.9110(4)nm, c=0.87367(17)nm, β=97.67(3)°, Z=2, V=1.0501(4)nm3, Dc=1.571g·cm-3, μ=1.546mm-1, F(000)=500, R=0.0209, wR=0.0381 [I ≥2σ(I)]. The str uctures consist of discrete molecules containing five coordinate tin atoms in a seriously distorted trigonal bipyramidal configuration. The molecules are packed in the unit cell in one dimensional chain complex through a weak interaction between the chlorine atom, the sulfur atom and one of the other sulfurs of an adjacent molecule. CCDC: 180034.展开更多
A novel one-dimensional chain complex [Zn(dafo)2(H2O)2](NO3)2 was synthesized. It has been characterized by IR, UV, TGA, Elemental analysis and X-ray diffraction analysis. The crystal belongs to triclinic system, P1 s...A novel one-dimensional chain complex [Zn(dafo)2(H2O)2](NO3)2 was synthesized. It has been characterized by IR, UV, TGA, Elemental analysis and X-ray diffraction analysis. The crystal belongs to triclinic system, P1 space group. The Crystallographic data are: a = 0.702 7(14) nm, b = 0.828 95(17) nm, c = 10.225(2) nm, α = 95.02(3)°, β = 91.45(3)°, γ = 99.85(3)°. The crystal structure data indicate that the Zn(Ⅱ) ion was coordinated with the four nitrogen atoms of two dafo and two oxygen atoms of two coordination water molecules, respectively. The complex has a one-dimensional chain structure, which is formed by hydrogen bonds.展开更多
文摘N-(m-ferrocenylphenyl)-formamide has been synthesized by the reaction of m-ferrocenyl-aniline with DMF, and characterized by elements analysis, IR, 1H NMR, and X-ray structure determination. The crystallized was in the monoclinic, P21/c space group, with a=0.140 94(3) nm, b=0.102 87(2) nm, c=0.100 26(2) nm, β=104.85(3)° and final R indices [I>2σ(I)] R1=0.072 7, wR2=0.184 5. An infinite one-dimensional chain is formed by intermolecular hydrogen bonding N-H...O. Cyclic voltammetry was studied comparing with the parent compound (m-ferrocenylaniline). CCDC: 243511.
文摘The chlorodibenzyltin dithiopiperidylcarbamate was synthesized by the reaction of dibenzyltin dichloride with dithiopiperidylcarbamate and was characterized by elemental analysis, IR and 1H NMR. The crystal structure was determined by X ray single crystal diffraction. The crystallographic data are as follows: monoclinic, space group P21, a=0.63464(13)nm, b=1.9110(4)nm, c=0.87367(17)nm, β=97.67(3)°, Z=2, V=1.0501(4)nm3, Dc=1.571g·cm-3, μ=1.546mm-1, F(000)=500, R=0.0209, wR=0.0381 [I ≥2σ(I)]. The str uctures consist of discrete molecules containing five coordinate tin atoms in a seriously distorted trigonal bipyramidal configuration. The molecules are packed in the unit cell in one dimensional chain complex through a weak interaction between the chlorine atom, the sulfur atom and one of the other sulfurs of an adjacent molecule. CCDC: 180034.
文摘A novel one-dimensional chain complex [Zn(dafo)2(H2O)2](NO3)2 was synthesized. It has been characterized by IR, UV, TGA, Elemental analysis and X-ray diffraction analysis. The crystal belongs to triclinic system, P1 space group. The Crystallographic data are: a = 0.702 7(14) nm, b = 0.828 95(17) nm, c = 10.225(2) nm, α = 95.02(3)°, β = 91.45(3)°, γ = 99.85(3)°. The crystal structure data indicate that the Zn(Ⅱ) ion was coordinated with the four nitrogen atoms of two dafo and two oxygen atoms of two coordination water molecules, respectively. The complex has a one-dimensional chain structure, which is formed by hydrogen bonds.
