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铜离子交换分子筛上NO吸附的IR光谱及TPD研究 被引量:7
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作者 张文祥 贾明君 +5 位作者 张春雷 张丽华 吴通好 孙铁 八寻秀典 岩本正和 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1998年第7期1112-1114,共3页
采用原位IR光谱及TPD技术研究了NO在铜离子交换分子筛上各种表面物种的生成及脱附,并与NO在Cu-ZSM-5上的分解反应性能相关联,考察了Cu-ZSM-5反应活性高的原因及O2的生成机理.NO的吸附状态随分子筛母体... 采用原位IR光谱及TPD技术研究了NO在铜离子交换分子筛上各种表面物种的生成及脱附,并与NO在Cu-ZSM-5上的分解反应性能相关联,考察了Cu-ZSM-5反应活性高的原因及O2的生成机理.NO的吸附状态随分子筛母体种类及铜离子交换度的不同而变化,交换度较高的ZSM-5催化剂上容易形成NO-3物种,该物种对NO分解及O2的生成具有重要作用. 展开更多
关键词 铜离子交换 分子筛 一氧化氮 吸附 分解 催化剂
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银、铜离子双组份无机抗菌剂 被引量:15
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作者 朱伟员 《化工新型材料》 CAS CSCD 2001年第10期37-38,45,共3页
采用水热法制取层状磷酸锆离子交换体 ,通过控制离子交换顺序、交换条件 ,制得含Ag+ 、Cu2 + 双组份杀菌活性成份的无机抗菌剂 ,抗菌剂杀菌力达 10 0 %、防霉等级为0级、具有较好的加工稳定性。
关键词 无机抗菌剂 离子交换 铜离子交换 磷酸锆盐 双组分
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Simulated solution condition experiment and process design for copper deep removal from nickel anodes based on ion-exchange
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作者 TANG Xiao-wei ZHAO Zhong-wei 《Journal of Central South University》 2025年第4期1353-1367,共15页
Removing copper from nickel electrolysis anode solution has been a major keypoint in the nickel metallurgy industry.In this study,we proposed a novel process flow to promote removing copper from nickel electrolysis an... Removing copper from nickel electrolysis anode solution has been a major keypoint in the nickel metallurgy industry.In this study,we proposed a novel process flow to promote removing copper from nickel electrolysis anode solution.A simulated nickel anode solution was designed,and static and dynamic adsorption experiments were conducted to determine the best of solution pH,adsorption time and temperature,resin dosage and particle size,and stirring speed.The optimal conditions were explored for copper removal from nickel electrolysis anode solution.Based on the optimal experimental conditions and the relevant experimental data,a novel process for copper removal from nickel electrolysis anodes was designed and verified.This novel process of copper removal from nickel electrolysis anodes was confirmed with nickel anolyte solution with nickel 50−60 g/L and copper 0.5 g/L.After finishing the novel process of copper removal,the nickel in the purified nickel anolyte became undetectable and copper concentration was 3 mg/L,the novel process of resin adsorption to remove copper from nickel anode solution through static and dynamic adsorptions has an efficacious copper removal.It is a beneficial supplement to traditional methods. 展开更多
关键词 copper removal nickel extract ion exchange RESIN adsorption DESORPTION
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