The condensation reaction of Fc C 6H 4 CO 2 C 6H 4 CHO with H 2N C 6H 4 OC 4H 9 has been found to give Fc C 6H 4 CO 2 C 6H 4 CH=N C 6H 4 OC 4H 9(Fc,ferrocenyl),which is a potential organometallic liquid crystal with s...The condensation reaction of Fc C 6H 4 CO 2 C 6H 4 CHO with H 2N C 6H 4 OC 4H 9 has been found to give Fc C 6H 4 CO 2 C 6H 4 CH=N C 6H 4 OC 4H 9(Fc,ferrocenyl),which is a potential organometallic liquid crystal with single crystal structure.It crystallized as triclinic crystal system,P1 space material group,a=1.2074(2)nm,b=1.23790(10)nm,c=2.0825(4)nm,α=77.980(10)°,β=85.580(10)°=66.430(10)°,Z=5,V=2.7903(7)nm 3,Dc=1.327mg/m 3,F(000)=1168,9785 independent reflections,R=0.0460,wR=0.1063.展开更多
文摘The condensation reaction of Fc C 6H 4 CO 2 C 6H 4 CHO with H 2N C 6H 4 OC 4H 9 has been found to give Fc C 6H 4 CO 2 C 6H 4 CH=N C 6H 4 OC 4H 9(Fc,ferrocenyl),which is a potential organometallic liquid crystal with single crystal structure.It crystallized as triclinic crystal system,P1 space material group,a=1.2074(2)nm,b=1.23790(10)nm,c=2.0825(4)nm,α=77.980(10)°,β=85.580(10)°=66.430(10)°,Z=5,V=2.7903(7)nm 3,Dc=1.327mg/m 3,F(000)=1168,9785 independent reflections,R=0.0460,wR=0.1063.
