To recycle arsenic from an As-Sb fly ash,a newly continuous reductive method for obtaining elemental As with additive of PbO was proposed.In the first reduction stage,PbO promoted the As segregation from the As-Sb fly...To recycle arsenic from an As-Sb fly ash,a newly continuous reductive method for obtaining elemental As with additive of PbO was proposed.In the first reduction stage,PbO promoted the As segregation from the As-Sb fly ash,due to which most As volatilized and Sb retained in roasted residues in phases of As-Sb-Pb-O and As-Sb-Pb alloy.With the increase of PbO and reductant amounts,the Sb fixation rate increased in the first reduction stage,and further the Sb content in the elemental As obtained from the second reduction stage decreased.After being roasted for 30 min at 550℃ with the addition of 20%activated carbon and 12%PbO in the first reduction stage,the As volatilization rate and Sb fixation rate from the As-Sb fly ash reached 92.86%and 79.38%,respectively.Then through the second reduction of the volatile matters at 650℃,the As and Sb contents in the obtained elemental As reached 99.07 wt%and 0.22 wt%respectively,indicating that the obtained As could be used to prepare high purity As,thereby rendering the As-Sb fly ash recycling.展开更多
To accurately evaluate the degradation process of prestressed concrete continuous bridges exposed to aggressive environments in life-cycle,a finite element-based approach with respect to the lifetime performance asses...To accurately evaluate the degradation process of prestressed concrete continuous bridges exposed to aggressive environments in life-cycle,a finite element-based approach with respect to the lifetime performance assessment of concrete bridges was proposed.The existing assessment methods were firstly introduced and compared.Some essential mechanics problems involved in the degradation process,such as the deterioration of materials properties,the reduction of sectional areas and the variation of overall structural performance caused by the first two problems,were investigated and solved.A computer program named CBDAS(Concrete Bridge Durability Analysis System) was written to perform the above-metioned approach.Finally,the degradation process of a prestressed concrete continuous bridge under chloride penetration was discussed.The results show that the concrete normal stress for serviceability limit state exceeds the threshold value after 60 a,but the various performance indicators at ultimate limit state are consistently in the allowable level during service life.Therefore,in the case of prestressed concrete bridges,the serviceability limit state is more possible to have durability problems in life-cycle;however,the performance indicators at ultimate limit state can satisfy the requirements.展开更多
基金Project(51874153) supported by the National Natural Science Foundation of ChinaProject(LZB2021003) supported by Fundamental Research Funds for the Central UniversitiesDHU Distinguished Young Professor Program,China。
文摘To recycle arsenic from an As-Sb fly ash,a newly continuous reductive method for obtaining elemental As with additive of PbO was proposed.In the first reduction stage,PbO promoted the As segregation from the As-Sb fly ash,due to which most As volatilized and Sb retained in roasted residues in phases of As-Sb-Pb-O and As-Sb-Pb alloy.With the increase of PbO and reductant amounts,the Sb fixation rate increased in the first reduction stage,and further the Sb content in the elemental As obtained from the second reduction stage decreased.After being roasted for 30 min at 550℃ with the addition of 20%activated carbon and 12%PbO in the first reduction stage,the As volatilization rate and Sb fixation rate from the As-Sb fly ash reached 92.86%and 79.38%,respectively.Then through the second reduction of the volatile matters at 650℃,the As and Sb contents in the obtained elemental As reached 99.07 wt%and 0.22 wt%respectively,indicating that the obtained As could be used to prepare high purity As,thereby rendering the As-Sb fly ash recycling.
基金Project(2006.318.223.02-01) supported by the Ministry of Transportation and Communications through the Scientific and Technological Funds of ChinaProject(2007AA11Z104) supported by the High Technology Research and Development of ChinaProject(20090072110045) supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China
文摘To accurately evaluate the degradation process of prestressed concrete continuous bridges exposed to aggressive environments in life-cycle,a finite element-based approach with respect to the lifetime performance assessment of concrete bridges was proposed.The existing assessment methods were firstly introduced and compared.Some essential mechanics problems involved in the degradation process,such as the deterioration of materials properties,the reduction of sectional areas and the variation of overall structural performance caused by the first two problems,were investigated and solved.A computer program named CBDAS(Concrete Bridge Durability Analysis System) was written to perform the above-metioned approach.Finally,the degradation process of a prestressed concrete continuous bridge under chloride penetration was discussed.The results show that the concrete normal stress for serviceability limit state exceeds the threshold value after 60 a,but the various performance indicators at ultimate limit state are consistently in the allowable level during service life.Therefore,in the case of prestressed concrete bridges,the serviceability limit state is more possible to have durability problems in life-cycle;however,the performance indicators at ultimate limit state can satisfy the requirements.
