A new Schiff base, 2 hydroxy 1 napthaldehyde 2 amino thiazole(HNATS) and its Cu(Ⅱ) complex was synthesized. The complex[Cu(Ⅱ) (HNATS) 2] could exhibit an efficient peroxitase like catalytic activity, and catalyze th...A new Schiff base, 2 hydroxy 1 napthaldehyde 2 amino thiazole(HNATS) and its Cu(Ⅱ) complex was synthesized. The complex[Cu(Ⅱ) (HNATS) 2] could exhibit an efficient peroxitase like catalytic activity, and catalyze the coupling reaction of 2,4 dichlorophenol and 4 amino antipyrine with hydrogen peroxide. The effect of SDS on the catalytic activity of mimetic enzyme was studied. Based on the reaction, the determination of O ·- 2 by this new spectrophotometric method was developed. The proposed method was used to determine SOD activity of garlic, scallion and onion with satisfactory results.展开更多
In this paper, a novel polymeric complex [MnNa（Salicylate）2（CH3OH）（H2O）]n·0.5nH2O was obtained and characterized by IR spectra, elemental analysis and single crystal X-ray diffraction. The titled complex is...In this paper, a novel polymeric complex [MnNa（Salicylate）2（CH3OH）（H2O）]n·0.5nH2O was obtained and characterized by IR spectra, elemental analysis and single crystal X-ray diffraction. The titled complex is crystallized in triclinic system, space group P1 with a=0.763 82（15） nm, b= 1.037 1（2） nm, c=1.290 9（3） nm, α= 103.59（3）°, β=104.65（3）°, γ=109.50（3）°, V=0.873 6（3） nm 3, Z=2, Dc=1.556 Mg/m 3, Mr=409.20, μ=0.823 mm -1, F（000）=418, R=0.0614, wR= 0.147 6. The activity in catalyzing the superoxygen anionic free radical dismutation was determinated.展开更多
Two diphenylamine compoundsdiclofenac copper(II)and clofenamic copper(II)were synthesized.The molecular composition and structure of these analogues of SOD were determined by IR spectrum and elemental analysis. The ...Two diphenylamine compoundsdiclofenac copper(II)and clofenamic copper(II)were synthesized.The molecular composition and structure of these analogues of SOD were determined by IR spectrum and elemental analysis. The SOD like activity of both analogues of SOD and natural SOD were measured by the modification of NBTillumination method in water solution.The results show that these compounds have good SODlike activities.展开更多
文摘A new Schiff base, 2 hydroxy 1 napthaldehyde 2 amino thiazole(HNATS) and its Cu(Ⅱ) complex was synthesized. The complex[Cu(Ⅱ) (HNATS) 2] could exhibit an efficient peroxitase like catalytic activity, and catalyze the coupling reaction of 2,4 dichlorophenol and 4 amino antipyrine with hydrogen peroxide. The effect of SDS on the catalytic activity of mimetic enzyme was studied. Based on the reaction, the determination of O ·- 2 by this new spectrophotometric method was developed. The proposed method was used to determine SOD activity of garlic, scallion and onion with satisfactory results.
文摘In this paper, a novel polymeric complex [MnNa（Salicylate）2（CH3OH）（H2O）]n·0.5nH2O was obtained and characterized by IR spectra, elemental analysis and single crystal X-ray diffraction. The titled complex is crystallized in triclinic system, space group P1 with a=0.763 82（15） nm, b= 1.037 1（2） nm, c=1.290 9（3） nm, α= 103.59（3）°, β=104.65（3）°, γ=109.50（3）°, V=0.873 6（3） nm 3, Z=2, Dc=1.556 Mg/m 3, Mr=409.20, μ=0.823 mm -1, F（000）=418, R=0.0614, wR= 0.147 6. The activity in catalyzing the superoxygen anionic free radical dismutation was determinated.
文摘Two diphenylamine compoundsdiclofenac copper(II)and clofenamic copper(II)were synthesized.The molecular composition and structure of these analogues of SOD were determined by IR spectrum and elemental analysis. The SOD like activity of both analogues of SOD and natural SOD were measured by the modification of NBTillumination method in water solution.The results show that these compounds have good SODlike activities.
