Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular st...Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular structure and luminescence properties,TADF molecules are far from meeting the needs of practical applications in terms of variety and number.In this paper,three twisted TADF molecules are studied and their photophysical properties are theoretically predicted based on the thermal vibrational correlation function method combined with multiscale calculations.The results show that all the molecules exhibit fast reverse intersystem crossing(RISC)rates(kRISC),predicting their TADF luminescence properties.In addition,the binding of DHPAzSi as the donor unit with different acceptors can change the dihedral angle between the ground and excited states,and the planarity of the acceptors is positively correlated with the reorganization energy,a property that has a strong influence on the non-radiative process.Furthermore,a decrease in the energy of the molecular charge transfer state and an increase in the kRISC were observed in the films.This study not only provides a reliable explanation for the observed experimental results,but also offers valuable insights that can guide the design of future TADF molecules.展开更多
A lightweight aggregate concrete-filled steel tube(LACFST) spatial truss beam was tested under bending load. The performance was studied by the analysis of the beam deflection and strains in its chords and webs. Accor...A lightweight aggregate concrete-filled steel tube(LACFST) spatial truss beam was tested under bending load. The performance was studied by the analysis of the beam deflection and strains in its chords and webs. According to the test results, several assumptions were made to deduce the bearing capacity calculation method based on the force balance of the whole section. An optimal dimension relationship for the truss beam chords was proposed and verified by finite element analysis. Results show that the LACFST spatial truss beam failed after excessive deflection. The strain distribution agreed with Bernoulli-Euler theoretical prediction. The truss beam flexural bearing capacity calculation results matched test evidence with only a 3% difference between the two. Finite element analyses with different chord dimensions show that the ultimate bearing capacity increases as the chord dimensions increase when the chords have a diameter smaller than optimal one; otherwise, it remains almost unchanged as the chord dimensions increase.展开更多
In order to calculate the air temperature of the near surface layer in urban environment,the surface layer air was divided into several sections in the vertical direction,and some energy balance equations were develop...In order to calculate the air temperature of the near surface layer in urban environment,the surface layer air was divided into several sections in the vertical direction,and some energy balance equations were developed for each air layer,in which the heat exchange due to vertical turbulence and horizontal air flow was taken into account.Then,the vertical temperature distribution of the surface layer air was obtained through the coupled calculation using the energy balance equations of underlying surfaces and building walls.Moreover,the measured air temperatures in a small area(with a horizontal scale of less than 500 m) and a large area(with a horizontal scale of more than 1 000 m) in Guangzhou in summer were used to validate the proposed model.The calculated results accord well with the measured ones,with a maximum relative error of 4.18%.It is thus concluded that the proposed model is a high-accuracy method to theoretically analyze the urban heat island and the thermal environment.展开更多
文摘Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular structure and luminescence properties,TADF molecules are far from meeting the needs of practical applications in terms of variety and number.In this paper,three twisted TADF molecules are studied and their photophysical properties are theoretically predicted based on the thermal vibrational correlation function method combined with multiscale calculations.The results show that all the molecules exhibit fast reverse intersystem crossing(RISC)rates(kRISC),predicting their TADF luminescence properties.In addition,the binding of DHPAzSi as the donor unit with different acceptors can change the dihedral angle between the ground and excited states,and the planarity of the acceptors is positively correlated with the reorganization energy,a property that has a strong influence on the non-radiative process.Furthermore,a decrease in the energy of the molecular charge transfer state and an increase in the kRISC were observed in the films.This study not only provides a reliable explanation for the observed experimental results,but also offers valuable insights that can guide the design of future TADF molecules.
基金Project(51208176)supported by the National Natural Science Foundation of ChinaProjects(2012M511187,2013T60493)supported by the China Postdoctoral Science FoundationProject(2015B17414)supported by the Fundamental Research Funds for the Central Universities,China
文摘A lightweight aggregate concrete-filled steel tube(LACFST) spatial truss beam was tested under bending load. The performance was studied by the analysis of the beam deflection and strains in its chords and webs. According to the test results, several assumptions were made to deduce the bearing capacity calculation method based on the force balance of the whole section. An optimal dimension relationship for the truss beam chords was proposed and verified by finite element analysis. Results show that the LACFST spatial truss beam failed after excessive deflection. The strain distribution agreed with Bernoulli-Euler theoretical prediction. The truss beam flexural bearing capacity calculation results matched test evidence with only a 3% difference between the two. Finite element analyses with different chord dimensions show that the ultimate bearing capacity increases as the chord dimensions increase when the chords have a diameter smaller than optimal one; otherwise, it remains almost unchanged as the chord dimensions increase.
基金Project(50808083) supported by the National Natural Science Foundation of China
文摘In order to calculate the air temperature of the near surface layer in urban environment,the surface layer air was divided into several sections in the vertical direction,and some energy balance equations were developed for each air layer,in which the heat exchange due to vertical turbulence and horizontal air flow was taken into account.Then,the vertical temperature distribution of the surface layer air was obtained through the coupled calculation using the energy balance equations of underlying surfaces and building walls.Moreover,the measured air temperatures in a small area(with a horizontal scale of less than 500 m) and a large area(with a horizontal scale of more than 1 000 m) in Guangzhou in summer were used to validate the proposed model.The calculated results accord well with the measured ones,with a maximum relative error of 4.18%.It is thus concluded that the proposed model is a high-accuracy method to theoretically analyze the urban heat island and the thermal environment.
