Rich-nickel layered ternary NCM811 has been widely used in the field of electric vehicles ascribed to its high theoretical specific capacity.However,poor cycling stability and rate-performance hindered its further dev...Rich-nickel layered ternary NCM811 has been widely used in the field of electric vehicles ascribed to its high theoretical specific capacity.However,poor cycling stability and rate-performance hindered its further development.Herein,different amounts of nitrogen-doped carbon were wrapped on the surface of NCM811 via a facile rheological phase method by regulating the amount of dopamine hydrochloride.The effects of the coating amounts on the structure and electrochemical performance are investigated.The DFT calculation,XRD,SEM and XPS reveal that an appropriate amount of nitrogen-doped carbon coating could uniformly form a protective layer on the NCM811 surface and the introduced N could anchor Ni atoms to inhibit the Li^(+)/Ni^(2+)mixing,but excessive amount would reduce Ni^(3+)to Ni^(2+)so as to conversely aggravate Li^(+)/Ni^(2+)mixing.Among the samples,the NCM811-CN0.75 sample exhibits the most excellent electrochemical performance,delivering a high-rate capacity of 151.6 mA·h/g at 10C,and long-term cyclability with 82.2%capacity retention after 300 cycles at 5C,exhibiting remarkable rate-performance and cyclability.展开更多
针对磁性液体在太空微重力环境下的表面不稳定性问题,基于磁性液体表面不稳定性与其磁响应特性的关系,运用OPC(OLE for Process Control)通信技术设计出一种新型磁性液体性能研究装置。研究装置由硬件和软件两部分组成,硬件包括计算机...针对磁性液体在太空微重力环境下的表面不稳定性问题,基于磁性液体表面不稳定性与其磁响应特性的关系,运用OPC(OLE for Process Control)通信技术设计出一种新型磁性液体性能研究装置。研究装置由硬件和软件两部分组成,硬件包括计算机、控制面板、可编程逻辑控制器、电压调节模块和电磁铁等,软件部分主要采用OPC实现MATLAB与S7-200PLC的通信,可通过三种模式调节磁场来研究磁性液体的表面不稳定性,装置运行稳定,实现对磁性液体表面不稳定现象的控制及动态展示。展开更多
为分析靠圆柱孔一侧射出的弓形截面非圆柱液流在横向气流中的脱落现象,使用CLSVOF(Couple Level Set VOF)多相流模型与大涡模拟(LES)模型相结合的方法,对非圆柱液流的脱落过程进行数值模拟。结果表明:非圆柱液流在横向气流中的脱落现象...为分析靠圆柱孔一侧射出的弓形截面非圆柱液流在横向气流中的脱落现象,使用CLSVOF(Couple Level Set VOF)多相流模型与大涡模拟(LES)模型相结合的方法,对非圆柱液流的脱落过程进行数值模拟。结果表明:非圆柱液流在横向气流中的脱落现象是由迎风面上气液密度差产生的Rayleigh-Taylor(R-T)不稳定性和液流边缘气液速度差产生的Kelvin-Helmholtz(K-H)不稳定性共同形成的表面波引起的,同时液流边缘外侧产生的连续漩涡也促进了液流的脱落;横向气流速度增加时,由于表面波增强液流的脱落量增大,横向气流方向改变时由于迎风面上的表面波现象减弱脱落量降低,说明了迎风面上形成的不稳定性表面波是引起液流脱落的主要因素。展开更多
Slope stability is of critical importance in the process of surface-underground mining combination. The influence of underground mining on pit slope stability was mainly discussed, and the self-stabilization of underg...Slope stability is of critical importance in the process of surface-underground mining combination. The influence of underground mining on pit slope stability was mainly discussed, and the self-stabilization of underground stopes was also studied. The random finite element method was used to analyze the probability of the rock mass stability degree of both pit slopes and underground stopes. Meanwhile, 3D elasto-plastic finite element method was used to research into the stress, strain and rock mass failure resulting from mining. The results of numerical simulation indicate that the mining of the underground test stope has certain influence on the stability of the pit slope, but the influence is not great. The safety factor of pit slope is decreased by 0.06, and the failure probability of the pit slope is increased by 1.84%. In addition, the strata yielding zone exists around the underground test stope. The results basically conform to the information coming from the field monitoring.展开更多
In order to investigate the mechanism of nanoparticles enhancing the heat and mass transfer of the ammonia-water absorption process,several types of binary nanofluids were prepared by mixing Al2O3 nanoparticles with p...In order to investigate the mechanism of nanoparticles enhancing the heat and mass transfer of the ammonia-water absorption process,several types of binary nanofluids were prepared by mixing Al2O3 nanoparticles with polyacrylic acid(PAA),TiO2 with polyethylene glycol(PEG 1000),and TiN,SiC,hydroxyapatite(noodle-like) with PEG 10000 to ammonia-water solution,respectively.The thermal conductivities were measured by using a KD2 Pro thermal properties analyzer.The influences of surfactant and ammonia on the dispersion stabilities of the binary nanofluids were investigated by the light absorbency ratio index methods.The results show that the type,content and size of nanoparticles,the temperature as well as the dispersion stability are the key parameters that affect the thermal conductivity of nanofluids.For the given nanoparticle material and the base fluid,the thermal conductivity ratio of the nanofluid to the ammonia-water liquid increases as the nanoparticle content and the temperature are increased,and the diameter of nanoparticle is decreased.Furthermore,the thermal conductivity ratio increases significantly by improving the stabilities of nanofluids,which is achieved by adding surfactants or performing the proper ammonia content in the fluid.展开更多
Non-aqueous emulsions have a wide range of applications in cosmetics,drug-controlled release,and the preparation of functional nanoparticles.However,due to the weaker polarity of non-aqueous solvents,these emulsions o...Non-aqueous emulsions have a wide range of applications in cosmetics,drug-controlled release,and the preparation of functional nanoparticles.However,due to the weaker polarity of non-aqueous solvents,these emulsions often exhibit inferior stability compared to their aqueous counterparts.In this experiment,the properties of quaternary ammonium surfactants in glycerol were investigated through surface tension measurements,to further enhance the stability of n-decane/glycerol emulsions,hydrophilic nanoparticles SiO_(2) were modified in situ using double tailed quaternary ammonium surfactants Di-C_(12)DAB and Di-C_(16)DAB.Stable n-decane/glycerol Pickering emulsions were successfully prepared.These emulsions were stable at 45℃for over six months,and no significant changes in droplet size occurred.The minimum droplet size of the emulsion was only 2-3μm.Contact angle measurements showed that the wettability of the silica surface was tremendously affected by the concentration and the alkyl chain length of the double-tailed surfactants.In the presence of Di-C_(12)DAB,the contact angle of glycerol on the silica surface increased monotonically with the surfactant concentration.This explains the phenomenon that the Pickering emulsions containing Di-C_(12)DAB and silica particles were stable within the contact angle range of 80°-120°.Comparatively,the contact angle of the glycerol on the silica surface in the presence of Di-C_(16)DAB first increased with surfactant concentrations and then decreased,reaching a maximum at 0.6 mmol/L.It can be concluded that Di-C_(12)DAB formed monolayers at the surface of silica particles within all investigated concentrations.On the contrary,Di-C_(16)DAB formed monolayers at concentrations below 0.6 mmol/L and formed double layers at concentrations above 0.6 mmol/L,leading to a non-monotonic change in the contact angle with respect to concentration.Using these stable non-aqueous Pickering emulsions as templates,polymer microspheres with a particle size of 2-3μm were successfully prepared with high yield.This work is helpful to expand the potential applications of non-aqueous emulsions in the encapsulation of drug,controlled release,material preparation,and cosmetic formulations.展开更多
基金Project(2021H0028) supported by the Natural Scienceof Fujian Province,ChinaProject(JAT200455) supported by the Fujian Provincial Young and Middle-aged Teacher Education Project,ChinaProject(fma2023003) supported by the Open Fund of Fujian Provincial Key Laboratory of Functional Materials and Applications,China。
文摘Rich-nickel layered ternary NCM811 has been widely used in the field of electric vehicles ascribed to its high theoretical specific capacity.However,poor cycling stability and rate-performance hindered its further development.Herein,different amounts of nitrogen-doped carbon were wrapped on the surface of NCM811 via a facile rheological phase method by regulating the amount of dopamine hydrochloride.The effects of the coating amounts on the structure and electrochemical performance are investigated.The DFT calculation,XRD,SEM and XPS reveal that an appropriate amount of nitrogen-doped carbon coating could uniformly form a protective layer on the NCM811 surface and the introduced N could anchor Ni atoms to inhibit the Li^(+)/Ni^(2+)mixing,but excessive amount would reduce Ni^(3+)to Ni^(2+)so as to conversely aggravate Li^(+)/Ni^(2+)mixing.Among the samples,the NCM811-CN0.75 sample exhibits the most excellent electrochemical performance,delivering a high-rate capacity of 151.6 mA·h/g at 10C,and long-term cyclability with 82.2%capacity retention after 300 cycles at 5C,exhibiting remarkable rate-performance and cyclability.
文摘针对磁性液体在太空微重力环境下的表面不稳定性问题,基于磁性液体表面不稳定性与其磁响应特性的关系,运用OPC(OLE for Process Control)通信技术设计出一种新型磁性液体性能研究装置。研究装置由硬件和软件两部分组成,硬件包括计算机、控制面板、可编程逻辑控制器、电压调节模块和电磁铁等,软件部分主要采用OPC实现MATLAB与S7-200PLC的通信,可通过三种模式调节磁场来研究磁性液体的表面不稳定性,装置运行稳定,实现对磁性液体表面不稳定现象的控制及动态展示。
文摘为分析靠圆柱孔一侧射出的弓形截面非圆柱液流在横向气流中的脱落现象,使用CLSVOF(Couple Level Set VOF)多相流模型与大涡模拟(LES)模型相结合的方法,对非圆柱液流的脱落过程进行数值模拟。结果表明:非圆柱液流在横向气流中的脱落现象是由迎风面上气液密度差产生的Rayleigh-Taylor(R-T)不稳定性和液流边缘气液速度差产生的Kelvin-Helmholtz(K-H)不稳定性共同形成的表面波引起的,同时液流边缘外侧产生的连续漩涡也促进了液流的脱落;横向气流速度增加时,由于表面波增强液流的脱落量增大,横向气流方向改变时由于迎风面上的表面波现象减弱脱落量降低,说明了迎风面上形成的不稳定性表面波是引起液流脱落的主要因素。
文摘Slope stability is of critical importance in the process of surface-underground mining combination. The influence of underground mining on pit slope stability was mainly discussed, and the self-stabilization of underground stopes was also studied. The random finite element method was used to analyze the probability of the rock mass stability degree of both pit slopes and underground stopes. Meanwhile, 3D elasto-plastic finite element method was used to research into the stress, strain and rock mass failure resulting from mining. The results of numerical simulation indicate that the mining of the underground test stope has certain influence on the stability of the pit slope, but the influence is not great. The safety factor of pit slope is decreased by 0.06, and the failure probability of the pit slope is increased by 1.84%. In addition, the strata yielding zone exists around the underground test stope. The results basically conform to the information coming from the field monitoring.
基金Projects(51176029,50876020) supported by the National Natural Science Foundation of ChinaProject(2011BAJ03B00) supported by the 12th Five-Year National Science and Technology Support Key Program of China Project(ybjj1124) supported by the Foundation of Graduate School of Southeast University,China
文摘In order to investigate the mechanism of nanoparticles enhancing the heat and mass transfer of the ammonia-water absorption process,several types of binary nanofluids were prepared by mixing Al2O3 nanoparticles with polyacrylic acid(PAA),TiO2 with polyethylene glycol(PEG 1000),and TiN,SiC,hydroxyapatite(noodle-like) with PEG 10000 to ammonia-water solution,respectively.The thermal conductivities were measured by using a KD2 Pro thermal properties analyzer.The influences of surfactant and ammonia on the dispersion stabilities of the binary nanofluids were investigated by the light absorbency ratio index methods.The results show that the type,content and size of nanoparticles,the temperature as well as the dispersion stability are the key parameters that affect the thermal conductivity of nanofluids.For the given nanoparticle material and the base fluid,the thermal conductivity ratio of the nanofluid to the ammonia-water liquid increases as the nanoparticle content and the temperature are increased,and the diameter of nanoparticle is decreased.Furthermore,the thermal conductivity ratio increases significantly by improving the stabilities of nanofluids,which is achieved by adding surfactants or performing the proper ammonia content in the fluid.
文摘Non-aqueous emulsions have a wide range of applications in cosmetics,drug-controlled release,and the preparation of functional nanoparticles.However,due to the weaker polarity of non-aqueous solvents,these emulsions often exhibit inferior stability compared to their aqueous counterparts.In this experiment,the properties of quaternary ammonium surfactants in glycerol were investigated through surface tension measurements,to further enhance the stability of n-decane/glycerol emulsions,hydrophilic nanoparticles SiO_(2) were modified in situ using double tailed quaternary ammonium surfactants Di-C_(12)DAB and Di-C_(16)DAB.Stable n-decane/glycerol Pickering emulsions were successfully prepared.These emulsions were stable at 45℃for over six months,and no significant changes in droplet size occurred.The minimum droplet size of the emulsion was only 2-3μm.Contact angle measurements showed that the wettability of the silica surface was tremendously affected by the concentration and the alkyl chain length of the double-tailed surfactants.In the presence of Di-C_(12)DAB,the contact angle of glycerol on the silica surface increased monotonically with the surfactant concentration.This explains the phenomenon that the Pickering emulsions containing Di-C_(12)DAB and silica particles were stable within the contact angle range of 80°-120°.Comparatively,the contact angle of the glycerol on the silica surface in the presence of Di-C_(16)DAB first increased with surfactant concentrations and then decreased,reaching a maximum at 0.6 mmol/L.It can be concluded that Di-C_(12)DAB formed monolayers at the surface of silica particles within all investigated concentrations.On the contrary,Di-C_(16)DAB formed monolayers at concentrations below 0.6 mmol/L and formed double layers at concentrations above 0.6 mmol/L,leading to a non-monotonic change in the contact angle with respect to concentration.Using these stable non-aqueous Pickering emulsions as templates,polymer microspheres with a particle size of 2-3μm were successfully prepared with high yield.This work is helpful to expand the potential applications of non-aqueous emulsions in the encapsulation of drug,controlled release,material preparation,and cosmetic formulations.
