The catalytic activity measurement for the NO+CO reaction over CuO/CeO\-2/\%γ\%\|Al\-2O\-3 catalysts at a low\|temperature(200 ℃) shows that the activity is strongly related to ceria loading amount, and both surface...The catalytic activity measurement for the NO+CO reaction over CuO/CeO\-2/\%γ\%\|Al\-2O\-3 catalysts at a low\|temperature(200 ℃) shows that the activity is strongly related to ceria loading amount, and both surface dispersed ceria species and crystalline CeO\-2 shows a significant enhancement on the activity. The effect of ceria species is contributed to their promoting the reduction of copper oxide species.展开更多
We performed density functional theory calculations of H, C, and O chemisorption on the UN(001) and(111) surfaces using the generalized gradient approximation(GGA) and the Hubbard U parameter and revised Perdew-Burke-...We performed density functional theory calculations of H, C, and O chemisorption on the UN(001) and(111) surfaces using the generalized gradient approximation(GGA) and the Hubbard U parameter and revised Perdew-Burke-Ernzerhof(RPBE) exchange-correlation functional at non-spin polarized level with the periodic slab model. Chemisorption energies vs. distance of molecules from UN(001) and UN(111) surfaces have been optimized for four symmetrical chemisorption sites, respectively. The results show that the Hollow, N-top, and Hollow adsorption sites are the most stable sites for H, C, and O atoms with chemisorption energies of 13.06,25.50 and 27.34 kJ/mol for UN(001) surface, respectively. From the point of adsorbent(UN(001) and UN(111)surfaces in this paper), interaction of O with the chemisorbed surface is of the maximum magnitude, then C and H, which are in agreement with electronegativities of individual atoms. For the UN(001) surface, U-N bond lengths change relatively little(< 9%) as a result of H chemisorption, however C and O chemisorptions result in remarkable changes for U-N bond lengths in interlayer(> 10%). Electronic structure calculations indicate that Bridge position is equivalent with Hollow position, and the most stable chemisorption position for H, C,and O atoms are all Bridge(or Hollow) position for the UN(111) surface. Calculated electronic density of states(DOSs) demonstrate electronic charge transfer between s, p orbitals in chemisorbed atoms and U 6d, 5f orbitals.展开更多
In this talk a review is given of currently carricd out studies on laser-induced desorption from surfaces of compound semiconductors.The reviewincludes only the non-thermal processes.which can be detected by eitherirr...In this talk a review is given of currently carricd out studies on laser-induced desorption from surfaces of compound semiconductors.The reviewincludes only the non-thermal processes.which can be detected by eitherirradiation with laser of subgap photon energies or with extremely low-intensity pulsed lasers.It is emphasized also that laser induced non-thermaldesorption is a powerful technique for surface characterization and surfacecleaning.展开更多
Many earlier experiments have shown that reflection from rock surfaces depends upon surface roughness,in-cidence zenith angle,viewing zenith angle,incidence azimuth and viewing azimuth. However,no research exists show...Many earlier experiments have shown that reflection from rock surfaces depends upon surface roughness,in-cidence zenith angle,viewing zenith angle,incidence azimuth and viewing azimuth. However,no research exists show-ing the interaction effects of these variables. Using granite as a model surface,we have designed an orthogonal,two level test having seven factors. Analysis of variance shows that surface roughness,relative viewing azimuth,and the in-teraction between these two factors are the largest sources of variance in our experiment. Hence we should include the interaction term in reflection models of granite.展开更多
Why do some room and pillar retreat panels encounter abnormal conditions？ What factors deserve the most consideration during the planning and execution phases of mining and what can be done to mitigate those abnormal...Why do some room and pillar retreat panels encounter abnormal conditions？ What factors deserve the most consideration during the planning and execution phases of mining and what can be done to mitigate those abnormal conditions when they are encountered7 To help answer these questions, and to determine some of the relevant factors influencing the conditions of room and pillar （R ＆ P） retreat min- ing entries, four consecutive R ＆ P retreat panels were evaluated. This evaluation was intended to rein- force the influence of topographic changes, depth of cover, multiple-seam interactions, geological conditions, and mining geometry. This paper details observations were made in four consecutive R ＆ P retreat panels and the data were collected from an instrumentation site during retreat mining. The pri- mary focus was on the differences observed among the four panels and within the panels themselves. The instrumentation study was initially planned to evaluate the interactions between primary and secondary support, but produced rather interesting results relating to the loading encountered under the current mining conditions. In addition to the obse^ation and ｜ll^trumentation, numerical modeling was per- formed to evaluate the stress condi~!ons. Both the LaModel 3.0 and Rocscience Phase 2 programs were used to evaluate these four panels, The results of both models indicated a drastic reduction in the vertical stresses experienced in these panels due to the full extraction mining in overlying seams when compared to the full overburden load. Both models showed a higher level of stress associated with the outside entries of the panels. These results agree quite well with the observations and instrumentation studies performed at the mine. These efforts provided two overarching conclusions concerning R ＆ P retreat mine planning and execution. The first was that there are four areas that should not be overlooked during R ＆ P retreat mining： topographic relief, multiple^seaPa stress relief, stress concentrations near the gob edge, and geologic changes in the immediate roof. The second is that in order to successfully retreat an R ＆ P panel, a three-phased approach to the design and analysis of the panel should be conducted： the planning phase, evaluation phase, and monitoring phase.展开更多
文摘The catalytic activity measurement for the NO+CO reaction over CuO/CeO\-2/\%γ\%\|Al\-2O\-3 catalysts at a low\|temperature(200 ℃) shows that the activity is strongly related to ceria loading amount, and both surface dispersed ceria species and crystalline CeO\-2 shows a significant enhancement on the activity. The effect of ceria species is contributed to their promoting the reduction of copper oxide species.
基金Supported by National Natural Science Foundation of China(Nos.51401237,51271198 and 11474358)Self-Topics Fund of Xi’an Research Institute of High Technology(Nos.2014QNJJ018 and YX2012cxpy06)
文摘We performed density functional theory calculations of H, C, and O chemisorption on the UN(001) and(111) surfaces using the generalized gradient approximation(GGA) and the Hubbard U parameter and revised Perdew-Burke-Ernzerhof(RPBE) exchange-correlation functional at non-spin polarized level with the periodic slab model. Chemisorption energies vs. distance of molecules from UN(001) and UN(111) surfaces have been optimized for four symmetrical chemisorption sites, respectively. The results show that the Hollow, N-top, and Hollow adsorption sites are the most stable sites for H, C, and O atoms with chemisorption energies of 13.06,25.50 and 27.34 kJ/mol for UN(001) surface, respectively. From the point of adsorbent(UN(001) and UN(111)surfaces in this paper), interaction of O with the chemisorbed surface is of the maximum magnitude, then C and H, which are in agreement with electronegativities of individual atoms. For the UN(001) surface, U-N bond lengths change relatively little(< 9%) as a result of H chemisorption, however C and O chemisorptions result in remarkable changes for U-N bond lengths in interlayer(> 10%). Electronic structure calculations indicate that Bridge position is equivalent with Hollow position, and the most stable chemisorption position for H, C,and O atoms are all Bridge(or Hollow) position for the UN(111) surface. Calculated electronic density of states(DOSs) demonstrate electronic charge transfer between s, p orbitals in chemisorbed atoms and U 6d, 5f orbitals.
文摘In this talk a review is given of currently carricd out studies on laser-induced desorption from surfaces of compound semiconductors.The reviewincludes only the non-thermal processes.which can be detected by eitherirradiation with laser of subgap photon energies or with extremely low-intensity pulsed lasers.It is emphasized also that laser induced non-thermaldesorption is a powerful technique for surface characterization and surfacecleaning.
基金Projects KZCX3-SW-338-1 supported by the Science and Technology Innovation Foundation of Chinese Academy of Science40572167 by the National Natural Science Foundation of China
文摘Many earlier experiments have shown that reflection from rock surfaces depends upon surface roughness,in-cidence zenith angle,viewing zenith angle,incidence azimuth and viewing azimuth. However,no research exists show-ing the interaction effects of these variables. Using granite as a model surface,we have designed an orthogonal,two level test having seven factors. Analysis of variance shows that surface roughness,relative viewing azimuth,and the in-teraction between these two factors are the largest sources of variance in our experiment. Hence we should include the interaction term in reflection models of granite.
文摘Why do some room and pillar retreat panels encounter abnormal conditions？ What factors deserve the most consideration during the planning and execution phases of mining and what can be done to mitigate those abnormal conditions when they are encountered7 To help answer these questions, and to determine some of the relevant factors influencing the conditions of room and pillar （R ＆ P） retreat min- ing entries, four consecutive R ＆ P retreat panels were evaluated. This evaluation was intended to rein- force the influence of topographic changes, depth of cover, multiple-seam interactions, geological conditions, and mining geometry. This paper details observations were made in four consecutive R ＆ P retreat panels and the data were collected from an instrumentation site during retreat mining. The pri- mary focus was on the differences observed among the four panels and within the panels themselves. The instrumentation study was initially planned to evaluate the interactions between primary and secondary support, but produced rather interesting results relating to the loading encountered under the current mining conditions. In addition to the obse^ation and ｜ll^trumentation, numerical modeling was per- formed to evaluate the stress condi~!ons. Both the LaModel 3.0 and Rocscience Phase 2 programs were used to evaluate these four panels, The results of both models indicated a drastic reduction in the vertical stresses experienced in these panels due to the full extraction mining in overlying seams when compared to the full overburden load. Both models showed a higher level of stress associated with the outside entries of the panels. These results agree quite well with the observations and instrumentation studies performed at the mine. These efforts provided two overarching conclusions concerning R ＆ P retreat mine planning and execution. The first was that there are four areas that should not be overlooked during R ＆ P retreat mining： topographic relief, multiple^seaPa stress relief, stress concentrations near the gob edge, and geologic changes in the immediate roof. The second is that in order to successfully retreat an R ＆ P panel, a three-phased approach to the design and analysis of the panel should be conducted： the planning phase, evaluation phase, and monitoring phase.
