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新型超高效合相色谱技术及其在石化领域的应用 被引量:4
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作者 刘静 黄文氢 张明森 《石油化工》 CAS CSCD 北大核心 2016年第7期885-893,共9页
简单介绍了超高效合相色谱的仪器原理和性能特点,介绍了该技术的主要优势及应用领域,重点综述了超高效合相色谱技术在国内外石化领域中的应用情况,包括复杂低聚物材料组分的分离分析、塑料中残留单体及添加剂分析、油品分析、表面活性... 简单介绍了超高效合相色谱的仪器原理和性能特点,介绍了该技术的主要优势及应用领域,重点综述了超高效合相色谱技术在国内外石化领域中的应用情况,包括复杂低聚物材料组分的分离分析、塑料中残留单体及添加剂分析、油品分析、表面活性剂分析以及精细化工产品中的手性产物的分离分析等,并在此基础上提出了今后超高效合相色谱技术的发展方向。 展开更多
关键词 超高效合相色谱 低聚物分析 聚合物添加分析 油品分析 表面活性剂分析 手性分离
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酸性蓝分光光度法测定氯化十二烷基二甲基苄基铵的改进研究 被引量:4
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作者 施周 王湘 许光眉 《中国环境监测》 CAS CSCD 北大核心 2006年第6期9-13,共5页
对酸性蓝分光光度法测定氯化十二烷基二甲基苄基铵(DDMBAC)进行了改进研究,探讨了分析过程中的影响因素和优化条件,应用统计学原理确定了该方法在实验室内的误差结构、精密度、准确度、线性范围,并建立了空白值的质量控制图。
关键词 季铵盐型表面活性 DDMBAC 分光光度法 酸性蓝1 表面活性剂分析
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Modification technology for separation of oily sludge 被引量:7
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作者 李小兵 刘炯天 +1 位作者 肖云奇 肖鑫 《Journal of Central South University》 SCIE EI CAS 2011年第2期367-373,共7页
Based on the analysis of the properties of oily sludge samples,the effect of modification parameters,such as liquid to solid (L/S) ratio,agitation temperature,agitation intensity,agitation time and pH on the modificat... Based on the analysis of the properties of oily sludge samples,the effect of modification parameters,such as liquid to solid (L/S) ratio,agitation temperature,agitation intensity,agitation time and pH on the modification of oily sludge was investigated with the content of oil remnants in dry sludge as a reference index. Remixing experiments were carried out according to a simplex-lattice design,where Sx4056 was used as the demulsifier,petroleum sulfonate as the surfactant and sodium silicate (Na2SiO3) as the dispersant. The surface modification reagent formulation was optimized by a regression equation on the modified effect and based on the amounts of surface modification reagents. The results show that the content of the oil remaining in dry oily sludge is 0.28% of 10.15% oily sludge,when the reagent concentration rises to 3.5 g/L under the optimum experimental conditions. 展开更多
关键词 oily sludge surface modification REAGENT simplex-lattice design
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Wettability and surfactivity of sodium phosphate surfactants in strong alkali solutions 被引量:4
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作者 陈胜慧 董金凤 《Journal of Central South University》 SCIE EI CAS 2010年第5期924-929,共6页
The wettability,surfactivity and the correlation between wettability and surfactivity of sodium diethylhexylphosphate,sodium diethylhexyl polyoxyethylene phosphate and their complex in NaOH solutions were studied.A co... The wettability,surfactivity and the correlation between wettability and surfactivity of sodium diethylhexylphosphate,sodium diethylhexyl polyoxyethylene phosphate and their complex in NaOH solutions were studied.A complex alkali resistant phosphate surfactant with good permeability was prepared.The wettability of surfactants was investigated by measuring the immersion time,sinking time and capillary effects of nature cotton grey fabric in NaOH solutions.The surfactivity of the surfactants was characterized by measuring the surface tension.The effect of the complex on the surface appearance of cotton grey fabric was also investigated with a scanning electron microscope(SEM) .The results show that all the surfactants exhibit good wettability for cotton grey fabric in 0.5-5.0 mol/L of NaOH solutions,the complex system exhibits better wettability in 5.0-7.0 mol/L of NaOH solutions,in comparison with either corresponding single surfactant component employed,and wettability is well correlative with the surfactivities of the surfactant.SEM images indicate that the cotton grey fabric is well wetted by the alkaline surfactant solution and the quality of fabric is improved. 展开更多
关键词 sodium diethylhexylphosphate sodium diethylhexyl polyoxyethylene phosphate WETTABILITY surfactivity ALKALI SURFACTANT
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