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激光-分子束-表面散射装置的研制 被引量:1
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作者 王利 陆建江 +4 位作者 曹更玉 孙巨龙 吕日昌 孙继武 吴魁 《真空科学与技术》 CSCD 1995年第1期14-22,共9页
介绍了自行设计和加工的激光-分子束-表面散射装置,并对超高真空转动密封结构作了详细描述。差分泵浦的超音速分子束对准样品中心,射入超高真空主室。样品架安放在主室中央,四极质谱检测器可绕样品转动,用来测量表面散射分子的平动... 介绍了自行设计和加工的激光-分子束-表面散射装置,并对超高真空转动密封结构作了详细描述。差分泵浦的超音速分子束对准样品中心,射入超高真空主室。样品架安放在主室中央,四极质谱检测器可绕样品转动,用来测量表面散射分子的平动能及角分布。三个石英窗口作为激光窗口,可用LIF或MPI方法来测量表面散射分子的内能态分布,也可用于研究表面光化学。最后给出了分子束发散角及室温时CH2I2在Ag(110)表面用308um激光光解碎片碘的TOF谱的测量结果。 展开更多
关键词 激光 分子束 表面散射 表面光化学
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中国科学院大连化学物理研究所研究甲醇光催化提高催化剂效能
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《石油化工》 CAS CSCD 北大核心 2013年第1期29-29,共1页
中国科学院大连化学物理研究所将实时双光子光电子能谱研究表面光化学和光催化的方法,应用到TiO2表面光催化反应机理的探索中。该研究将使催化剂的催化速率更快、选择能力更强且稳定性更好。
关键词 中国科学院大连化学物理研究所 催化剂 光催化 表面光化学 甲醇 催化反应机理 光电子能谱 TIO2
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单晶硅作为新型的基因芯片基底的探索 被引量:2
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作者 孙豳 武巍 +1 位作者 洪莲 赵新生 《物理化学学报》 SCIE CAS CSCD 北大核心 2002年第7期581-584,共4页
成功地将单晶Si(111)表面光化学引入官能团的技术与水溶性碳二亚胺催化多肽合成技术结合起来,制备并表征了ss-DNA共价修饰的Si(111)表面.进一步证明了该表面具有特异性杂交的活性和反复使用的稳定性.为制备出可靠的、可反复使用的基因... 成功地将单晶Si(111)表面光化学引入官能团的技术与水溶性碳二亚胺催化多肽合成技术结合起来,制备并表征了ss-DNA共价修饰的Si(111)表面.进一步证明了该表面具有特异性杂交的活性和反复使用的稳定性.为制备出可靠的、可反复使用的基因芯片提供了一种新的方法. 展开更多
关键词 单晶硅 基因芯片 硅(111) 寡聚核苷酸 酯缩合反应 共价键合 表面光化学 DNA 序列测定
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Cooperative effect of surface alloying and laser texturing on tribological performance of lubricated surfaces 被引量:5
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作者 万轶 熊党生 李建亮 《Journal of Central South University》 SCIE EI CAS 2010年第5期906-910,共5页
The cooperative effect of laser surface texturing(LST) and double glow plasma surface alloying on tribological performance of lubricated sliding contacts was investigated.A Nd:YAG laser was used to generate microdimpl... The cooperative effect of laser surface texturing(LST) and double glow plasma surface alloying on tribological performance of lubricated sliding contacts was investigated.A Nd:YAG laser was used to generate microdimples on steel surfaces. Dimples with the diameter of 150μm and the depth of 30-35μm distributed circumferentially on the disc surface.The alloying element Cr was sputtered to the laser texturing steel surface by double glow plasma technique.A deep diffusion layer with a thickness of 30μm and a high hardness of HV900 was formed in this alloy.Tribological experiments of three types of samples(smooth,texturing and texturing+alloying) were conducted with a ring-on-disc tribometer to simulate the face seal.It is found that,in comparison with smooth steel surfaces,the laser texturing samples significantly reduce the friction coefficient.Moreover,the lower wear rate of the sample treated with the two surface techniques is observed. 展开更多
关键词 laser surface texturing double glow plasma surface alloying technology carbon steel tribological performance lubricated surface
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Defect-free surface of quartz glass polished in elastic mode by chemical impact reaction 被引量:1
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作者 彭文强 关朝亮 李圣怡 《Journal of Central South University》 SCIE EI CAS 2014年第12期4438-4444,共7页
Removal of brittle materials in the brittle or ductile mode inevitably causes damaged or strained surface layers containing cracks, scratches or dislocations. Within elastic deformation, the arrangement of each atom c... Removal of brittle materials in the brittle or ductile mode inevitably causes damaged or strained surface layers containing cracks, scratches or dislocations. Within elastic deformation, the arrangement of each atom can be recovered back to its original position without any defects introduced. Based on surface hydroxylation and chemisorption theory, material removal mechanism of quartz glass in the elastic mode is analyzed to obtain defect-free surface. Elastic contact condition between nanoparticle and quartz glass surface is confirmed from the Hertz contact theory model. Atoms on the quartz glass surface are removed by chemical bond generated by impact reaction in the elastic mode, so no defects are generated without mechanical process. Experiment was conducted on a numerically controlled system for nanoparticle jet polishing, and one flat quartz glass was polished in the elastic mode. Results show that scratches on the sample surface are completely removed away with no mechanical defects introduced, and microroughness(Ra) is decreased from 1.23 nm to 0.47 nm. Functional group Ce — O — Si on ceria nanoparticles after polishing was detected directly and indirectly by FTIR, XRD and XPS spectra analysis from which the chemical impact reaction is validated. 展开更多
关键词 defect-free surface chemical impact reaction nanoparticle jet polishing elastic mode
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