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磷氮化改性菜籽油润滑添加剂在菜籽油基础油和矿物油中的摩擦学性能 被引量:14
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作者 方建华 陈波水 +1 位作者 黄伟九 郭小川 《石油炼制与化工》 CAS CSCD 北大核心 2002年第4期29-33,共5页
在菜籽油色拉油中引入磷、氮,合成了两种新型润滑油添加剂——磷氮化改性菜籽油添加剂,并利用红外光谱对其主要官能团进行了鉴定。通过四球试验机考察了它们在菜籽油和矿物油中的抗磨性能与极压性能;用扫描电子显微镜观察分析磨斑表面... 在菜籽油色拉油中引入磷、氮,合成了两种新型润滑油添加剂——磷氮化改性菜籽油添加剂,并利用红外光谱对其主要官能团进行了鉴定。通过四球试验机考察了它们在菜籽油和矿物油中的抗磨性能与极压性能;用扫描电子显微镜观察分析磨斑表面的形貌。结果表明:两种磷氮化改性菜籽油添加剂能明显改善菜籽油的抗磨和减摩性能,但在矿物油中的作用不明显。其润滑作用机理是由于长链菜籽油分子的载体作用、磷和氮的高反应活性以及三者的协同作用与摩擦金属表面形成了一层高强度的吸附膜和/或摩擦化学反应膜。 展开更多
关键词 磷氮化 改性 菜籽油润滑添加剂 基础油 矿物油 摩擦学性能
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Friction and Wear Performance of Magnesium Alloy against Steel under Lubrication of Rapeseed Oil with BN-containing Additive 被引量:6
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作者 Fang Jianhua Chen Boshui +2 位作者 Dong Ling Wu Jiang Wang Jiu 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2011年第1期70-74,共5页
A BN-containing additive,the boron and nitrogen modified rapeseed oil (abbreviated as BNR),was prepared by chemical modification of rapeseed oil with boric and nitrous compounds.The friction and wear performances of t... A BN-containing additive,the boron and nitrogen modified rapeseed oil (abbreviated as BNR),was prepared by chemical modification of rapeseed oil with boric and nitrous compounds.The friction and wear performances of the AZ91D magnesium alloy against the GCr15 bearing steel under lubrication of rapeseed oil containing BNR were evaluated on a SRV tribotester.The topography and chemical species of the worn surfaces of magnesium alloy were analyzed by a scanning electron microscope (SEM) and an X-ray photoelectron spectroscope (XPS),respectively.The test results indicated that the friction and wear of the magnesium alloy-steel tribomates could be effectively reduced by incorporating BNR into the rapeseed oil lubricant.The friction coefficients and the wear scars of magnesium alloy decreased with an increasing content of BNR.The surface lubricated with the BNR-doped rapeseed oil demonstrated less wear as compared with that lubricated with neat rapeseed oil.The enhanced anti-wear and friction-reducing abilities of rapeseed oil provided by BNR in the lubrication of magnesium alloy against steel were ascribed to the formation of a composite boundary lubrication film due to the strong adsorption of BNR and rapeseed oil onto the lubricated surfaces and their tribochemical reactions with magnesium alloy. 展开更多
关键词 friction and wear magnesium alloy BN-containing additive rapeseed oil
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