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硝胺填料HMX的聚合-包覆改性及其应用 被引量:2
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作者 马凤国 吴文辉 谭惠民 《北京理工大学学报》 EI CAS CSCD 2000年第3期389-393,共5页
研究羟乙基丙烯酸酯 -丙烯酸酯 -丙烯腈共聚物 (PHMA)与异佛尔酮二异氰酸酯(IPDI)的乳液聚合反应对硝胺晶体填料 HMX的包覆及其对含能复合材料力学性能的影响 .通过 XPS测试研究预聚物在 HMX表面的吸附及聚合包覆的效果 ,得到最佳的反... 研究羟乙基丙烯酸酯 -丙烯酸酯 -丙烯腈共聚物 (PHMA)与异佛尔酮二异氰酸酯(IPDI)的乳液聚合反应对硝胺晶体填料 HMX的包覆及其对含能复合材料力学性能的影响 .通过 XPS测试研究预聚物在 HMX表面的吸附及聚合包覆的效果 ,得到最佳的反应条件 .通过静态力学性能测试测定复合材料的力学性能 .XPS测试表明 ,乳液聚合比溶液聚合更有利于交联反应在 HMX表面进行 .乳液聚合 -包覆工艺条件为反应温度 4 5℃ ,反应时间 12 0 min,预聚物质量为 0 .15~ 0 .2 0 g时包覆效果最好 .包覆的 HMX用于含能复合材料 ,材料的拉伸强度提高了 2 1.3% ,表明在硝胺 展开更多
关键词 聚合-包覆改性 硝胺填料 HMX 高分子复合材料
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Surface modification of calcium carbonate:A review of theories,methods and applications 被引量:23
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作者 LI Chun-quan LIANG Chao +4 位作者 CHEN Zhen-ming DI Yong-hao ZHENG Shui-lin WEI Shi SUN Zhi-ming 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第9期2589-2611,共23页
Calcium carbonate,which is widely employed as a filler added into the polymer matrix,has large numbers of applications owing to the excellent properties such as low cost,non-toxicity,high natural reserves and biocompa... Calcium carbonate,which is widely employed as a filler added into the polymer matrix,has large numbers of applications owing to the excellent properties such as low cost,non-toxicity,high natural reserves and biocompatibility.Nevertheless,in order to obtain the good filling effect,calcium carbonate needs to be surface modified by organic molecules so as to enhance the dispersion and compatibility within the composites.This review paper systematically introduces the theory,methods,and applications progress of calcium carbonate with surface modification.Additionally,the key factors that affect the properties of the composites as well as the current difficulties and challenges are highlighted.The current research progress and potential application prospects of calcium carbonate in the fields of plastics,rubber,paper,medicine and environmental protection are discussed as well.Generally,this review can provide valuable reference for the modification and comprehensive utilization of calcium carbonate. 展开更多
关键词 calcium carbonate surface modification polymer-based composite monolayer coating modification mechanism
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