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渣油中沥青质胶粒缔合状况初探 被引量:30
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作者 刘东 王宗贤 阙国和 《燃料化学学报》 EI CAS CSCD 北大核心 2002年第3期281-284,共4页
The hydrogen bond of asphaltenes in Liaohe,Gudao and Shengli vacuum residues is studied by use of in situ FT IR spectroscopy, and the strength of hydrogen bonding in different samples is investigated through the o... The hydrogen bond of asphaltenes in Liaohe,Gudao and Shengli vacuum residues is studied by use of in situ FT IR spectroscopy, and the strength of hydrogen bonding in different samples is investigated through the obsorbtivity of hydrogen bond in IR spectra It is found that the strength of Liaohe is bigger than that of Shengli while the strength of Shengli is bigger than that of Gudao At the same time, a concept of "Association Index" is mentioned in this paper, the molecular weight of alphaltenes in Liaohe, Gudao and Shengli vacuum residues is studied by using benzene and nitrobenzene as solvents respectively, the bonding conditions of asphaltene molecules solved in benzene is calculated and expressed through the "Association Index" After comparing the front two results and based on the researches carried out previously we inferred that the function of hydrogen bonding is one of the main facts of the association between the asphaltene 展开更多
关键词 渣油 沥青质胶粒 缔合状况 红外光谱 分子量 氢键
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