Carbon materials with adjustable porosity,controllable het-eroatom doping and low-cost have been received considerable attention as supercapacitor electrodes.However,using carbon materials with abundant micropores,a h...Carbon materials with adjustable porosity,controllable het-eroatom doping and low-cost have been received considerable attention as supercapacitor electrodes.However,using carbon materials with abundant micropores,a high surface area and a high-dopant content for an aqueous su-percapacitor with a high energy output still remains a challenge.We report the easy synthesis of interconnected carbon spheres by a polymerization re-action between p-benzaldehyde and 2,6-diaminopyridine.The synthesis in-volves adjusting the mass ratio of the copolymer and KOH activator to achieve increased charge storage ability and high energy output,which are attributed to the high ion-accessible area provided by the large number of micropores,high N/O contents and rapid ion diffusion channels in the porous structure.At a PMEC∶KOH mass ratio of 1∶1,the high electrolyte ion-adsorption area(2599.76 m^(2) g^(−1))and the N/O dopant atoms of the conductive framework of a typical carbon electrode produce a superior specific capacity(303.2 F g^(−1)@0.5 A g^(−1))giving an assembled symmetric capacitor a high energy delivery of 11.3 Wh kg^(−1)@250 W kg^(−1).This study presents a simple strategy for synthesizing microporous carbon and highlights its potential use in KOH-based supercapacitors.展开更多
Porous spherical MnCo_(2)S_(4) was synthesized by a simple solvothermal method.Thanks to the well-designedbimetallic composition and the unique porous spherical structure,the MnCo_(2)S_(4) electrode exhibited an excep...Porous spherical MnCo_(2)S_(4) was synthesized by a simple solvothermal method.Thanks to the well-designedbimetallic composition and the unique porous spherical structure,the MnCo_(2)S_(4) electrode exhibited an exceptionalspecific capacitance of 190.8 mAh·g^(-1)at 1 A·g^(-1),greatly higher than the corresponding monometallic sulfides MnS(31.7 mAh·g^(-1))and Co_(3)S_(4)(86.7 mAh·g^(-1)).Impressively,the as-assembled MnCo_(2)S_(4)||porous carbon(PC)hybridsupercapacitor(HSC),showed an outstanding energy density of 76.88 Wh·kg^(-1)at a power density of 374.5 W·kg^(-1),remarkable cyclic performance with a capacity retention of 86.8% after 10000 charge-discharge cycles at 5 A·g^(-1),and excellent Coulombic efficiency of 99.7%.展开更多
基金financially supported by University-level key projects of Anhui University of Science and Technology(QNZD2021-04,QNZD2021-07)Scientific Research Foundation for High-level Talents of Anhui University of Science and Technology(2021yjrc22,13210572)+2 种基金Huainan Science and Technology Bureau Plan Project(2023A3111)Open Research Fund Program of Engineering Technology Research Center of Coal Resources Comprehensive Utilization(MTYJZX202204)Natural Science Research Project of Anhui Educational Committee(2023AH051184,2023AH051210)。
文摘Carbon materials with adjustable porosity,controllable het-eroatom doping and low-cost have been received considerable attention as supercapacitor electrodes.However,using carbon materials with abundant micropores,a high surface area and a high-dopant content for an aqueous su-percapacitor with a high energy output still remains a challenge.We report the easy synthesis of interconnected carbon spheres by a polymerization re-action between p-benzaldehyde and 2,6-diaminopyridine.The synthesis in-volves adjusting the mass ratio of the copolymer and KOH activator to achieve increased charge storage ability and high energy output,which are attributed to the high ion-accessible area provided by the large number of micropores,high N/O contents and rapid ion diffusion channels in the porous structure.At a PMEC∶KOH mass ratio of 1∶1,the high electrolyte ion-adsorption area(2599.76 m^(2) g^(−1))and the N/O dopant atoms of the conductive framework of a typical carbon electrode produce a superior specific capacity(303.2 F g^(−1)@0.5 A g^(−1))giving an assembled symmetric capacitor a high energy delivery of 11.3 Wh kg^(−1)@250 W kg^(−1).This study presents a simple strategy for synthesizing microporous carbon and highlights its potential use in KOH-based supercapacitors.
文摘Porous spherical MnCo_(2)S_(4) was synthesized by a simple solvothermal method.Thanks to the well-designedbimetallic composition and the unique porous spherical structure,the MnCo_(2)S_(4) electrode exhibited an exceptionalspecific capacitance of 190.8 mAh·g^(-1)at 1 A·g^(-1),greatly higher than the corresponding monometallic sulfides MnS(31.7 mAh·g^(-1))and Co_(3)S_(4)(86.7 mAh·g^(-1)).Impressively,the as-assembled MnCo_(2)S_(4)||porous carbon(PC)hybridsupercapacitor(HSC),showed an outstanding energy density of 76.88 Wh·kg^(-1)at a power density of 374.5 W·kg^(-1),remarkable cyclic performance with a capacity retention of 86.8% after 10000 charge-discharge cycles at 5 A·g^(-1),and excellent Coulombic efficiency of 99.7%.
