The research demonstrated that laser powder bed fusion(LPBF)coupled with controlled annealing at 1200°C,could significantly increase the proportion of coincidence site lattice(CSL)grain boundary,thereby achieving...The research demonstrated that laser powder bed fusion(LPBF)coupled with controlled annealing at 1200°C,could significantly increase the proportion of coincidence site lattice(CSL)grain boundary,thereby achieving an outstanding synergy of enhanced strength and exceptional ductility.The plastic deformation behavior,strain hardening behavior,and fracture behavior of LPBF 316L steel annealing at 1200℃for 20 h were studied through quasi-in-situ tensile process.It was found that LPBF 316L steel formed a certain proportion of deformation twins during the tensile process,and the formation of twins changed the crystal orientation,thus promoting further slip and crystal deformation.The synergistic effect of slip and twin promoted higher plasticity.LPBF process coupled with controlled annealing at 1200°C for 20 h leads to a ultimate tensile strength of 613 MPa and total elongation of 73.8%.展开更多
Three coordination polymers[Mn(epda)(2,2'⁃bipy)(H_(2)O)](1),[Mn(epda)(phen)](2),and[Co_(2)(epda)2(bpe)2(H_(2)O)_(4)]·5H_(2)O(3)(H2epda=5⁃ethyl⁃pyridine⁃2,3⁃dicarboxylic acid,2,2'⁃bipy=2,2'⁃bipyridine,...Three coordination polymers[Mn(epda)(2,2'⁃bipy)(H_(2)O)](1),[Mn(epda)(phen)](2),and[Co_(2)(epda)2(bpe)2(H_(2)O)_(4)]·5H_(2)O(3)(H2epda=5⁃ethyl⁃pyridine⁃2,3⁃dicarboxylic acid,2,2'⁃bipy=2,2'⁃bipyridine,phen=phenanthroline,bpe=1,2⁃bis(4⁃pyridyl)ethylene)were synthesized by solvothermal reactions and characterized by single⁃crystal X⁃ray diffraction,thermogravimetric analyses,IR spectroscopy and elemental analysis.1 displays a 1D chain struc⁃ture,and these chains are joined by O-H…O hydrogen bonding andπ⁃πstacking interactions to generate a 2D layer structure.2 displays a 2D layer structure,and adjacent layers are generated 3D architecture throughπ⁃πstacking interactions.3 displays a 1D chain structure,and adjacent chains are generated double layer structure through O-H…O hydrogen bonding.The fluorescent properties of 1 and 3 indicate that they can potentially be used as a luminescent sensor.1 was highly selective and sensitive towards o⁃nitrophenol through different detection mechanisms,however,3 was highly selective and sensitive towards 2,4,6⁃trinitrophenol.In addition,the magnetic behavior of 2 has also been investigated.CCDC:2172533,1,2355773,2,2355774,3.展开更多
The predictive capacity of numerical analyses in geotechnical engineering depends strongly on the efficiency of constitutive models used for modeling of interfaces behavior.Interfaces are considered as thin layers of ...The predictive capacity of numerical analyses in geotechnical engineering depends strongly on the efficiency of constitutive models used for modeling of interfaces behavior.Interfaces are considered as thin layers of the soil adjacent to structures boundary whose major role is transferring loads from structures to soil masses.An interface model within the bounding surface plasticity framework and the critical state soil mechanics is presented.To this aim,general formulation of the interface model according to the bounding surface plasticity theory is described first.Similar to granular soils,it has been shown that the mechanical behavior of sand-structure interfaces is highly affected by the interface state that is the combined influences of density and applied normal stress.Therefore,several ingredients of the model are directly related to the interface state.As a result of this feature,the model is enabled to distinguish interfaces in dense state from those in loose state and to provide realistic predictions over wide ranges of density and normal stress values.In evaluation of the model,a reasonable correspondence between the model predictions and the experimental data of various research teams is found.展开更多
Based on the pseudo potential plane-wave method of density functional theory （DFT）, Ti1-xNbxAk （x=0, 0.062 5, 0.083 3, 0.125, 0.250） crystals＇ geometry structure, elastic constants, electronic structure and Mulli...Based on the pseudo potential plane-wave method of density functional theory （DFT）, Ti1-xNbxAk （x=0, 0.062 5, 0.083 3, 0.125, 0.250） crystals＇ geometry structure, elastic constants, electronic structure and Mulliken populations were calculated, and the effects of doping on the geometric structure, electronic structure and bond strength were systematically analyzed. The results show that the influence of Nb on the geometric structure is little in terms of the plasticity, and with the increase of Nb content, the covalent bond strength remarkably reduces, and Ti-Al, Nb-M （M=Ti, Al） and other hybrid bonds enhance; meanwhile, the peak district increases and the pseudo-energy gap first decreases and then increases, the overall band structure narrows, the covalent bond and direction of bonds reduce. The population analysis also shows that the results are consistent with the electronic structure analysis. The density of states of TiAINb shows that Nb doping can enhance the activity of Al and benefit the form of Al2O3 film. All the calculations reveal that the room temperature plasticity and the antioxidation properties of the compounds can be improved with the Nb content of 8.33%-12.5% （mole fraction）.展开更多
In the present study,the thermal,mechanical,and biological properties of xAg/Ti-30Ta(x=0,0.41,0.82 and 2.48 at%)shape memory alloys(SMAs)were investigated.The study was conducted using optical and scanning electron mi...In the present study,the thermal,mechanical,and biological properties of xAg/Ti-30Ta(x=0,0.41,0.82 and 2.48 at%)shape memory alloys(SMAs)were investigated.The study was conducted using optical and scanning electron microscopy(SEM),X-ray diffractometry(XRD),compression test,and shape memory testing.The xAg/Ti-Ta was made using a powder metallurgy technique and microwave-sintering process.The results revealed that the addition of Ag has a significant effect on the pore size and shape,whereas the smallest pore size of 11μm was found with the addition of 0.41 at%along with a relative density of 72%.The fracture stress and strain increased with the addition of Ag,reaching the minimum values around 0.41 at%Ag.Therefore,this composition showed the maximum stress and strain at fracture region.Moreover,0.82 Ag/Ti-Ta shows more excellent corrosion resistance and biocompatibility than other percentages,obtaining almost the same behaviour of the pure Ti and Ti-6Al-4V alloys,which can be recommended for their promising and potential response for biomaterial applications.展开更多
A new strategy is presented to solve robust multi-physics multi-objective optimization problem known as improved multi-objective collaborative optimization （IMOCO） and its extension improved multi-objective robust c...A new strategy is presented to solve robust multi-physics multi-objective optimization problem known as improved multi-objective collaborative optimization （IMOCO） and its extension improved multi-objective robust collaborative （IMORCO）. In this work, the proposed IMORCO approach combined the IMOCO method, the worst possible point （WPP） constraint cuts and the Genetic algorithm NSGA-II type as an optimizer in order to solve the robust optimization problem of multi-physics of microstructures with uncertainties. The optimization problem is hierarchically decomposed into two levels： a microstructure level, and a disciplines levels, For validation purposes, two examples were selected： a numerical example, and an engineering example of capacitive micro machined ultrasonic transducers （CMUT） type. The obtained results are compared with those obtained from robust non-distributed and distributed optimization approach, non-distributed multi-objective robust optimization （NDMORO） and multi-objective collaborative robust optimization （McRO）, respectively. Results obtained from the application of the IMOCO approach to an optimization problem of a CMUT cell have reduced the CPU time by 44% ensuring a Pareto front close to the reference non-distributed multi-objective optimization （NDMO） approach （mahalanobis distance, D2M =0.9503 and overall spread, So=0.2309）. In addition, the consideration of robustness in IMORCO approach applied to a CMUT cell of optimization problem under interval uncertainty has reduced the CPU time by 23% keeping a robust Pareto front overlaps with that obtained by the robust NDMORO approach （D2M =10.3869 and So=0.0537）.展开更多
基金Project(52474418)supported by the National Natural Science Foundation of ChinaProject(YDZJSX2022A012)supported by the Central Guiding Local Science and Technology Development Foundation,China。
文摘The research demonstrated that laser powder bed fusion(LPBF)coupled with controlled annealing at 1200°C,could significantly increase the proportion of coincidence site lattice(CSL)grain boundary,thereby achieving an outstanding synergy of enhanced strength and exceptional ductility.The plastic deformation behavior,strain hardening behavior,and fracture behavior of LPBF 316L steel annealing at 1200℃for 20 h were studied through quasi-in-situ tensile process.It was found that LPBF 316L steel formed a certain proportion of deformation twins during the tensile process,and the formation of twins changed the crystal orientation,thus promoting further slip and crystal deformation.The synergistic effect of slip and twin promoted higher plasticity.LPBF process coupled with controlled annealing at 1200°C for 20 h leads to a ultimate tensile strength of 613 MPa and total elongation of 73.8%.
文摘Three coordination polymers[Mn(epda)(2,2'⁃bipy)(H_(2)O)](1),[Mn(epda)(phen)](2),and[Co_(2)(epda)2(bpe)2(H_(2)O)_(4)]·5H_(2)O(3)(H2epda=5⁃ethyl⁃pyridine⁃2,3⁃dicarboxylic acid,2,2'⁃bipy=2,2'⁃bipyridine,phen=phenanthroline,bpe=1,2⁃bis(4⁃pyridyl)ethylene)were synthesized by solvothermal reactions and characterized by single⁃crystal X⁃ray diffraction,thermogravimetric analyses,IR spectroscopy and elemental analysis.1 displays a 1D chain struc⁃ture,and these chains are joined by O-H…O hydrogen bonding andπ⁃πstacking interactions to generate a 2D layer structure.2 displays a 2D layer structure,and adjacent layers are generated 3D architecture throughπ⁃πstacking interactions.3 displays a 1D chain structure,and adjacent chains are generated double layer structure through O-H…O hydrogen bonding.The fluorescent properties of 1 and 3 indicate that they can potentially be used as a luminescent sensor.1 was highly selective and sensitive towards o⁃nitrophenol through different detection mechanisms,however,3 was highly selective and sensitive towards 2,4,6⁃trinitrophenol.In addition,the magnetic behavior of 2 has also been investigated.CCDC:2172533,1,2355773,2,2355774,3.
文摘The predictive capacity of numerical analyses in geotechnical engineering depends strongly on the efficiency of constitutive models used for modeling of interfaces behavior.Interfaces are considered as thin layers of the soil adjacent to structures boundary whose major role is transferring loads from structures to soil masses.An interface model within the bounding surface plasticity framework and the critical state soil mechanics is presented.To this aim,general formulation of the interface model according to the bounding surface plasticity theory is described first.Similar to granular soils,it has been shown that the mechanical behavior of sand-structure interfaces is highly affected by the interface state that is the combined influences of density and applied normal stress.Therefore,several ingredients of the model are directly related to the interface state.As a result of this feature,the model is enabled to distinguish interfaces in dense state from those in loose state and to provide realistic predictions over wide ranges of density and normal stress values.In evaluation of the model,a reasonable correspondence between the model predictions and the experimental data of various research teams is found.
基金Project(07JJ3102) supported by Hunan Provincial Natural Science Foundation,ChinaProject(k0902132-11) supported by Changsha Municipal Science and Technology,China
文摘Based on the pseudo potential plane-wave method of density functional theory （DFT）, Ti1-xNbxAk （x=0, 0.062 5, 0.083 3, 0.125, 0.250） crystals＇ geometry structure, elastic constants, electronic structure and Mulliken populations were calculated, and the effects of doping on the geometric structure, electronic structure and bond strength were systematically analyzed. The results show that the influence of Nb on the geometric structure is little in terms of the plasticity, and with the increase of Nb content, the covalent bond strength remarkably reduces, and Ti-Al, Nb-M （M=Ti, Al） and other hybrid bonds enhance; meanwhile, the peak district increases and the pseudo-energy gap first decreases and then increases, the overall band structure narrows, the covalent bond and direction of bonds reduce. The population analysis also shows that the results are consistent with the electronic structure analysis. The density of states of TiAINb shows that Nb doping can enhance the activity of Al and benefit the form of Al2O3 film. All the calculations reveal that the room temperature plasticity and the antioxidation properties of the compounds can be improved with the Nb content of 8.33%-12.5% （mole fraction）.
基金Project(Q.J130000.2524.12H60)supported by the Ministry of Higher Education of Malaysia and Universiti Teknologi Malaysia。
文摘In the present study,the thermal,mechanical,and biological properties of xAg/Ti-30Ta(x=0,0.41,0.82 and 2.48 at%)shape memory alloys(SMAs)were investigated.The study was conducted using optical and scanning electron microscopy(SEM),X-ray diffractometry(XRD),compression test,and shape memory testing.The xAg/Ti-Ta was made using a powder metallurgy technique and microwave-sintering process.The results revealed that the addition of Ag has a significant effect on the pore size and shape,whereas the smallest pore size of 11μm was found with the addition of 0.41 at%along with a relative density of 72%.The fracture stress and strain increased with the addition of Ag,reaching the minimum values around 0.41 at%Ag.Therefore,this composition showed the maximum stress and strain at fracture region.Moreover,0.82 Ag/Ti-Ta shows more excellent corrosion resistance and biocompatibility than other percentages,obtaining almost the same behaviour of the pure Ti and Ti-6Al-4V alloys,which can be recommended for their promising and potential response for biomaterial applications.
文摘A new strategy is presented to solve robust multi-physics multi-objective optimization problem known as improved multi-objective collaborative optimization （IMOCO） and its extension improved multi-objective robust collaborative （IMORCO）. In this work, the proposed IMORCO approach combined the IMOCO method, the worst possible point （WPP） constraint cuts and the Genetic algorithm NSGA-II type as an optimizer in order to solve the robust optimization problem of multi-physics of microstructures with uncertainties. The optimization problem is hierarchically decomposed into two levels： a microstructure level, and a disciplines levels, For validation purposes, two examples were selected： a numerical example, and an engineering example of capacitive micro machined ultrasonic transducers （CMUT） type. The obtained results are compared with those obtained from robust non-distributed and distributed optimization approach, non-distributed multi-objective robust optimization （NDMORO） and multi-objective collaborative robust optimization （McRO）, respectively. Results obtained from the application of the IMOCO approach to an optimization problem of a CMUT cell have reduced the CPU time by 44% ensuring a Pareto front close to the reference non-distributed multi-objective optimization （NDMO） approach （mahalanobis distance, D2M =0.9503 and overall spread, So=0.2309）. In addition, the consideration of robustness in IMORCO approach applied to a CMUT cell of optimization problem under interval uncertainty has reduced the CPU time by 23% keeping a robust Pareto front overlaps with that obtained by the robust NDMORO approach （D2M =10.3869 and So=0.0537）.
