Hollow multi-shelled structure(HoMS)is the novel multifunctional structural system,which are con-structed with nanoparticles as structural units,featuring two or more shells,multiple interfaces,and numerous chan-nels ...Hollow multi-shelled structure(HoMS)is the novel multifunctional structural system,which are con-structed with nanoparticles as structural units,featuring two or more shells,multiple interfaces,and numerous chan-nels and demonstrating outstanding properties in energy conversion and mass transfer.In recent years,owing to the breakthroughs in synthetic methods,the diversity of composition and structure of HoMS has been greatly enriched,showing broad application prospects in energy,catalysis,environment and other fields.This review focuses on the research status of HoMS for catalytic applications.Firstly,the new synthesis method for HoMS,namely the sequen-tial templating approach,is introduced from both practical and theoretical perspectives.Then,it summarizes and discusses the structure-performance relationship between the shell structure and catalytic performance.The unique temporal-spatial ordering property of mass transport in HoMS and the major breakthroughs it brings in catalytic applications are discussed.Finally,it looks forward to the opportunities and challenges in the development of HoMS.展开更多
With consideration of the differences between concrete and steel,three solutions using genetic evolutionary structural optimization algorithm were presented to automatically develop optimal strut-and-tie model for dee...With consideration of the differences between concrete and steel,three solutions using genetic evolutionary structural optimization algorithm were presented to automatically develop optimal strut-and-tie model for deep beams.In the finite element analysis of the first method,the concrete and steel rebar are modeled by a plane element and a bar element,respectively.In the second method,the concrete and steel are assigned to two different plane elements,whereas in the third method only one kind of plane element is used with no consideration of the differences of the two materials.A simply supported beam under two point loads was presented as an example to verify the validity of the three proposed methods.The results indicates that all the three methods can generate optimal strut-and-tie models and the third algorithm has powerful capability in searching more optimal results with less computational effort.The effectiveness of the proposed algorithm III has also been demonstrated by other two examples.展开更多
Constrained optimization problems are very important as they are encountered in many science and engineering applications.As a novel evolutionary computation technique,cuckoo search(CS) algorithm has attracted much at...Constrained optimization problems are very important as they are encountered in many science and engineering applications.As a novel evolutionary computation technique,cuckoo search(CS) algorithm has attracted much attention and wide applications,owing to its easy implementation and quick convergence.A hybrid cuckoo pattern search algorithm(HCPS) with feasibility-based rule is proposed for solving constrained numerical and engineering design optimization problems.This algorithm can combine the stochastic exploration of the cuckoo search algorithm and the exploitation capability of the pattern search method.Simulation and comparisons based on several well-known benchmark test functions and structural design optimization problems demonstrate the effectiveness,efficiency and robustness of the proposed HCPS algorithm.展开更多
Ce O2@Si O2 core-shell nanoparticles were prepared by microemulsion method, and metalloporphyrins were immobilized on the Ce O2@Si O2 core-shell nanoparticles surface via amide bond. The supported metalloporphyrin cat...Ce O2@Si O2 core-shell nanoparticles were prepared by microemulsion method, and metalloporphyrins were immobilized on the Ce O2@Si O2 core-shell nanoparticles surface via amide bond. The supported metalloporphyrin catalysts were characterized by N2 adsorption-desorption isotherm(BET), scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray diffraction(XRD), ultraviolet and visible spectroscopy(UV-Vis), and Fourier transform infrared spectroscopy(FT-IR). The results show that the morphology of Ce O2@Si O2 nanoparticles is core-shell microspheres with about 30 nm in diameter, and metalloporphyrins are immobilized on the Ce O2@Si O2 core-shell nanoparticles via amide bond. Especially, the core-shell structure contains multi Ce O2 core and thin Si O2 shell, which may benefit the synergistic effect between the Ce O2 core and the porphyrin anchored on the very thin Si O2 shell. As a result, this supported metalloporphyrin catalysts present comparably high catalytic activity and stability for oxidation of ethylbenzene with molecular oxygen, namely, ethylbenzene conversion remains around 12% with identical selectivity of about 80% for acetophenone even after six-times reuse of the catalyst.展开更多
In this work,a variable structure control(VSC)technique is proposed to achieve satisfactory robustness for unstable processes.Optimal values of unknown parameters of VSC are obtained using Whale optimization algorithm...In this work,a variable structure control(VSC)technique is proposed to achieve satisfactory robustness for unstable processes.Optimal values of unknown parameters of VSC are obtained using Whale optimization algorithm which was recently reported in literature.Stability analysis has been done to verify the suitability of the proposed structure for industrial processes.The proposed control strategy is applied to three different types of unstable processes including non-minimum phase and nonlinear systems.A comparative study ensures that the proposed scheme gives superior performance over the recently reported VSC system.Furthermore,the proposed method gives satisfactory results for a cart inverted pendulum system in the presence of external disturbance and noise.展开更多
Aimed at the problem of classification of non-hydrocarbons of crude oil, the theoretical standpoint that the polarity of a compound depends on the whole structure and composition of molecule instead of a kind of heter...Aimed at the problem of classification of non-hydrocarbons of crude oil, the theoretical standpoint that the polarity of a compound depends on the whole structure and composition of molecule instead of a kind of heteroatom or its functional group was presented. A method was established for the systematically structural identification of nitric compounds in crude oil. The pre-fractionation of a crude oil sample into 7 fractions was performed by di- adsorption column chromatography with neutral aluminum oxide and silica gel. Subsequently, the individual components were obtained by using capillary column gas chromatography, and the types of compounds were detected by a mass spectrometer. In combination with a chemometric resolution, the compounds of fraction were further identified. This method can relieve the difficulty of classical analysis in identifying those species with very low contents or without being completely separated. The structures of 168 nitric compounds in a crude oil sample were determined by this method.展开更多
文摘Hollow multi-shelled structure(HoMS)is the novel multifunctional structural system,which are con-structed with nanoparticles as structural units,featuring two or more shells,multiple interfaces,and numerous chan-nels and demonstrating outstanding properties in energy conversion and mass transfer.In recent years,owing to the breakthroughs in synthetic methods,the diversity of composition and structure of HoMS has been greatly enriched,showing broad application prospects in energy,catalysis,environment and other fields.This review focuses on the research status of HoMS for catalytic applications.Firstly,the new synthesis method for HoMS,namely the sequen-tial templating approach,is introduced from both practical and theoretical perspectives.Then,it summarizes and discusses the structure-performance relationship between the shell structure and catalytic performance.The unique temporal-spatial ordering property of mass transport in HoMS and the major breakthroughs it brings in catalytic applications are discussed.Finally,it looks forward to the opportunities and challenges in the development of HoMS.
基金Project(50908082) supported by the National Natural Science Foundation of ChinaProject(2009ZK3111) supported by the Science and Technology Department of Hunan Province,China
文摘With consideration of the differences between concrete and steel,three solutions using genetic evolutionary structural optimization algorithm were presented to automatically develop optimal strut-and-tie model for deep beams.In the finite element analysis of the first method,the concrete and steel rebar are modeled by a plane element and a bar element,respectively.In the second method,the concrete and steel are assigned to two different plane elements,whereas in the third method only one kind of plane element is used with no consideration of the differences of the two materials.A simply supported beam under two point loads was presented as an example to verify the validity of the three proposed methods.The results indicates that all the three methods can generate optimal strut-and-tie models and the third algorithm has powerful capability in searching more optimal results with less computational effort.The effectiveness of the proposed algorithm III has also been demonstrated by other two examples.
基金Projects([2013]2082,[2009]2061)supported by the Science Technology Foundation of Guizhou Province,ChinaProject([2013]140)supported by the Excellent Science Technology Innovation Talents in Universities of Guizhou Province,ChinaProject(2008040)supported by the Natural Science Research in Education Department of Guizhou Province,China
文摘Constrained optimization problems are very important as they are encountered in many science and engineering applications.As a novel evolutionary computation technique,cuckoo search(CS) algorithm has attracted much attention and wide applications,owing to its easy implementation and quick convergence.A hybrid cuckoo pattern search algorithm(HCPS) with feasibility-based rule is proposed for solving constrained numerical and engineering design optimization problems.This algorithm can combine the stochastic exploration of the cuckoo search algorithm and the exploitation capability of the pattern search method.Simulation and comparisons based on several well-known benchmark test functions and structural design optimization problems demonstrate the effectiveness,efficiency and robustness of the proposed HCPS algorithm.
基金Projects(J21103045,J1210040,J1103312) supported by the National Natural Science Foundation of ChinaProject supported by the Fundamental Research Funds for the Central Universities of China
文摘Ce O2@Si O2 core-shell nanoparticles were prepared by microemulsion method, and metalloporphyrins were immobilized on the Ce O2@Si O2 core-shell nanoparticles surface via amide bond. The supported metalloporphyrin catalysts were characterized by N2 adsorption-desorption isotherm(BET), scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray diffraction(XRD), ultraviolet and visible spectroscopy(UV-Vis), and Fourier transform infrared spectroscopy(FT-IR). The results show that the morphology of Ce O2@Si O2 nanoparticles is core-shell microspheres with about 30 nm in diameter, and metalloporphyrins are immobilized on the Ce O2@Si O2 core-shell nanoparticles via amide bond. Especially, the core-shell structure contains multi Ce O2 core and thin Si O2 shell, which may benefit the synergistic effect between the Ce O2 core and the porphyrin anchored on the very thin Si O2 shell. As a result, this supported metalloporphyrin catalysts present comparably high catalytic activity and stability for oxidation of ethylbenzene with molecular oxygen, namely, ethylbenzene conversion remains around 12% with identical selectivity of about 80% for acetophenone even after six-times reuse of the catalyst.
文摘In this work,a variable structure control(VSC)technique is proposed to achieve satisfactory robustness for unstable processes.Optimal values of unknown parameters of VSC are obtained using Whale optimization algorithm which was recently reported in literature.Stability analysis has been done to verify the suitability of the proposed structure for industrial processes.The proposed control strategy is applied to three different types of unstable processes including non-minimum phase and nonlinear systems.A comparative study ensures that the proposed scheme gives superior performance over the recently reported VSC system.Furthermore,the proposed method gives satisfactory results for a cart inverted pendulum system in the presence of external disturbance and noise.
文摘Aimed at the problem of classification of non-hydrocarbons of crude oil, the theoretical standpoint that the polarity of a compound depends on the whole structure and composition of molecule instead of a kind of heteroatom or its functional group was presented. A method was established for the systematically structural identification of nitric compounds in crude oil. The pre-fractionation of a crude oil sample into 7 fractions was performed by di- adsorption column chromatography with neutral aluminum oxide and silica gel. Subsequently, the individual components were obtained by using capillary column gas chromatography, and the types of compounds were detected by a mass spectrometer. In combination with a chemometric resolution, the compounds of fraction were further identified. This method can relieve the difficulty of classical analysis in identifying those species with very low contents or without being completely separated. The structures of 168 nitric compounds in a crude oil sample were determined by this method.
