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杂质对于磷酸二氢钾结晶的影响研究 被引量:16
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作者 党亚固 费德君 +1 位作者 胡秀英 唐建华 《高校化学工程学报》 EI CAS CSCD 北大核心 2008年第6期911-914,共4页
初步净化后湿法磷酸生产的磷酸二氢钾常含有多种杂质。采用间歇结晶法研究了Fe3+、Al3+、Mg2+、Ca2+、F-、SO42-杂质对磷酸二氢钾结晶介稳区宽度、结晶晶形、诱导时间、结晶生长速度等的影响。实验结果表明:各种杂质离子均导致结晶介稳... 初步净化后湿法磷酸生产的磷酸二氢钾常含有多种杂质。采用间歇结晶法研究了Fe3+、Al3+、Mg2+、Ca2+、F-、SO42-杂质对磷酸二氢钾结晶介稳区宽度、结晶晶形、诱导时间、结晶生长速度等的影响。实验结果表明:各种杂质离子均导致结晶介稳区增大,其中高价金属离子Fe3+、Al3+的影响最为显著,随着Fe3+、Al3+浓度的增加,晶体的长径比显著增大,晶体由棱柱状变为针状,诱导时间延长,晶体生长速度变小,Al3+的影响比Fe3+略大。F-浓度增大,晶体的长径比反而变小。SO42-浓度增大,平均粒径先减小后由于生成聚晶而增大,晶形仍为棱柱状,单晶长径比先缓慢增大而后略有减小。掺杂Ca2+、Mg2+对晶形影响很小。研究结果对于磷酸二氢钾的结晶生长条件选择有重要的参考价值。 展开更多
关键词 杂质 磷酸二氢钾 结晶晶形 介稳区宽度
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湿法磷酸生产精细磷酸一铵结晶改善剂研究 被引量:4
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作者 党亚固 费德君 林晶 《无机盐工业》 CAS 北大核心 2010年第4期49-51,共3页
研究了氨中和法净化湿法磷酸的效果,筛选出了适宜的结晶改善剂。研究结果表明:在中和终点pH为4.0时,铝离子、铁离子、氟离子的净化率均达到98%以上,镁离子的净化率为50%,生成的磷酸一铵结晶细小,呈针状。氟离子作为结晶改善剂,能明显消... 研究了氨中和法净化湿法磷酸的效果,筛选出了适宜的结晶改善剂。研究结果表明:在中和终点pH为4.0时,铝离子、铁离子、氟离子的净化率均达到98%以上,镁离子的净化率为50%,生成的磷酸一铵结晶细小,呈针状。氟离子作为结晶改善剂,能明显消除铝离子对于结晶的影响,但对于铁离子的效果不明显;螯合结晶改善剂Chet-a可以基本消除铁离子的影响。采用氟离子和Chet-a联合作用,可以基本消除杂质对结晶的影响,改善晶形,产品磷酸一铵长径比达3.5:1,可以生产出合格的产品。 展开更多
关键词 磷酸一铵 结晶晶形 杂质 结晶改善剂
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Simulation of dynamic recrystallization for aluminium alloy 7050 using cellular automaton 被引量:4
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作者 黄始全 易幼平 刘超 《Journal of Central South University》 SCIE EI CAS 2009年第1期18-24,共7页
The prediction of microstructure evolution plays an important role in the design of forging process. In the present work, the cellular automaton (CA) program was developed to simulate the process of dynamic recrystall... The prediction of microstructure evolution plays an important role in the design of forging process. In the present work, the cellular automaton (CA) program was developed to simulate the process of dynamic recrystallization (DRX) for aluminium alloy 7050. The material constants in CA models, including dislocation density, nucleation rate and grain growth, were determined by the isothermal compress tests on Gleeble 1500 machine. The model of dislocation density was obtained by linear regression method based on the experimental results. The influences of the deformation parameters on the percentage of DRX and the mean grain size for aluminium alloy 7050 were investigated in details by means of CA simulation. The simulation results show that, as temperature increases from 350 to 450 ℃ at a strain rate of 0.01 s?1, the percentage of DRX also increases greatly and the mean grain size decreases from 50 to 39.3 μm. The mean size of the recrystallied grains (R-grains) mainly depends on the Zener-Hollomon parameter. To obtain fine grain, the desired deformation temperature is determined from 400 to 450 ℃. 展开更多
关键词 aluminium alloy 7050 dynamic recrystallization cellular automaton
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Modeling on dynamic recrystallization of aluminium alloy 7050 during hot compression based on cellular automaton 被引量:6
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作者 李军超 谢志远 +1 位作者 李松蒲 臧艳艳 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第3期497-507,共11页
The dynamic recrystallization(DRX) process of hot compressed aluminium alloy 7050 was predicted using cellular automaton(CA) combined with topology deformation. The hot deformatation characteristics of aluminium alloy... The dynamic recrystallization(DRX) process of hot compressed aluminium alloy 7050 was predicted using cellular automaton(CA) combined with topology deformation. The hot deformatation characteristics of aluminium alloy 7050 were investigated by hot uniaxial compression tests in order to obtain the material parameters used in the CA model. The influences of process parameters(strain, strain rate and temperature) on the fraction of DRX and the average recrystallization grain(R-grain) size were investigated and discussed. It is found that larger stain, higher temperature and lower strain rate(less than 0.1 s^(–1)) are beneficial to the increasing fraction of DRX. And the deformation temperature affects the mean R-grain size much more greatly than other parameters. It is also noted that there is a critical strain for the occurrence of DRX which is related to strain rate and temperature. In addition, it is shown that the CA model with topology deformation is able to simulate the microstructural evolution and the flow behavior of aluminium alloy 7050 material under various deformation conditions. 展开更多
关键词 cellular automaton dynamic recrystallization aluminium alloy 7050 flow stress
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