The microstructure evolutions of two A1-Zn-Mg alloys, one of which was alloyed with Sc and Zr, and the kinetics of A13(SCl-xZrx) precipitates in the A1-Zn-Mg alloy during homogenization were investigated. Both alloy...The microstructure evolutions of two A1-Zn-Mg alloys, one of which was alloyed with Sc and Zr, and the kinetics of A13(SCl-xZrx) precipitates in the A1-Zn-Mg alloy during homogenization were investigated. Both alloys under as-cast condition with supersaturated, non-equilibrium T(Mg32(A1, Zn)49) phase and impurities phase were displayed. When the homogenization temperatures are below 350 ~C, Zn and Mg atoms precipitate from matrix; however, when the temperatures are above 400 ~C, T phase dissolves into matrix, enhancing solid-solution strengthening. Kinetics of A13(Scl.xZrx) precipitates was studied based on Jmat Pro software calculation and the difference values between the hardness of the two alloys in each homogenization condition. The calculations predict that the Sc and Zr solubilities in ct-A1 decline with the presence of Mg and Zn. Investigation of the difference values reveals that when the temperature is between 300 ~C and 350 ~C, the nucleation rate of A13(Sc1-xZrx) precipitates is the highest and the strengthening effect from A13(SCl_xZrx) precipitates is the best. After homogenization at 470℃ for 12 h, non-equilibrium T phase disappears, while impurity phase remains. The mean diameter of A13(Scl_xZrx) precipitates is around 18 urn. Ideas about better fulfilling the potentials of Sc and Zr were proposed at last.展开更多
The solidification microstructure,fracture morphologies,and mechanical properties of an Al-18Si alloy and alloys modified with Al-5Ti and Al-3P master alloys were investigated using an optical microscope,scanning elec...The solidification microstructure,fracture morphologies,and mechanical properties of an Al-18Si alloy and alloys modified with Al-5Ti and Al-3P master alloys were investigated using an optical microscope,scanning electron microscope,and an electronic universal testing machine.The results show that additions of Al-5Ti and Al-3P have significant effects on the size and area fraction of the primary Si and the mechanical properties of the Al-18Si alloy.Compared to the Al-18Si alloy modified with 0.6 wt%Al-5Ti at 850°C,when the Al-18Si alloy was modified with 0.3 wt%Al-5Ti and 0.5 wt%Al-3P at the same temperature,the average size of the primary Si decreased from 39 to 14μm and the area fraction increased from 9.5%to 11.6%.The biggest influencing factor on the tensile strength and elongation of the Al-18Si alloy is the addition of Al-3P,followed by the modification temperature and the addition of Al-5Ti.At a modification temperature of 850°C,the tensile strength and elongation of the Al-18Si alloy modified with 0.3 wt%Al-5Ti+0.5 wt%Al-3P increased by 19.6%and 88.6%,respectively compared to that of the Al-18Si alloy modified with 0.6 wt%Al-5Ti.展开更多
基金Project(JPPT-115-2-948) supported by the National Civilian Matched Project of China
文摘The microstructure evolutions of two A1-Zn-Mg alloys, one of which was alloyed with Sc and Zr, and the kinetics of A13(SCl-xZrx) precipitates in the A1-Zn-Mg alloy during homogenization were investigated. Both alloys under as-cast condition with supersaturated, non-equilibrium T(Mg32(A1, Zn)49) phase and impurities phase were displayed. When the homogenization temperatures are below 350 ~C, Zn and Mg atoms precipitate from matrix; however, when the temperatures are above 400 ~C, T phase dissolves into matrix, enhancing solid-solution strengthening. Kinetics of A13(Scl.xZrx) precipitates was studied based on Jmat Pro software calculation and the difference values between the hardness of the two alloys in each homogenization condition. The calculations predict that the Sc and Zr solubilities in ct-A1 decline with the presence of Mg and Zn. Investigation of the difference values reveals that when the temperature is between 300 ~C and 350 ~C, the nucleation rate of A13(Sc1-xZrx) precipitates is the highest and the strengthening effect from A13(SCl_xZrx) precipitates is the best. After homogenization at 470℃ for 12 h, non-equilibrium T phase disappears, while impurity phase remains. The mean diameter of A13(Scl_xZrx) precipitates is around 18 urn. Ideas about better fulfilling the potentials of Sc and Zr were proposed at last.
基金Project(51571039) supported by the National Natural Science Foundation of China
文摘The solidification microstructure,fracture morphologies,and mechanical properties of an Al-18Si alloy and alloys modified with Al-5Ti and Al-3P master alloys were investigated using an optical microscope,scanning electron microscope,and an electronic universal testing machine.The results show that additions of Al-5Ti and Al-3P have significant effects on the size and area fraction of the primary Si and the mechanical properties of the Al-18Si alloy.Compared to the Al-18Si alloy modified with 0.6 wt%Al-5Ti at 850°C,when the Al-18Si alloy was modified with 0.3 wt%Al-5Ti and 0.5 wt%Al-3P at the same temperature,the average size of the primary Si decreased from 39 to 14μm and the area fraction increased from 9.5%to 11.6%.The biggest influencing factor on the tensile strength and elongation of the Al-18Si alloy is the addition of Al-3P,followed by the modification temperature and the addition of Al-5Ti.At a modification temperature of 850°C,the tensile strength and elongation of the Al-18Si alloy modified with 0.3 wt%Al-5Ti+0.5 wt%Al-3P increased by 19.6%and 88.6%,respectively compared to that of the Al-18Si alloy modified with 0.6 wt%Al-5Ti.