Rocks will suffer different degree of damage under freeze-thaw(FT)cycles,which seriously threatens the long-term stability of rock engineering in cold regions.In order to study the mechanism of rock FT damage,energy c...Rocks will suffer different degree of damage under freeze-thaw(FT)cycles,which seriously threatens the long-term stability of rock engineering in cold regions.In order to study the mechanism of rock FT damage,energy calculation method and energy self-inhibition model are introduced to explore their energy characteristics in this paper.The applicability of the energy self-inhibition model was verified by combining the data of FT cycles and uniaxial compression tests of intact and pre-cracked sandstone samples,as well as published reference data.In addition,the energy evolution characteristics of FT damaged rocks were discussed accordingly.The results indicate that the energy self-inhibition model perfectly characterizes the energy accumulation characteristics of FT damaged rocks under uniaxial compression before the peak strength and the energy dissipation characteristics before microcrack unstable growth stage.Taking the FT damaged cyan sandstone sample as an example,it has gone through two stages dominated by energy dissipation mechanism and energy accumulation mechanism,and the energy rate curve of the pre-cracked sample shows a fall-rise phenomenon when approaching failure.Based on the published reference data,it was found that the peak total input energy and energy storage limit conform to an exponential FT decay model,with corresponding decay constants ranging from 0.0021 to 0.1370 and 0.0018 to 0.1945,respectively.Finally,a linear energy storage equation for FT damaged rocks was proposed,and its high reliability and applicability were verified by combining published reference data,the energy storage coefficient of different types of rocks ranged from 0.823 to 0.992,showing a negative exponential relationship with the initial UCS(uniaxial compressive strength).In summary,the mechanism by which FT weakens the mechanical properties of rocks has been revealed from an energy perspective in this paper,which can provide reference for related issues in cold regions.展开更多
Significant changes in spontaneous potential and exciting currents are observed during water and grout injection in a simulated porous media. Obvious correlations between the seepage flow field and the electric field ...Significant changes in spontaneous potential and exciting currents are observed during water and grout injection in a simulated porous media. Obvious correlations between the seepage flow field and the electric field in the porous media are identified.In this work, a detailed experimental study of geoelectric field variation occurring in water migration was reported by analyzing water and grout injection processes in a simulated porous media. The spontaneous potential varies linearly with the thickness of unsaturated porous media. Very interestingly, the spontaneous potential generated in the second grout injection exhibits some"memory" of previous grouting paths. The decreases in spontaneous potential observed during grout injection is very probably due to that the spontaneous potential variations are primarily caused by electro-filtration potential, as indicated by the far larger viscosity of grout compared to that of water. The geoelectric response can be utilized to effectively identify the grouting paths in water-bearing rocks.展开更多
A multi-domain nonlinear dynamic model of a proportional solenoid valve was presented.The electro-magnetic,mechanical and fluid subsystems of the valve were investigated,including their interactions.Governing equation...A multi-domain nonlinear dynamic model of a proportional solenoid valve was presented.The electro-magnetic,mechanical and fluid subsystems of the valve were investigated,including their interactions.Governing equations of the valve were derived in the form of nonlinear state equations.By comparing the simulated and measured data,the simulation model is validated with a deviation less than 15%,which can be used for the structural design and control algorithm optimization of proportional solenoid valves.展开更多
In order to simulate the airflow in anhydrous case and the water-air flow in groundwater case, a numerical model of airflow in soil was developed. For the nonlinearity of the governing partial differential equation, t...In order to simulate the airflow in anhydrous case and the water-air flow in groundwater case, a numerical model of airflow in soil was developed. For the nonlinearity of the governing partial differential equation, the corresponding discretization and linearization methods were given. Due to the mass transfer between air-phase and water-phase, phase states of the model elements were constantly changing. Thus, parameters of the model were divided into primary ones and secondary ones, and the primary variables changing with phase states and the secondary variables can be obtained by their functional relationship with the primary variables. Additionally, the special definite condition of this numerical model was illustrated. Two examples were given to simulate the airflow in soil whether there was groundwater or not, and the effectiveness of the numerical model is verified by comparing the results of simulation with that of exoeriment.展开更多
Li Fe PO4/C was prepared via solid state reaction and characterized with X-ray powder diffraction and charge–discharge test. As-prepared Li Fe PO4/C has a triphylite structure and exhibits an excellent rate capabilit...Li Fe PO4/C was prepared via solid state reaction and characterized with X-ray powder diffraction and charge–discharge test. As-prepared Li Fe PO4/C has a triphylite structure and exhibits an excellent rate capability and capacity retention. Electrochemical impedance spectroscopy(EIS) was applied to investigate LixFe PO4/C(0<x<1) electrode on temperature variation. The valid equivalent circuit for EIS fitting was determined which contains an intercalation capacitance for Li+ ion accumulation and consumption in the electrode reaction. The surface layer impedance needs to be included in the equivalent circuit when Li Fe PO4/C is deeply delithiated at a relatively high temperature. EIS examination indicates that a temperature rise leads to a better reversibility, lower charge transfer resistance, higher exchange current density J0 and greater Li+ ion diffusion coefficient for the LixFe PO4/C electrode process. The Li+ ion concentration in LixFe PO4/C is potential to impact the Li+ ion diffusion coefficient, and a decrease in the former results in an increase in the latter.展开更多
基金Project(52174088)supported by the National Natural Science Foundation of ChinaProject(104972024JYS0007)supported by the Independent Innovation Research Fund Graduate Free Exploration,Wuhan University of Technology,China。
文摘Rocks will suffer different degree of damage under freeze-thaw(FT)cycles,which seriously threatens the long-term stability of rock engineering in cold regions.In order to study the mechanism of rock FT damage,energy calculation method and energy self-inhibition model are introduced to explore their energy characteristics in this paper.The applicability of the energy self-inhibition model was verified by combining the data of FT cycles and uniaxial compression tests of intact and pre-cracked sandstone samples,as well as published reference data.In addition,the energy evolution characteristics of FT damaged rocks were discussed accordingly.The results indicate that the energy self-inhibition model perfectly characterizes the energy accumulation characteristics of FT damaged rocks under uniaxial compression before the peak strength and the energy dissipation characteristics before microcrack unstable growth stage.Taking the FT damaged cyan sandstone sample as an example,it has gone through two stages dominated by energy dissipation mechanism and energy accumulation mechanism,and the energy rate curve of the pre-cracked sample shows a fall-rise phenomenon when approaching failure.Based on the published reference data,it was found that the peak total input energy and energy storage limit conform to an exponential FT decay model,with corresponding decay constants ranging from 0.0021 to 0.1370 and 0.0018 to 0.1945,respectively.Finally,a linear energy storage equation for FT damaged rocks was proposed,and its high reliability and applicability were verified by combining published reference data,the energy storage coefficient of different types of rocks ranged from 0.823 to 0.992,showing a negative exponential relationship with the initial UCS(uniaxial compressive strength).In summary,the mechanism by which FT weakens the mechanical properties of rocks has been revealed from an energy perspective in this paper,which can provide reference for related issues in cold regions.
基金Project(2013CB036003)supported by the National Basic Research,Program of ChinaProject(2010QNA54)Fundamental Research Funds for the Central Universities,ChinaProject supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions,China
文摘Significant changes in spontaneous potential and exciting currents are observed during water and grout injection in a simulated porous media. Obvious correlations between the seepage flow field and the electric field in the porous media are identified.In this work, a detailed experimental study of geoelectric field variation occurring in water migration was reported by analyzing water and grout injection processes in a simulated porous media. The spontaneous potential varies linearly with the thickness of unsaturated porous media. Very interestingly, the spontaneous potential generated in the second grout injection exhibits some"memory" of previous grouting paths. The decreases in spontaneous potential observed during grout injection is very probably due to that the spontaneous potential variations are primarily caused by electro-filtration potential, as indicated by the far larger viscosity of grout compared to that of water. The geoelectric response can be utilized to effectively identify the grouting paths in water-bearing rocks.
基金Project(2008ZHZX1A0502) supported by the Independence Innovation Achievements Transformation Crucial Special Program of Shandong Province,China
文摘A multi-domain nonlinear dynamic model of a proportional solenoid valve was presented.The electro-magnetic,mechanical and fluid subsystems of the valve were investigated,including their interactions.Governing equations of the valve were derived in the form of nonlinear state equations.By comparing the simulated and measured data,the simulation model is validated with a deviation less than 15%,which can be used for the structural design and control algorithm optimization of proportional solenoid valves.
基金Project(Y5080022) supported by the Natural Science Foundation of Zhejiang Province,ChinaProject(RC1202) supported by Scientific and Technological Program of Water Resources Department of Zhejiang Province in 2012,ChinaProject(Y201224384) supported by Scientific Research Program of Education Department of Zhejiang Province in 2012,China
文摘In order to simulate the airflow in anhydrous case and the water-air flow in groundwater case, a numerical model of airflow in soil was developed. For the nonlinearity of the governing partial differential equation, the corresponding discretization and linearization methods were given. Due to the mass transfer between air-phase and water-phase, phase states of the model elements were constantly changing. Thus, parameters of the model were divided into primary ones and secondary ones, and the primary variables changing with phase states and the secondary variables can be obtained by their functional relationship with the primary variables. Additionally, the special definite condition of this numerical model was illustrated. Two examples were given to simulate the airflow in soil whether there was groundwater or not, and the effectiveness of the numerical model is verified by comparing the results of simulation with that of exoeriment.
基金Project(2010ZC051)supported by the Natural Science Foundation of Yunnan Province,ChinaProject(20140439)supported by Analysis and Testing Foundation from Kunming University of Science and Technology,ChinaProject(14118245)supported by Starting Research Fund from Kunming University of Science and Technology,China
文摘Li Fe PO4/C was prepared via solid state reaction and characterized with X-ray powder diffraction and charge–discharge test. As-prepared Li Fe PO4/C has a triphylite structure and exhibits an excellent rate capability and capacity retention. Electrochemical impedance spectroscopy(EIS) was applied to investigate LixFe PO4/C(0<x<1) electrode on temperature variation. The valid equivalent circuit for EIS fitting was determined which contains an intercalation capacitance for Li+ ion accumulation and consumption in the electrode reaction. The surface layer impedance needs to be included in the equivalent circuit when Li Fe PO4/C is deeply delithiated at a relatively high temperature. EIS examination indicates that a temperature rise leads to a better reversibility, lower charge transfer resistance, higher exchange current density J0 and greater Li+ ion diffusion coefficient for the LixFe PO4/C electrode process. The Li+ ion concentration in LixFe PO4/C is potential to impact the Li+ ion diffusion coefficient, and a decrease in the former results in an increase in the latter.
