Electrodeposition of aluminum from benzene-tetrahydrofuran-Al Cl3-Li Al H4 was studied at room temperature. Galvanostatic electrolysis was used to investigate the effect of various parameters on deposit morphology and...Electrodeposition of aluminum from benzene-tetrahydrofuran-Al Cl3-Li Al H4 was studied at room temperature. Galvanostatic electrolysis was used to investigate the effect of various parameters on deposit morphology and crystal size, including current density, temperature, molar ratio of benzene/tetrahydrofuran and stirring speed. The deposit microstructure was adjusted by changing the parameters, and the optimum operating conditions were determined. Dense, bright and adherent aluminum coatings were obtained over a wide range of current densities(10-25 m A/cm2), molar ratio of benzene and tetrahydrofuran(4:1 to 7:8) and stirring speeds(200-500 r/min). Smaller grain sizes and well-adhered deposits were obtained at lower temperatures. Aluminum-magnesium alloys could potentially be used as hydrogen storage materials. A novel method for Al-Mg deposition was proposed by using pure Mg anodes in the organic solvents system benzene-tetrahydrofuran-Al Cl3-Li Al H4. XRD shows that the aluminum-magnesium alloys are mainly Al3Mg2 and Al12Mg17.展开更多
With the experiment and finite element simulation, the influences of power ultrasonic on the solidification structure of 7050 aluminum alloy ingot in semi-continuous casting were researched, and the effects of casting...With the experiment and finite element simulation, the influences of power ultrasonic on the solidification structure of 7050 aluminum alloy ingot in semi-continuous casting were researched, and the effects of casting speed on solidification structure in ultrasonic field were also analyzed. The experiment and simulation results show that the solidification structure of the ingot is homogeneously distributed, and its grain size is obviously refined at ultrasonic power of 240 W. The average grain sizes, which can be seen from the Leica microscope, are less than 100 μm. When the casting speed is 45-50 mm/min, the best grain refinement is obtained.展开更多
The dynamic recrystallization(DRX) process of hot compressed aluminium alloy 7050 was predicted using cellular automaton(CA) combined with topology deformation. The hot deformatation characteristics of aluminium alloy...The dynamic recrystallization(DRX) process of hot compressed aluminium alloy 7050 was predicted using cellular automaton(CA) combined with topology deformation. The hot deformatation characteristics of aluminium alloy 7050 were investigated by hot uniaxial compression tests in order to obtain the material parameters used in the CA model. The influences of process parameters(strain, strain rate and temperature) on the fraction of DRX and the average recrystallization grain(R-grain) size were investigated and discussed. It is found that larger stain, higher temperature and lower strain rate(less than 0.1 s^(–1)) are beneficial to the increasing fraction of DRX. And the deformation temperature affects the mean R-grain size much more greatly than other parameters. It is also noted that there is a critical strain for the occurrence of DRX which is related to strain rate and temperature. In addition, it is shown that the CA model with topology deformation is able to simulate the microstructural evolution and the flow behavior of aluminium alloy 7050 material under various deformation conditions.展开更多
基金Projects(51101104,51372156)supported by the National Natural Science Foundation of ChinaProject(LJQ2015074)supported by the Program for Liaoning Excellent Talents in University,China
文摘Electrodeposition of aluminum from benzene-tetrahydrofuran-Al Cl3-Li Al H4 was studied at room temperature. Galvanostatic electrolysis was used to investigate the effect of various parameters on deposit morphology and crystal size, including current density, temperature, molar ratio of benzene/tetrahydrofuran and stirring speed. The deposit microstructure was adjusted by changing the parameters, and the optimum operating conditions were determined. Dense, bright and adherent aluminum coatings were obtained over a wide range of current densities(10-25 m A/cm2), molar ratio of benzene and tetrahydrofuran(4:1 to 7:8) and stirring speeds(200-500 r/min). Smaller grain sizes and well-adhered deposits were obtained at lower temperatures. Aluminum-magnesium alloys could potentially be used as hydrogen storage materials. A novel method for Al-Mg deposition was proposed by using pure Mg anodes in the organic solvents system benzene-tetrahydrofuran-Al Cl3-Li Al H4. XRD shows that the aluminum-magnesium alloys are mainly Al3Mg2 and Al12Mg17.
基金Project(2010CB731700) supported by the National Basic Research Program of China
文摘With the experiment and finite element simulation, the influences of power ultrasonic on the solidification structure of 7050 aluminum alloy ingot in semi-continuous casting were researched, and the effects of casting speed on solidification structure in ultrasonic field were also analyzed. The experiment and simulation results show that the solidification structure of the ingot is homogeneously distributed, and its grain size is obviously refined at ultrasonic power of 240 W. The average grain sizes, which can be seen from the Leica microscope, are less than 100 μm. When the casting speed is 45-50 mm/min, the best grain refinement is obtained.
基金Project(2012ZX04010-8)supported by National Key Technology R&D Program of China
文摘The dynamic recrystallization(DRX) process of hot compressed aluminium alloy 7050 was predicted using cellular automaton(CA) combined with topology deformation. The hot deformatation characteristics of aluminium alloy 7050 were investigated by hot uniaxial compression tests in order to obtain the material parameters used in the CA model. The influences of process parameters(strain, strain rate and temperature) on the fraction of DRX and the average recrystallization grain(R-grain) size were investigated and discussed. It is found that larger stain, higher temperature and lower strain rate(less than 0.1 s^(–1)) are beneficial to the increasing fraction of DRX. And the deformation temperature affects the mean R-grain size much more greatly than other parameters. It is also noted that there is a critical strain for the occurrence of DRX which is related to strain rate and temperature. In addition, it is shown that the CA model with topology deformation is able to simulate the microstructural evolution and the flow behavior of aluminium alloy 7050 material under various deformation conditions.
