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挤压吹塑过程中淀粉的粉、母粒、膜三态结构演变规律 被引量:2
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作者 朱洁 崔波 +2 位作者 高伟 王琨 贾思强 《食品与机械》 北大核心 2021年第9期23-28,共6页
目的:研究淀粉在挤压吹塑过程中粉、母粒、膜三态的结构演变规律。方法:以羟丙基二淀粉磷酸酯为原料,通过挤压吹塑制备淀粉膜。采用傅里叶红外光谱—衰减全反射(FTIR-ATR)、X-射线衍射(XRD)、热稳定分析仪(TGA)、凝胶渗透色谱(GPC)等技... 目的:研究淀粉在挤压吹塑过程中粉、母粒、膜三态的结构演变规律。方法:以羟丙基二淀粉磷酸酯为原料,通过挤压吹塑制备淀粉膜。采用傅里叶红外光谱—衰减全反射(FTIR-ATR)、X-射线衍射(XRD)、热稳定分析仪(TGA)、凝胶渗透色谱(GPC)等技术手段,分析淀粉在粉态、母粒态和膜态下的结晶结构、热稳定性及分子结构变化。结果:经挤压后,淀粉晶型由粉态的A型转变为母粒态和膜态的V型,且膜态样品的衍生峰强度相比于母粒态增加;淀粉分子发生降解导致相对分子质量降低;同时,三态样品的水分含量和溶解度呈不同的变化趋势。结论:挤压吹塑过程中,挤压机的高温、高剪切,促进成了膜组分间的相互作用,破坏了淀粉分子结构。 展开更多
关键词 挤压吹塑 粉态 母粒 结晶结构 热稳定性
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大焦炉生产焦炭热态粉化性能的研究 被引量:3
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作者 钱贵 徐靖 +2 位作者 张小勇 樊俊宝 张代林 《煤炭转化》 CAS CSCD 北大核心 2021年第2期18-24,共7页
针对焦炭在高炉中受到不同料层间的挤压、摩擦以及CO2溶损反应引起的粉化行为,采用高温连续热反应装置考察大焦炉(7 m)生产焦炭与单种煤所炼焦炭在国标条件等30%反应量及非等温条件下对反应速率和不同转鼓转数等参数的影响,揭示了焦炭... 针对焦炭在高炉中受到不同料层间的挤压、摩擦以及CO2溶损反应引起的粉化行为,采用高温连续热反应装置考察大焦炉(7 m)生产焦炭与单种煤所炼焦炭在国标条件等30%反应量及非等温条件下对反应速率和不同转鼓转数等参数的影响,揭示了焦炭热态粉化性能的差异性与CO2反应的劣化机理。结果表明:转鼓转数在350 r~600 r时,非等温和国标条件下焦炭粉化率的特征变化量(Δf)上升的速率趋于稳定,而等反应量30%条件下Δf有轻微下降;焦炭的粉化率与高温碳溶反应时间呈正比,CO2与焦炭内部气孔碳基质扩孔和开孔效应导致其劣化粉化。 展开更多
关键词 大焦炉 化性能 碳溶反应 劣化机理 气孔结构
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北京怀柔地区钉型腐殖酸复混板栗专用肥的研究初报 被引量:2
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作者 魏刚 周金池 +1 位作者 孙福 王晓军 《北京林业大学学报》 CAS CSCD 北大核心 1998年第4期87-92,共6页
通过在北京市怀柔县沙峪乡红军庄低产坡地做板栗专用肥试验,将新型板栗复混专用肥(“钉型”肥)分9种配方肥料与等量养分的粉态肥及当地传统施肥为对照,在产量、百果重、叶绿素含量、百叶鲜重、干重和空蓬率等几个指标上进行了比较... 通过在北京市怀柔县沙峪乡红军庄低产坡地做板栗专用肥试验,将新型板栗复混专用肥(“钉型”肥)分9种配方肥料与等量养分的粉态肥及当地传统施肥为对照,在产量、百果重、叶绿素含量、百叶鲜重、干重和空蓬率等几个指标上进行了比较.结果表明,“钉型”肥中以5,6,7配方与粉态肥相同配方及当地传统施肥相比,在以上几个指标上均达到显著或极显著的差异水平.本试验结果为进一步优选出适合北京地区板栗生长的专用肥奠定了基础. 展开更多
关键词 板栗 钉型肥料 粉态肥料 配方
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低NO_x旋流燃烧器一、二次风混合特性分析 被引量:21
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作者 周志军 周丛丛 +4 位作者 许建华 周俊虎 刘茂省 刘建忠 岑可法 《中国电机工程学报》 EI CSCD 北大核心 2010年第11期8-14,共7页
在设计的新型低NOx旋流燃烧器中,采用温度示踪法研究一、二次风的混合情况。通过分析冷态煤粉浓度的分布及煤粉高浓度区域面积的大小,得到:中心管扩角越小,二次风混入越晚,冷态高煤粉浓度区域面积越大;一次风率为0.2、一次风速为15m/s... 在设计的新型低NOx旋流燃烧器中,采用温度示踪法研究一、二次风的混合情况。通过分析冷态煤粉浓度的分布及煤粉高浓度区域面积的大小,得到:中心管扩角越小,二次风混入越晚,冷态高煤粉浓度区域面积越大;一次风率为0.2、一次风速为15m/s、直流二次风速为25m/s时冷态高煤粉浓度区域面积较大,有利于降低NOx的生成;内二次风旋流开度减小较外二次风旋流开度减小对冷态高煤粉浓度区域面积的影响大;内旋流强度为1.35、外旋流强度为1.56为最佳的试验工况。 展开更多
关键词 低NOx旋流燃烧器 温度示踪法 混合 浓度
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Cemented backfill technology based on phosphorous gypsum 被引量:5
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作者 王新民 赵彬 张钦礼 《Journal of Central South University》 SCIE EI CAS 2009年第2期285-291,共7页
Physical-chemical properties of phosphorous gypsum, proportion and cemented mechanism of slurry with gypsum as aggregate were studied to remove the harms of gypsum pile, combining with difficult problems of excessive ... Physical-chemical properties of phosphorous gypsum, proportion and cemented mechanism of slurry with gypsum as aggregate were studied to remove the harms of gypsum pile, combining with difficult problems of excessive mined-out gobs, enormous ore body under roadway and low recovery ratio of Yongshaba Mine, Kaiyang Phosphor Mine Group, Guizhou Province, China. An appropriate backfill system and craflwork were designed, using shattering milling method to crush gypsum, double-axles mixing and strong activation mixing way to mix slurry, cemented slurry and mullock backfill alternately process. The results show that gypsum is fit for backfilling afterwards by adding fly ash, though it is not an ideal aggregate for fine granule and coagulate retardation. The suggested dosage (the mass ratio of cement to fly ash to gypsum) is 1:1:6-1:1:8 with mass fraction of solid materials 60%-63%. Slurry is transported in suspend state with non-plastic strength, and then in concretion state after backfilling. The application to mine shows the technology is feasible, and gypsum utilization ratio is up to 100%. Transportation and backfill effect is very good for paste-like slurry and drenching cemented slurry into mullock, and the compressive strength and recovery ratio are 2.0 MPa and 82.6%, respectively, with the maximum subsidence of surface only 1.307 mm. Furthermore, the investment of system is about 7 × 10^6 yuan (RMB), only 1/10 of that of traditional paste backfill system. 展开更多
关键词 phosphorous gypsum self-flowing transportation cemented backfill cemented mechanism backfill system and craftwork
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Influence of fly ash on early-age cracking behavior of high-flowing concrete 被引量:5
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作者 郑建岚 王雪芳 《Journal of Central South University》 SCIE EI CAS 2009年第2期312-319,共8页
The effects of quality and content of fly ash on the early-age cracking behavior of high-flowing concrete (HFC) were investigated. The early-age cracking behavior of the HFC was analyzed by combining the tests of ev... The effects of quality and content of fly ash on the early-age cracking behavior of high-flowing concrete (HFC) were investigated. The early-age cracking behavior of the HFC was analyzed by combining the tests of evaporation capacity and electrical resistivity of the HFC. In these tests, a modified flat-type specimen was adopted. The results show that the HFC will have a lower evaporation capacity when it is mixed with fine fly ash, while it will have a higher evaporation capacity when grade II! fly ash is used as mineral admixture. And the electrical resistivity rate of HFC reduces with the increase of the content of fly ash. A nonlinear relationship exists between the cracking time of HFC and the minimum electrical resistivity. The early-age cracking behavior of HFC with fly ash can be enhanced by appropriately increasing the fine particle content and MgO, K2O, and SO3 contents of fly ash. The optimal content of fly ash, which makes a satisfied early-age cracking behavior of HFC, is obtained. And when the content of fly ash exceeds a critical value, the early-age cracking behavior of HFC will rapidly decrease. 展开更多
关键词 high-flowing concrete fly ash cracking behavior electrical resistivity
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Tensile mechanical behavior of additively manufactured 316L austenitic stainless steels in liquid lead-bismuth eutectic and in air
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作者 WEN Tao ZHONG Zhi-huai +6 位作者 ZHU Sai-sai ZHOU Man-man WANG Pei CHAI Lin-jiang LIU Guo-qing PANG Bo GONG Xing 《Journal of Central South University》 2025年第8期2823-2840,共18页
In this work,tensile mechanical behavior of 316L steels fabricated by three different processing methods(casting,powder extrusion printing(PEP)and laser powder bed fusion(LPBF))was studied in the presence of liquid le... In this work,tensile mechanical behavior of 316L steels fabricated by three different processing methods(casting,powder extrusion printing(PEP)and laser powder bed fusion(LPBF))was studied in the presence of liquid lead-bismuth eutectic(LBE)and air at 350℃.The results show that all three steels tested in LBE are not subjected to evident degradation of tensile elongation to failure and strength compared to those tested in air,suggesting that LME does not occur regardless of the processing methods.The LPBF 316L steel exhibits the highest yield strength(420-435 MPa),followed by casting 316 L(~242 MPa)and PEP 316L(146-165 MPa).Ultimate tensile strength of three steels is comparable and ranges from 427 to 485 MPa.The PEP and casting 316L steels have similar total elongation to failure(i.e.,40.0%-43.8%),whereas this property decreases markedly to 18.6%-19.5% for the LPBF 316 L steel.The superior strength and relatively low ductility of the LPBF 316L steel can be attributed to nanosized dislocations trapped at cell structures which can produce a remarkable strengthening effect to the steel matrix.By contrast,due to massive residual micropores,the PEP 316L steel has the lowest strength. 展开更多
关键词 316L steel liquid lead-bismuth eutectic tensile properties powder extrusion printing laser powder bed fusion
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