Highly oriented cubic, hollow cubic and spherical nanoparticles of cobalt-iron Prussian blue analogues were synthesized in poly oxyethylene tertoctylphenyl ether (TritonX-100)/n-hexanol/cyclohexane microemulsion. The ...Highly oriented cubic, hollow cubic and spherical nanoparticles of cobalt-iron Prussian blue analogues were synthesized in poly oxyethylene tertoctylphenyl ether (TritonX-100)/n-hexanol/cyclohexane microemulsion. The effects of the water-to-surfactant molar ratio (w), the reactant concentration and the reaction temperature on the morphology of cobalt-iron Prussian blue analogues were studied. The samples were characterized by transmission electron microscopy (TEM), field emission scan electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD) and infrared spectroscopy (IR).展开更多
A new cyano-bridged Gadolinium^(Ⅲ)-Iron^(Ⅲ)complex{[Gd(DMF)_(3)(DMSO)(H_(2)O)_(3)]2H_(2)0(DMF=N,N·-dimethylformamide;DMSO=dimethylsulfoxidel}was synthesized by the grinding reaction method,.It crysta-]llizes in...A new cyano-bridged Gadolinium^(Ⅲ)-Iron^(Ⅲ)complex{[Gd(DMF)_(3)(DMSO)(H_(2)O)_(3)]2H_(2)0(DMF=N,N·-dimethylformamide;DMSO=dimethylsulfoxidel}was synthesized by the grinding reaction method,.It crysta-]llizes in the triclinic.,space group P1 with ceIl parameters:a=O.90363(2)nm,b=1.25078(3)nm,c=1.41303(1)nm,穋m^(-3),Z=2,Mr=756.72,F(000)=760,Ⅲ)and the approxi-mately oriented octahedrally sixfold-coordinated Fe(Ⅲ)are linked by a cyano-bridge group to construct a dinuclear compound.The{[Gd(DMF)_(3)(DMSO)(H_(2)O)_(3)](Ⅲ)-Fe(Ⅲ)interaction is antiferromagnetic.CCDC:223430.展开更多
文摘Highly oriented cubic, hollow cubic and spherical nanoparticles of cobalt-iron Prussian blue analogues were synthesized in poly oxyethylene tertoctylphenyl ether (TritonX-100)/n-hexanol/cyclohexane microemulsion. The effects of the water-to-surfactant molar ratio (w), the reactant concentration and the reaction temperature on the morphology of cobalt-iron Prussian blue analogues were studied. The samples were characterized by transmission electron microscopy (TEM), field emission scan electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD) and infrared spectroscopy (IR).
文摘A new cyano-bridged Gadolinium^(Ⅲ)-Iron^(Ⅲ)complex{[Gd(DMF)_(3)(DMSO)(H_(2)O)_(3)]2H_(2)0(DMF=N,N·-dimethylformamide;DMSO=dimethylsulfoxidel}was synthesized by the grinding reaction method,.It crysta-]llizes in the triclinic.,space group P1 with ceIl parameters:a=O.90363(2)nm,b=1.25078(3)nm,c=1.41303(1)nm,穋m^(-3),Z=2,Mr=756.72,F(000)=760,Ⅲ)and the approxi-mately oriented octahedrally sixfold-coordinated Fe(Ⅲ)are linked by a cyano-bridge group to construct a dinuclear compound.The{[Gd(DMF)_(3)(DMSO)(H_(2)O)_(3)](Ⅲ)-Fe(Ⅲ)interaction is antiferromagnetic.CCDC:223430.
