Structure of 19 cluster cations for AgPn+ and AumPn+ generated by laser plasma reactions have been designed according to chemical bond and calculated using DV-Xamethod of quantum chemistry. The results show that P ato...Structure of 19 cluster cations for AgPn+ and AumPn+ generated by laser plasma reactions have been designed according to chemical bond and calculated using DV-Xamethod of quantum chemistry. The results show that P atoms always tend to form P4fragInnt, then combine with Au atoms. The ability of Au atoms to form cluster is stronger than Ag atorns. It combines with P4 fragment after forming chain or cluster of Au atoms.In many-nuclear system the 5d2, 6s1 hybrid orbitals of Au atoms overlap to foTm cluster skeleton orbitals with each other, there axe a lot of metallic nonbonding orbitals.展开更多
采用动态快速扫描UV-V is吸收光谱,研究了双向窄脉冲电源引发的等离子体化学反应器中,固体填料对气、液、固三相放电脱除废水中靛蓝二磺酸钠(ind igo carm ine,IDS)的影响.实验结果表明:固体填料的填充对气液两相放电反应器中的等离子...采用动态快速扫描UV-V is吸收光谱,研究了双向窄脉冲电源引发的等离子体化学反应器中,固体填料对气、液、固三相放电脱除废水中靛蓝二磺酸钠(ind igo carm ine,IDS)的影响.实验结果表明:固体填料的填充对气液两相放电反应器中的等离子体化学过程具有明显的增强作用;增强的程度由填料的特性决定,相同条件下,填充介质球填料时的处理效果好于填充导体填料时的,而且玻璃球介质填料又优于陶瓷填料;填充介质球的等离子体反应器中IDS的脱色为一级反应.展开更多
文摘Structure of 19 cluster cations for AgPn+ and AumPn+ generated by laser plasma reactions have been designed according to chemical bond and calculated using DV-Xamethod of quantum chemistry. The results show that P atoms always tend to form P4fragInnt, then combine with Au atoms. The ability of Au atoms to form cluster is stronger than Ag atorns. It combines with P4 fragment after forming chain or cluster of Au atoms.In many-nuclear system the 5d2, 6s1 hybrid orbitals of Au atoms overlap to foTm cluster skeleton orbitals with each other, there axe a lot of metallic nonbonding orbitals.
文摘采用动态快速扫描UV-V is吸收光谱,研究了双向窄脉冲电源引发的等离子体化学反应器中,固体填料对气、液、固三相放电脱除废水中靛蓝二磺酸钠(ind igo carm ine,IDS)的影响.实验结果表明:固体填料的填充对气液两相放电反应器中的等离子体化学过程具有明显的增强作用;增强的程度由填料的特性决定,相同条件下,填充介质球填料时的处理效果好于填充导体填料时的,而且玻璃球介质填料又优于陶瓷填料;填充介质球的等离子体反应器中IDS的脱色为一级反应.
