提出一种描述超/特高压磁控式并联电抗器(magnetically controlled shunt reactor,MCSR)非线性磁饱和特性的实用化解耦电磁暂态模型。基于动态磁阻的思想,提出瞬时等效电抗的算法,反映了交直流混合励磁条件下饱和等效电抗的实时动态变...提出一种描述超/特高压磁控式并联电抗器(magnetically controlled shunt reactor,MCSR)非线性磁饱和特性的实用化解耦电磁暂态模型。基于动态磁阻的思想,提出瞬时等效电抗的算法,反映了交直流混合励磁条件下饱和等效电抗的实时动态变化特性;以反双曲函数描述非线性磁路特性,对耦合磁路方程进行解耦,并用带阻尼的隐式梯形积分算法对瞬时等效电抗进行差分化,建立电磁暂态模型,能够与电磁暂态计算相兼容。已在电力系统全数字实时仿真装置(advanced digital power system simulator,ADPSS)中编程实现了仿真模型的工程化应用,并搭建标准算例,以工程投运的MCSR现场运行参数为模型输入量,进行仿真,计算结果数值精确,波形吻合,验证了模型的正确性。展开更多
Vanadium pentoxide xerogel films used for lithium rechargeable batteries were prepared from crystalline c-V2O5 by melt quenching method,then the electrochemical process of lithium intercalation into vanadium pentoxide...Vanadium pentoxide xerogel films used for lithium rechargeable batteries were prepared from crystalline c-V2O5 by melt quenching method,then the electrochemical process of lithium intercalation into vanadium pentoxide xerogel films was simulated with an equivalent circuit model, which was derived from the mechanism of electrode reactions. Measured electrochemical impedance spectra at various electrode potentials were analyzed by using the complex non-linear least-squares fitting method. The results show that impedance spectra consist of 2 high-to- medium frequency depressed arcs and a low frequency straight line. The high frequency arc is attributed to the absorption reaction of lithium ions into the oxide film, the medium frequency arc is attributed to the charge transfer reaction at the vanadium oxide/electrolyte interface and the low frequency is characterized by a straight line with a phase angle of 45° corresponding to the diffusion of lithium ion through vanadium oxide phase. The experimental and calculated results are compared and discussed focusing on the electrochemical performance and the state of charge of the electrode. Moreover, the high consistence of the fitted values of the model to the experimental data indicates that this mathematical model does give a satisfying description of the intercalation process of vanadium pentoxide xerogel films.展开更多
文摘提出一种描述超/特高压磁控式并联电抗器(magnetically controlled shunt reactor,MCSR)非线性磁饱和特性的实用化解耦电磁暂态模型。基于动态磁阻的思想,提出瞬时等效电抗的算法,反映了交直流混合励磁条件下饱和等效电抗的实时动态变化特性;以反双曲函数描述非线性磁路特性,对耦合磁路方程进行解耦,并用带阻尼的隐式梯形积分算法对瞬时等效电抗进行差分化,建立电磁暂态模型,能够与电磁暂态计算相兼容。已在电力系统全数字实时仿真装置(advanced digital power system simulator,ADPSS)中编程实现了仿真模型的工程化应用,并搭建标准算例,以工程投运的MCSR现场运行参数为模型输入量,进行仿真,计算结果数值精确,波形吻合,验证了模型的正确性。
文摘Vanadium pentoxide xerogel films used for lithium rechargeable batteries were prepared from crystalline c-V2O5 by melt quenching method,then the electrochemical process of lithium intercalation into vanadium pentoxide xerogel films was simulated with an equivalent circuit model, which was derived from the mechanism of electrode reactions. Measured electrochemical impedance spectra at various electrode potentials were analyzed by using the complex non-linear least-squares fitting method. The results show that impedance spectra consist of 2 high-to- medium frequency depressed arcs and a low frequency straight line. The high frequency arc is attributed to the absorption reaction of lithium ions into the oxide film, the medium frequency arc is attributed to the charge transfer reaction at the vanadium oxide/electrolyte interface and the low frequency is characterized by a straight line with a phase angle of 45° corresponding to the diffusion of lithium ion through vanadium oxide phase. The experimental and calculated results are compared and discussed focusing on the electrochemical performance and the state of charge of the electrode. Moreover, the high consistence of the fitted values of the model to the experimental data indicates that this mathematical model does give a satisfying description of the intercalation process of vanadium pentoxide xerogel films.
