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卟啉铁(Ⅲ)配合物尾端基团稳定化效应的研究
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作者 何宏山 黄锦汪 计亮年 《中山大学学报(自然科学版)》 CAS CSCD 北大核心 2001年第6期35-38,共4页
合成并表征了 6种苯并咪唑 (BzIm)、苯并噻唑 (BzTa)和苯并恶唑 (BzAz)作为尾端基团的卟啉铁 (Ⅲ )配合物 ,以UV_vis光谱技术测定了配合物与咪唑等形成的加合物稳定常数 β2 、跟踪了抗坏血酸存在下O2 和卟啉铁 (Ⅱ )的反应过程 .结果表... 合成并表征了 6种苯并咪唑 (BzIm)、苯并噻唑 (BzTa)和苯并恶唑 (BzAz)作为尾端基团的卟啉铁 (Ⅲ )配合物 ,以UV_vis光谱技术测定了配合物与咪唑等形成的加合物稳定常数 β2 、跟踪了抗坏血酸存在下O2 和卟啉铁 (Ⅱ )的反应过程 .结果表明 ,由于尾端基团对中心铁 (Ⅲ )和铁 (Ⅱ )的配位 ,使稳定常数增大。 展开更多
关键词 尾式金属卟啉 稳定常数 中间体 配合物 尾端基团 稳定化效应
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Effect of pore pressure on deformation and unstable snap-back for shear band and elastic rock system
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作者 王学滨 《Journal of Central South University of Technology》 EI 2007年第3期418-424,共7页
Fast Lagrangian analysis of continua(FLAC) was used to study the influence of pore pressure on the mechanical behavior of rock specimen in plane strain direct shear, the distribution of yielded elements, the distribut... Fast Lagrangian analysis of continua(FLAC) was used to study the influence of pore pressure on the mechanical behavior of rock specimen in plane strain direct shear, the distribution of yielded elements, the distribution of displacement and velocity across shear band as well as the snap-back (elastic rebound) instability. The effective stress law was used to represent the weakening of rock containing pore fluid under pressure. Numerical results show that rock specimen becomes soft (lower strength and hardening modulus) as pore pressure increases, leading to higher displacement skip across shear band. Higher pore pressure results in larger area of plastic zone, higher concentration of shear strain, more apparent precursor to snap-back (unstable failure) and slower snap-back. For higher pore pressure, the formation of shear band-elastic body system and the snap-back are earlier; the distance of snap-back decreases; the capacity of snap-back decreases, leading to lower elastic strain energy liberated beyond the instability and lower earthquake or rockburst magnitude. In the process of snap-back, the velocity skip across shear band is lower for rock specimen at higher pore pressure, showing the slower velocity of snap-back. 展开更多
关键词 pore pressure shear band snap-back STRAIN-SOFTENING unstable failure stress-strain curve
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