Lithium metal stands out as an exceptionally promising anode material,boasting an extraordinarily high theoretical capacity and impressive energy density.Despite these advantageous characters,the issues of dendrite fo...Lithium metal stands out as an exceptionally promising anode material,boasting an extraordinarily high theoretical capacity and impressive energy density.Despite these advantageous characters,the issues of dendrite formation and volume expansion of lithium metal anodes lead to performance decay and safety concerns,significantly impeding their advancement towards widespread commercial viability.Herein,a lithium-rich Li-B-In composite anode with abundant lithophilic sites and outstanding structural stability is reported to address the mentioned challenges.The evenly distributed Li-In alloy in the bulk phase of anodes act as mixed ion/electron conductors and nucleation sites,facilitating accelerated Li ions transport dynamics and suppressing lithium dendrite formation.Additionally,these micron-sized Li-In particles in LiB fibers framework can enhance overall structural integrity and provide sufficient interior space to accommodate the volume changes during cycling.The electrochemical performance of Li-B-In composite anode exhibits long-term cyclability,superior rate performance and high-capacity retention.This work confirms that the synergy between a 3 D skeleton and hetero-metallic lithiophilic sites can achieve stable and durable lithium metal anodes,offering innovative insights for the practical deployment of lithium metal batteries.展开更多
To investigate the stability of rock mass in high geostress underground powerhouse caverns subjected to excavation,a microseismic(MS)monitoring system was established and the discrete element method(DEM)-based numeric...To investigate the stability of rock mass in high geostress underground powerhouse caverns subjected to excavation,a microseismic(MS)monitoring system was established and the discrete element method(DEM)-based numerical simulation was carried out.The tempo-spatial damage characteristics of rock mass were analyzed.The evolution laws of MS source parameters during the formation of a rock collapse controlled by high geostress and geological structure were investigated.Additionally,a three-dimensional DEM model of the underground powerhouse caverns was built to reveal the deformation characteristics of rock mass.The results indicated that the MS events induced by excavation of high geostress underground powerhouse caverns occurred frequently.The large-stake crown of the main powerhouse was the main damage area.Prior to the rock collapse,the MS event count and accumulated energy release increased rapidly,while the apparent stress sharply increased and then decreased.The amount and proportion of shear and mixed MS events remarkably increased.The maximum displacement was generally located near the spandrel areas.The MS monitoring data and numerical simulation were in good agreement,which can provide significant references for damage evaluation and disaster forecasting in high geostress underground powerhouse caverns.展开更多
Consensus problems for discrete-time multi-agent systems were focused on. In order to design effective consensus protocols, which were aimed at ensuring that the concerned states of agents converged to a common value,...Consensus problems for discrete-time multi-agent systems were focused on. In order to design effective consensus protocols, which were aimed at ensuring that the concerned states of agents converged to a common value, a new consensus protocol for general discrete-time multi-agent system was proposed based on Lyapunov stability theory. For discrete-time multi-agent systems with desired trajectory, trajectory tracking and formation control problems were studied. The main idea of trajectory tracking problems was to design trajectory controller such that each agent tracked desired trajectory. For a type of formation problem with fixed formation structure, the formation structure set was introduced. According to the formation structure set, each agent can track its individual desired trajectory. Finally, simulations were provided to demonstrate the effectiveness of the theoretical results. The mlmerical results show that the states of agents converge to zero with consensus protocol, which is said to achieve a consensus asymptotically. In addition, through designing appropriate trajectory controllers, the simulation results show that agents converge to the desired trajectory asymptotically and can form different formations.展开更多
The stability and stabilization of a class of nonlinear discrete time delayed systems(NDTDS) with time-varying delay and norm-bounded nonlinearity are investigated. Based on discrete time Lyapunov–Krasovskii function...The stability and stabilization of a class of nonlinear discrete time delayed systems(NDTDS) with time-varying delay and norm-bounded nonlinearity are investigated. Based on discrete time Lyapunov–Krasovskii functional method, a sufficient delaydependent condition for asymptotic stability of nonlinear systems is offered. Then, this condition is used to design a new efficient delayed state feedback controller(DSFC) for stabilization of such systems. These conditions are in the linear matrix inequality(LMI) framework. Illustrative examples confirm the improvement of the proposed approach over the similar cases. Furthermore, the obtained stability and stabilization conditions will be extended to uncertain discrete time delayed systems(UDTDS) with polytopic parameter uncertainties and also with norm-bounded parameter uncertainties.展开更多
基金Project(2023YFC3905904)supported by the National Key Research and Development Program,ChinaProject(2220197000221)supported by the Team of Foshan National Hi-Tech Industrial Development Zone Industrialization Entrepreneurial Teams Program,ChinaProject(2024ZZTS0373)supported by the Central South University Graduate Student Autonomous Exploration Innovative Programme,China。
文摘Lithium metal stands out as an exceptionally promising anode material,boasting an extraordinarily high theoretical capacity and impressive energy density.Despite these advantageous characters,the issues of dendrite formation and volume expansion of lithium metal anodes lead to performance decay and safety concerns,significantly impeding their advancement towards widespread commercial viability.Herein,a lithium-rich Li-B-In composite anode with abundant lithophilic sites and outstanding structural stability is reported to address the mentioned challenges.The evenly distributed Li-In alloy in the bulk phase of anodes act as mixed ion/electron conductors and nucleation sites,facilitating accelerated Li ions transport dynamics and suppressing lithium dendrite formation.Additionally,these micron-sized Li-In particles in LiB fibers framework can enhance overall structural integrity and provide sufficient interior space to accommodate the volume changes during cycling.The electrochemical performance of Li-B-In composite anode exhibits long-term cyclability,superior rate performance and high-capacity retention.This work confirms that the synergy between a 3 D skeleton and hetero-metallic lithiophilic sites can achieve stable and durable lithium metal anodes,offering innovative insights for the practical deployment of lithium metal batteries.
基金Project(2017YFC1501100)supported by the National Key R&D Program of ChinaProjects(51809221,51679158)supported by the National Natural Science Foundation of China。
文摘To investigate the stability of rock mass in high geostress underground powerhouse caverns subjected to excavation,a microseismic(MS)monitoring system was established and the discrete element method(DEM)-based numerical simulation was carried out.The tempo-spatial damage characteristics of rock mass were analyzed.The evolution laws of MS source parameters during the formation of a rock collapse controlled by high geostress and geological structure were investigated.Additionally,a three-dimensional DEM model of the underground powerhouse caverns was built to reveal the deformation characteristics of rock mass.The results indicated that the MS events induced by excavation of high geostress underground powerhouse caverns occurred frequently.The large-stake crown of the main powerhouse was the main damage area.Prior to the rock collapse,the MS event count and accumulated energy release increased rapidly,while the apparent stress sharply increased and then decreased.The amount and proportion of shear and mixed MS events remarkably increased.The maximum displacement was generally located near the spandrel areas.The MS monitoring data and numerical simulation were in good agreement,which can provide significant references for damage evaluation and disaster forecasting in high geostress underground powerhouse caverns.
基金Projects(60474029,60774045,60604005) supported by the National Natural Science Foundation of ChinaProject supported by the Graduate Degree Thesis Innovation Foundation of Central South University,China
文摘Consensus problems for discrete-time multi-agent systems were focused on. In order to design effective consensus protocols, which were aimed at ensuring that the concerned states of agents converged to a common value, a new consensus protocol for general discrete-time multi-agent system was proposed based on Lyapunov stability theory. For discrete-time multi-agent systems with desired trajectory, trajectory tracking and formation control problems were studied. The main idea of trajectory tracking problems was to design trajectory controller such that each agent tracked desired trajectory. For a type of formation problem with fixed formation structure, the formation structure set was introduced. According to the formation structure set, each agent can track its individual desired trajectory. Finally, simulations were provided to demonstrate the effectiveness of the theoretical results. The mlmerical results show that the states of agents converge to zero with consensus protocol, which is said to achieve a consensus asymptotically. In addition, through designing appropriate trajectory controllers, the simulation results show that agents converge to the desired trajectory asymptotically and can form different formations.
文摘The stability and stabilization of a class of nonlinear discrete time delayed systems(NDTDS) with time-varying delay and norm-bounded nonlinearity are investigated. Based on discrete time Lyapunov–Krasovskii functional method, a sufficient delaydependent condition for asymptotic stability of nonlinear systems is offered. Then, this condition is used to design a new efficient delayed state feedback controller(DSFC) for stabilization of such systems. These conditions are in the linear matrix inequality(LMI) framework. Illustrative examples confirm the improvement of the proposed approach over the similar cases. Furthermore, the obtained stability and stabilization conditions will be extended to uncertain discrete time delayed systems(UDTDS) with polytopic parameter uncertainties and also with norm-bounded parameter uncertainties.
