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强磁性纳米固体催化剂NiFe2O4、CoFe2O4磁性强度测定的新方法
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作者 秦淑琪 杨声 +3 位作者 李锡恩 郭效军 杨武 高锦章 《石油化工》 CAS CSCD 北大核心 2004年第z1期585-586,共2页
研究了加入稀释剂测定磁性纳米固体催化剂磁性强度的新方法.该方法不同于传统的Gouy法.用该方法测定了研制的NiFe2O4、CoFe2O4分别在不同的温度焙烧后得到的不同粒径纳米强磁性固体催化剂的磁性强度,探讨了纳米固体催化剂粒径与磁性强... 研究了加入稀释剂测定磁性纳米固体催化剂磁性强度的新方法.该方法不同于传统的Gouy法.用该方法测定了研制的NiFe2O4、CoFe2O4分别在不同的温度焙烧后得到的不同粒径纳米强磁性固体催化剂的磁性强度,探讨了纳米固体催化剂粒径与磁性强度的变化规律.结果表明这些催化剂具有较小的粒径、较高的磁性及催化活性,利用磁性强度可对催化剂进行外磁场分离和回收. 展开更多
关键词 纳米固体催化剂 磁性强度 测定
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Effects of intense magnetic field on digestion and settling performances of bauxite 被引量:1
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作者 吕国志 张廷安 +4 位作者 王小晓 张旭华 刘燕 赵秋月 豆志河 《Journal of Central South University》 SCIE EI CAS 2014年第6期2168-2175,共8页
The effects of magnetic field intensity, roasting temperature and roasting time on digestion rate and settling performance of bauxite with different iron contents were investigated systematically. The results indicate... The effects of magnetic field intensity, roasting temperature and roasting time on digestion rate and settling performance of bauxite with different iron contents were investigated systematically. The results indicate that such magnetic treatment can profoundly change the microstructure and digestion performance of bauxite. For the two samples carrying different iron contents, phase transformation of the aluminum oxide phase proceeds faster in the high iron bauxite than the low one. The optimal pretreatment conditions of low iron bauxite are roasting temperature 550 ℃ and magnetic field intensity 6 T, while for high iron bauxite are 500 ℃ and 9 T. The digestion rate of alumina can reach 95% and 92% at digestion temperature of 190 ℃ and 250 ℃. The settling performances of roasted ore by intense magnetic field after digestion are enhanced through pretreatment. 展开更多
关键词 BAUXITE intense magnetic field phase transformation digestion performance settling performance
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Characteristics of non-magnetic nanoparticles in magnetically fluidized bed by adding coarse magnets 被引量:1
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作者 周立 刁润丽 +2 位作者 周涛 Hiroyuki Kage Yoshihide Mawatari 《Journal of Central South University》 SCIE EI CAS 2011年第5期1383-1388,共6页
The fluidization behavior of SiO2, ZnO and TiO2 non-magnetic nanoparticles was investigated in a magnetically fluidized bed (MFB) by adding coarse magnets. The effects of both the amount of coarse magnets and the ma... The fluidization behavior of SiO2, ZnO and TiO2 non-magnetic nanoparticles was investigated in a magnetically fluidized bed (MFB) by adding coarse magnets. The effects of both the amount of coarse magnets and the magnetic field intensity on the fluidization quality of these nanoparticles were investigated. The results show that the coarse magnets added to the bed lead to a reduction in the size of the aggregates formed naturally by the primary nanopartieles. As the macroscopic performances of improved fluidization quality, the bed expansion ratio increases whilst the minimum fluidization velocity decreases with increasing the magnetic field intensity, but for TiO2 nanoparticles there exists a suitable magnetic field intensity of 0.059 6 T. The optimal amounts of coarse magnets for SiO2, ZnO and TiO2 non-magnetic nanoparticles are 40%, 50% and 60% (mass fraction), respectively. The bed expansion results analyzed by the Richardson-Zaki scaling law show that the exponents depend on both the amount of coarse magnets and the magnetic field intensity. 展开更多
关键词 non-magnetic nanoparticles magnetic fluidization AGGLOMERATE coarse magnet
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Microstructure characteristics and effect of grain orientation on magnetic properties of Fe_(63)Co_(32)Gd_5 alloy ribbons
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作者 姚文静 王楠 LEE Je-hyun 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第6期2014-2019,共6页
By using the melt spinning techniques, the Fe63Co32Gd5 alloy ribbons with 15-50 m in thickness and 3-7 mm in width were prepared at the wheel speeds of 15, 20, 25 and 35 m/s. The rapid solidification microstructures w... By using the melt spinning techniques, the Fe63Co32Gd5 alloy ribbons with 15-50 m in thickness and 3-7 mm in width were prepared at the wheel speeds of 15, 20, 25 and 35 m/s. The rapid solidification microstructures were characterized by three layers, the middle layer of which reaches 80% thickness and forms the column grain of(Fe,Co) solid with Gd solution. Grain refinement takes place with the increase of the wheel speed. And after 0.5 h heat treatment at 823 K, the ribbon thickness becomes larger and the middle layer of column grain is very orderly perpendicular to the ribbon plane. The coercivity of quenched and annealed Fe63Co32Gd5 ribbons both have the inflection point at the wheel speed of 20 m/s, and the tendency is declining. The heat treatment processing makes the coercivity become lower by improving the order of(Fe,Co)17Gd2 compound. The saturation magnetization of quenched ribbons increases with the enhancement of wheel speed, whereas that of annealed ones decreases firstly and then increases. The minimum coercivity is 5.30×103 A/m and the maximum saturation magnetization is 163.62 A·m2/kg, which is obtained in the conditions of the wheel speed of 35 m/s and 0.5 h heat treatment at the temperature of 823 K. 展开更多
关键词 Fe-Co-Gd alloy ribbon rapid solidification phase composition magnetic properties
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A novel approach to investigate effect of magnetic field on dynamic properties of natural rubber based isotropic thick magnetorheological elastomers in shear mode
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作者 Sriharsha Hegde Katari Kiran K V Gangadharan 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第7期2612-2619,共8页
The preparation of natural rubber based isotropic thick magnetorheological elastomers(MRE) was focused on by varying the percentage volume concentration of carbonyl iron powder and developing a test set up to test the... The preparation of natural rubber based isotropic thick magnetorheological elastomers(MRE) was focused on by varying the percentage volume concentration of carbonyl iron powder and developing a test set up to test the dynamic properties. Effect of magnetic field on the damping ratio was studied on the amplification region of the transmissibility curve. The viscoelastic dynamic damping nature of the elastomer was also studied by analyzing the force-displacement hysteresis graphs. The results show that MR effect increases with the increase in magnetic field as well as carbonyl iron powder particle concentration. It is observed that softer matrix material produces more MR effect. A maximum of 125% improvement in the loss factor is observed for the MRE with 25% carbonyl iron volume concentration. FEMM simulation shows that as carbonyl iron particle distribution becomes denser, MR effect is improved. FEMM analysis also reveals that if the distance between the adjacent iron particles are reduced from 20 μm to 10 μm, a 40% increase in stored energy is observed. 展开更多
关键词 magnetorheological elastomer natural rubber carbonyl iron powder(CIP) dynamic analysis
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Solution combustion synthesis of Fe-Ni-Y_2O_3 nanocomposites for magnetic application
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作者 刘烨 秦明礼 +4 位作者 章林 贾宝瑞 陈鹏起 张德志 曲选辉 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第1期23-29,共7页
Fe-Ni-Y2O3 nanocomposites with uniform distribution of fine oxide particles in the gamma Fe Ni matrix were successfully fabricated via solution combustion followed by hydrogen reduction. The morphological characterist... Fe-Ni-Y2O3 nanocomposites with uniform distribution of fine oxide particles in the gamma Fe Ni matrix were successfully fabricated via solution combustion followed by hydrogen reduction. The morphological characteristics and phase transformation of the combusted powder and the Fe-Ni-Y2O3 nanocomposites were characterized by XRD, FESEM and TEM.Porous Fe-Ni-Y2O3 nanocomposites with crystallite size below 100 nm were obtained after reduction. The morphology, phases and magnetic property of Fe-Ni-Y2O3 nanocomposites reduced at different temperatures were investigated. The Fe-Ni-Y2O3 nanocomposite reduced at 900 °C has the maximum saturation magnetization and the minimum coercivity values of 167.41 A/(m2·kg)and 3.11 k A/m, respectively. 展开更多
关键词 nanocomposite powder solution combustion synthesis soft magnetic materials magnetic properties
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