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基于磁性测试揭示CoO储锂机理 被引量:1
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作者 徐熙祥 赵越 +1 位作者 阮明岳 李强 《储能科学与技术》 CSCD 北大核心 2024年第1期12-23,共12页
当今社会对储能技术需求日益迫切,电化学储能作为储能系统中的“桥梁”极具发展潜力,然而面临电化学储能中微量杂质相检测以及复杂界面储能探测的挑战,传统表征手段已经显示出局限性。储能材料的晶体结构、元素价态、电子能带以及电化... 当今社会对储能技术需求日益迫切,电化学储能作为储能系统中的“桥梁”极具发展潜力,然而面临电化学储能中微量杂质相检测以及复杂界面储能探测的挑战,传统表征手段已经显示出局限性。储能材料的晶体结构、元素价态、电子能带以及电化学特性与其磁学性质密切耦合,因此本文基于磁性测试,通过高低温等温磁化曲线(magnetic hysteresis,M-H)测试、零场冷/场冷(zero-field-cooled/field-cooled,ZFC/FC)变温磁化曲线测试,相较于传统表征手段X射线衍射(X-ray diffraction,XRD)、X射线光电子能谱(X-ray photoelectron spectroscopy,XPS)及高分辨透射电镜(high resolution transmission electron microscope,HRTEM),能够定量、高效、精准地检测出CoO中存在有效降低极化、提升首圈库仑效率(74.3%~83.77%)、提高大电流循环性能(2 A/g 50圈容量保持率116.59%)的微量金属Co杂质相(CoO/Co@20min 0.66%,CoO/Co@40min 2.27%)。同时本文利用原位实时磁学循环伏安法CV测试及恒流充放电测试,直观揭示出CoO在低电压区间里复杂、难以探测的空间电荷与固体电解质界面(solid electrolyte interphase,SEI)膜两种不同类型的界面储能机制,成功解释了CoO远超理论容量的额外容量来源。储能材料的合成制备离不开高度精准的杂质相检测,储能领域的下一步研究发展取决于能否对界面储能深入理解。本工作为杂质相检测及界面储能机理探测提供了一种无伤且高分辨的磁学全新视角,为推动储能领域的创新,解决当今社会面临的能源挑战贡献力量。 展开更多
关键词 磁学测试 杂质相监测 界面储能 原位实时磁学测试 磁电化学
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Simulation and Experimental Analysis of Mechanical Properties of a Bidirectional Adjustable Magnetorheological Fluid Damper
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作者 YANG Zhi−rong YE Zhong−min +2 位作者 LIU Jin−liang RAO Zhu−shi XIAO Wang−qiang 《船舶力学》 北大核心 2025年第6期1000-1012,共13页
The aim of this study is to address the issues associated with traditional magnetorheological fluid(MRF)dampers,such as insufficient damping force after power failure and susceptibility to settlement.In order to achie... The aim of this study is to address the issues associated with traditional magnetorheological fluid(MRF)dampers,such as insufficient damping force after power failure and susceptibility to settlement.In order to achieve this,a bidirectional adjustable MRF damper was designed and developed.Magnetic field simulation analysis was conducted on the damper,along with simulation analysis on its dynamic characteristics.The dynamic characteristics were ultimately validated through experimental testing on the material testing machine,thereby corroborating the theoretical simulation results.Concurrently,this process generated valuable test data for subsequent implementation of the semi-active vibration control system.The simulation and test results demonstrate that the integrated permanent magnet effectively accomplishes bidirectional regulation.The magnetic induction intensity of the damping channel is 0.2 T in the absence of current,increases to 0.5 T when a maximum forward current of 4 A is applied,and becomes 0 T when a maximum reverse current of 3.8 A is applied.When the excitation amplitude is 8 mm and the frequency is 2 Hz,with the applied currents varying,the maximum damping force reaches 8 kN,while the minimum damping force measures at 511 N.Additionally,at zero current,the damping force stands at 2 kN,which aligns closely with simulation results.The present paper can serve as a valuable reference for the design and research of semi-active MRF dampers. 展开更多
关键词 magnetorheological fluid(MRF) DAMPER permanent magnet finite element analysis test of mechanical properties
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