A C60-aromatic imino derivative with novel structure was prepared by reaction of C60 with benzoic 4-azido-2,3,5,6-tetrafluorobenzoicate in chlorobenzene,at 110℃-113℃,under Ar;which was confirmed by FAB-MS,FT-IR,1H N...A C60-aromatic imino derivative with novel structure was prepared by reaction of C60 with benzoic 4-azido-2,3,5,6-tetrafluorobenzoicate in chlorobenzene,at 110℃-113℃,under Ar;which was confirmed by FAB-MS,FT-IR,1H NMR,13C NMR,19F NMR,UV-vis and HPLC spectra.It cosistents with the C2v symmentry assoiated with [6,6] addition.In addition,this adduct was high stable in therm and high solubility in a solution of chloroform,toluene and acetone;It may find application as microelectronic material in biological,medical and building areas.展开更多
文摘A C60-aromatic imino derivative with novel structure was prepared by reaction of C60 with benzoic 4-azido-2,3,5,6-tetrafluorobenzoicate in chlorobenzene,at 110℃-113℃,under Ar;which was confirmed by FAB-MS,FT-IR,1H NMR,13C NMR,19F NMR,UV-vis and HPLC spectra.It cosistents with the C2v symmentry assoiated with [6,6] addition.In addition,this adduct was high stable in therm and high solubility in a solution of chloroform,toluene and acetone;It may find application as microelectronic material in biological,medical and building areas.
