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复合型酸气吸附剂的制备及性能研究
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作者 仇秀梅 刘叶冬阳 +2 位作者 蔡浩 龚关 梁雅琪 《硅酸盐通报》 CAS 北大核心 2024年第12期4512-4520,共9页
以高效处置矿山、地质、冶金等行业实验室和分析室在生产中产生的酸性有害气体为目的,以天然黏土矿物、碱金属矿物和无机助剂为原料,通过配方设计、挤出成型制备了系列复合型酸气吸附剂,并采用酸溶液浸泡实验和固定床动态吸附实验研究... 以高效处置矿山、地质、冶金等行业实验室和分析室在生产中产生的酸性有害气体为目的,以天然黏土矿物、碱金属矿物和无机助剂为原料,通过配方设计、挤出成型制备了系列复合型酸气吸附剂,并采用酸溶液浸泡实验和固定床动态吸附实验研究了其吸附性能。结果表明,复合型酸气吸附剂对HCl、HNO_(3)的浸泡吸附量分别为0.50~0.80 g/g和0.55~0.95 g/g,对挥发性HCl、HNO_(3)酸气吸收4 h后的Cl^(-)、NO_(3)^(-)吸附量分别大于35和40 mg/g,优于活性炭和市售同类型产品。复合型酸气吸附剂具有均匀微孔隙,其微观结构和化学组成更有利于挥发性酸气的扩散、捕捉和反应等,对Cl^(-)、NO_(3)^(-)的吸附过程符合准二级动力学模型,主要通过化学吸附、吸收作用并伴有物理吸附实现对挥发性HCl、HNO_(3)酸气的去除,具有推广价值。 展开更多
关键词 挥发性酸气 复合型吸附剂 黏土矿物 碱金属矿物 HCL HNO_(3)
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Separation of sulfide lead-zinc-silver ore under low alkalinity condition 被引量:11
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作者 孙伟 苏建芳 +1 位作者 张刚 胡岳华 《Journal of Central South University》 SCIE EI CAS 2012年第8期2307-2315,共9页
A complex lead-zinc-silver sulfide ore containing 2.98% Pb, 6.49% Zn and 116.32×10^-4 % Ag (mass fraction) from Yunnan Province, China, was subjected to this work. Research on mineral processing was conducted a... A complex lead-zinc-silver sulfide ore containing 2.98% Pb, 6.49% Zn and 116.32×10^-4 % Ag (mass fraction) from Yunnan Province, China, was subjected to this work. Research on mineral processing was conducted according to the properties of the lead-zinc-silver ore. Under low alkalinity condition, the lead minerals are successfully separated from the zinc minerals with new reagent YZN as zinc depressant, new reagent BPB as lead collector, CuSO4 as zinc activator and ethyl xanthate as zinc collector. The associated silver is mostly concentrated to the lead concentrate. With the process utilized in this work, a lead concentrate of 51.90% Pb with a recovery of 82.34% and a zinc concentrate of 56.96% Zn with a recovery of 81.98% are produced. The silver recovery in the lead concentrate is 80.61%. Interactions of flotation reagents with minerals were investigated, of which the results indicate that the presence of proper amount of Na2S can precipitate Pb^2+ and has a sulfidation on oxidized lead minerals. The results also show that NazCO3 and YZN used together as combined depressants for sphalerite can signally improve the depressing effect of new reagent YZN on sphalerite. 展开更多
关键词 lead-zinc-silver sulfide low alkalinity new flotation reagents lead-zinc separation silver recovery
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